Types of Equilibrium Class 11 Notes | EduRev

Chemistry Class 11

Class 11 : Types of Equilibrium Class 11 Notes | EduRev

The document Types of Equilibrium Class 11 Notes | EduRev is a part of the Class 11 Course Chemistry Class 11.
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Equilibrium

Basically, the term refers to what we might call a "balance of forces". In the case of mechanical equilibrium, this is its literal definition. A book sitting on a table top remains at rest because the downward force exerted by the earth's gravity acting on the book's mass is exactly balanced by the repulsive force between atoms that prevents two objects from simultaneously occupying the same space, acting in this case between the table surface and the book. 

If you pick up the book and raise it above the table top, the additional upward force exerted by your arm destroys the state of equilibrium as the book moves upward. 

If you wish to hold the book at rest above the table, you adjust the upward force to exactly balance the weight of the book, thus restoring equilibrium. 

An object is in a state of mechanical equilibrium when it is either static or in a state of unchanging motion. 

From the relation f=ma, it is apparent that if the net force on the object is zero, its acceleration must also be zero, so if we can see that an object is not undergoing a change in its motion, we know that it is in mechanical equilibrium.

Another kind of equilibrium we all experience is thermal equilibrium. When two objects are brought into contact, heat will flow from the warmer object to the cooler one until their temperatures become identical. 

Thermal equilibrium is a "balance of forces" in the sense that temperature is a measure of the tendency of an object to lose thermal energy. 

A metallic object at room temperature will feel cool to your hand when you first pick it up because the thermal sensors in your skin detect a flow of heat from your hand into the metal, but as the metal approaches the temperature of your hand, this sensation diminishes. 

The time it takes to achieve thermal equilibrium depends on how readily heat is conducted within and between the objects; thus a wooden object will feel warmer than a metallic object even if both are at room temperature because wood is a relatively poor thermal conductor.

Chemical equilibrium

When a chemical reaction e.g. 2HI(g) Types of Equilibrium Class 11 Notes | EduRev H2(g) + I2(g) takes place in a closed container the quantities of components change as some are consumed and others are formed. Eventually this change will come to an end, after which the composition will remain unchanged as long as the system remains undisturbed. The system is then said to be in its equilibrium state, or more simply, "at equilibrium".

It makes no difference whether we start with two moles of HI or one mole each of H2 and I2; once the reaction has run to completion, the quantities of these two components will be the same. In general, then, we can say that the composition of a chemical reaction system will tend to change in a direction that brings it closer to its equilibrium composition.

Dynamic equilibrium characteristics:

  • The state at which concentrations of reactants or products do not change with time.
  • It is attained when rate of forward reaction becomes equal to rate of backward reaction.
  • A dynamic equilibrium, attained from either side.

Chemical Equilibrium with Graph 

Types of Equilibrium Class 11 Notes | EduRev


Reversible reaction

A chemical equation of the form A → B represents the transformation of A into B, but it does not imply that all of the reactants will be converted into products, or that the reverse reaction B → A cannot also occur. 

In general, both processes can be expected to occur, resulting in an equilibrium mixture containing all of the components of the reaction system. If the equilibrium state is one in which significant quantities of both reactants and products are present then the reaction is said to incomplete or reversible. 

In principle, all chemical reactions are reversible, but this reversibility may not be observable if the fraction of products in the equilibrium mixture is very small, or if the reverse reaction is kinetically inhibited.

Irreversible reactions
Reversible reactions
1. Unidirectional
1. Both directional
2. Goes for completion
2. Never goes for completion
3. No equilibrium is attained
3. Attains equilibrium

4. A reaction is said to be irreversible when either of the product is settled down as solid or escapes out as gas, e.g.,

BaCl2 + Na2SO4 → BaSO4Types of Equilibrium Class 11 Notes | EduRev  + 2NaCl

CaCO3(s) → CaO(s) + CO2(g) ­ Types of Equilibrium Class 11 Notes | EduRev

4. Otherwise the reaction is reversible e.g.,

CaCO3(s) Types of Equilibrium Class 11 Notes | EduRev CaO(s) + CO2(g)

(in closed container)

 

Homogeneous equilibrium

The system in which all the reactant and product have same physical state.

Types of Equilibrium Class 11 Notes | EduRev

Types of Equilibrium Class 11 Notes | EduRev

CH3COOC2H5(aq) + H2O(aq) Types of Equilibrium Class 11 Notes | EduRev CH3COOH (aq) + C2H5OH (aq)

Heterogeneous equilibrium

The system in which atleast one reactant or product have different physical states from others. eg.

CaCO3(s) Types of Equilibrium Class 11 Notes | EduRev CaO(s) + CO2(g), This is three phase system

Salt  + H2O(aq) → Salt (aq), Three phase system.

Law of Mass Action

During the period 1864-1879 Cato Guldberg and Peter Waage showed that an equilibrium can be approached from either direction (see the hydrogen iodide illustration above), implying that any reaction aA + bB → cC + dD is really a competition between a "forward" and a "reverse" reaction. 

When a reaction is at equilibrium, the rates of these two reactions are identical, so no net (macroscopic) change is not observed, although individual components are actively being transformed at the microscopic level. 

Guldberg and Waage showed that the rate of the reaction in either direction is proportional to what they called the "active masses" of the various components:

rate of forward reaction = kf[A]a[B] b

rate of reverse reaction = kr[C]c[D]d

in which the proportionality constants are called rate constants and the quantities in square brackets represent concentrations. 

If we combine the two reactants A and B, the forward reaction starts immediately, but the formation of products allows the reverse process to get underway. As the reaction proceeds, the rate of the forward reaction diminishes while that of the reverse reaction increases. 

Eventually the two processes are proceeding at the same rate, and the reaction is at equilibrium: rate of forward reaction = rate of reverse reaction

kf[A]a [B]b = kr[C]c[D]d If we now change the composition of the system by adding some C or withdrawing some A (thus changing their "active masses"), the reverse rate will exceed the forward rate and a change in composition will occur until a new equilibrium composition is achieved. 

The Law of Mass Action is thus essentially the statement that the equilibrium composition of a reaction mixture can vary according to the quantities of components that are present.

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