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Cheat Sheet: Structure of the Atom

1. Charged Particles in Matter

Experiments with electricity and gas discharge tubes showed that atoms contain charged particles. These particles are called subatomic particles. Scientists discovered three important particles inside an atom: electrons, protons, and neutrons.

Subatomic Particles

Subatomic Particles

Important points:

  • Electrons carry negative charge.
  • Protons carry positive charge.
  • Neutrons have no charge.
  • Protons and neutrons together are called nucleons.

2. Atomic Models

Scientists proposed several models to explain the structure of atoms.

Thomson's Model of the Atom

Thomson proposed the plum pudding model.Thomson`s Model of the Atom

Main features

  • Atom is a sphere of positive charge.
  • Electrons are embedded in this sphere.
  • Positive and negative charges balance each other.
  • Therefore, the atom is electrically neutral.

Limitation

  • Could not explain the results of Rutherford's alpha particle experiment.

Rutherford's Model of the Atom

Rutherford performed the alpha particle scattering experiment using a thin gold foil.

Observations

  1. Most alpha particles passed straight through the foil.
  2. Some particles were deflected slightly.
  3. A very small number of particles rebounded.

Observations

Conclusions

  • Most of the atom is empty space.
  • Positive charge is concentrated in a very small region called the nucleus.
  • Nearly all the mass of the atom lies in the nucleus.
  • Electrons revolve around the nucleus in circular paths.

Drawback

According to classical physics:

  • Moving electrons should lose energy.
  • They should eventually fall into the nucleus.
  • This would make atoms unstable, which contradicts reality.

Bohr's Model of the Atom

Niels Bohr modified Rutherford's model to explain atomic stability.Bohr`s Model of the Atom

Main Postulates

  • Electrons revolve around the nucleus in fixed circular paths called shells or energy levels.
  • Electrons do not lose energy while moving in these shells.
  • Each shell has a definite energy.

Names of Shells

Names of Shells

3. Distribution of Electrons in Shells

Bohr and Bury proposed rules for electron distribution.

Rule 1: Maximum electrons in a shell

The maximum number of electrons in a shell is given by:

2n²

where n = shell number

Rule 1: Maximum electrons in a shell

Rule 2

The outermost shell cannot contain more than 8 electrons.

Rule 3

Electrons are filled in shells from inner shell to outer shell.

Example:

Rule 3

4. Valency

Definition

Valency is the combining capacity of an atom. It depends on the number of electrons in the outermost shell (valence electrons).Schematic atomic structure of the first eighteen elementsSchematic atomic structure of the first eighteen elements

Determination of Valency

If outer shell electrons ≤ 4
Valency = number of electrons.

If outer shell electrons > 4
Valency = 8 - number of electrons.

Examples

Examples

5. Atomic Number

Definition

Atomic number (Z) is the number of protons present in the nucleus of an atom.

Important facts:

  • All atoms of the same element have the same atomic number.
  • In a neutral atom:

Number of protons = Number of electrons

Examples

Examples

6. Mass Number

Definition

Mass number (A) is the total number of protons and neutrons in the nucleus.

Formula:

A = Number of protons + Number of neutrons

Example:

Carbon atom

Protons = 6
Neutrons = 6

Mass number = 12

7. Representation of an Atom

Atoms are represented as:

7. Representation of an Atom

Where:

A = Mass number
Z = Atomic number
X = Symbol of element

Example:

¹⁴₇N

This means:

  • Atomic number = 7
  • Mass number = 14

8. Isotopes

Definition

Isotopes are atoms of the same element that have:

  • Same atomic number
  • Different mass numbers.

Examples

Examples


Properties of Isotopes

Chemical properties: Same

Physical properties: Different

Uses of Isotopes

Uses of Isotopes


9. Isobars

Definition

Isobars are atoms of different elements having:

  • Same mass number
  • Different atomic numbers.

Example

Example

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FAQs on Cheat Sheet: Structure of the Atom

1. What are sub-atomic particles and their significance in atomic structure?
Ans. Sub-atomic particles are the fundamental constituents of an atom, which include protons, neutrons, and electrons. Protons are positively charged and reside in the nucleus, neutrons are neutral particles also found in the nucleus, and electrons are negatively charged particles that orbit around the nucleus. The arrangement and number of these particles determine the properties of an element, including its identity and behaviour in chemical reactions.
2. Describe the main atomic models developed throughout history.
Ans. Various atomic models have been proposed to explain atomic structure. Dalton's model suggested that atoms are indivisible particles. Thomson's model introduced the idea of a "plum pudding" structure, where electrons are embedded in a positively charged sphere. Rutherford's gold foil experiment led to the discovery of the nucleus, resulting in the nuclear model, which depicted atoms as having a dense nucleus surrounded by electrons. Bohr's model later refined this by introducing fixed orbits for electrons, leading to the modern understanding of electron distribution.
3. What is the Bohr-Bury scheme for electron distribution?
Ans. The Bohr-Bury scheme is a method for distributing electrons in an atom based on energy levels or shells. According to this scheme, electrons fill the energy levels starting from the innermost shell to the outermost. The first shell can hold up to 2 electrons, the second shell up to 8, the third shell up to 18, and so on, following the formula 2n², where n is the shell number. This distribution helps explain the chemical properties and reactivity of elements.
4. How do atomic number and mass number differ?
Ans. The atomic number of an element is the number of protons in its nucleus, which determines the element's identity and position in the periodic table. The mass number, on the other hand, is the total number of protons and neutrons in the nucleus. While the atomic number is unique to each element, different isotopes of the same element can have varying mass numbers due to differences in the number of neutrons.
5. What are isotopes and how do they differ from one another?
Ans. Isotopes are variants of a particular chemical element that have the same number of protons but different numbers of neutrons, resulting in different mass numbers. For example, carbon has isotopes such as ¹²C (6 protons and 6 neutrons) and ¹³C (6 protons and 7 neutrons). Isotopes exhibit similar chemical behaviour but can have different physical properties, such as stability and half-life, which is significant in fields like radiocarbon dating and medical imaging.
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