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The correct statements among the given are 
  • a)
    Antimony belongs to 15th group and 5th period
  • b)
    electron gain enthalpy of P > N > S > O
  • c)
    Minimum and maximum oxidation number of phosphorus is -3 and +6
  • d)
    Fluoroapatite, formula is Ca6(PO4)6 CaF2
Correct answer is option 'A'. Can you explain this answer?

Divey Sethi answered
Option A: Group 5A (or VA) of the periodic table are the pnictogens:  the nonmetals nitrogen (N), and phosphorus (P), the metalloids arsenic (As) and antimony (Sb), and the metal bismuth (Bi).
Option B: The electron gain enthalpy of P< N< S< O.
Option C: Minimum and maximum oxidation number of phosphorus are -3 and +5 respectively.
Option D: Fluorapatite is a phosphate mineral with the formula Ca5(PO4)3F .
Hence, option A is correct.

 
    Correct answer is '4'. Can you explain this answer?

    Molecular Orbital Theory and Antibonding Orbitals in Nitrogen

    Molecular orbital theory (MOT) is a theoretical model that describes the behavior of electrons in molecules based on the principles of quantum mechanics. It is used to explain and predict the properties of molecules, including their electronic and magnetic properties, bond lengths, bond angles, and so on.

    In MOT, the electrons in a molecule are treated as waves that are described by molecular orbitals (MOs), which are mathematical functions that represent the probability of finding an electron at a given point in space. These MOs are formed by combining the atomic orbitals of the atoms in the molecule.

    Antibonding orbitals are MOs that have a higher energy than the atomic orbitals from which they are formed. When electrons occupy these orbitals, they weaken the bond between the atoms in the molecule, making it more likely to break apart.

    Nitrogen has five valence electrons, which are represented by the atomic orbitals s and p. In the molecule N2, these atomic orbitals combine to form five MOs: two bonding MOs, two antibonding MOs, and one nonbonding MO.

    The two bonding MOs are lower in energy than the atomic orbitals from which they are formed, and they help to hold the two nitrogen atoms together. The nonbonding MO is filled with two electrons, which are shared equally between the two nitrogen atoms and do not contribute to the bond strength.

    The two antibonding MOs are higher in energy than the atomic orbitals from which they are formed, and they weaken the bond between the two nitrogen atoms. When all five valence electrons are placed into the MOs, there are four electrons in the antibonding MOs and one electron in the nonbonding MO.

    Therefore, according to molecular orbital theory, there are four electrons present in the antibonding orbitals of nitrogen.

    • a)
    • b)
    • c)
    • d)
    Correct answer is option 'B'. Can you explain this answer?

    Nikita Singh answered
    The second ionization energy refers to the energy required to remove the electron from the corresponding monovalent cation of the respective atom.
    It is expected to increase from left to right in the periodic table with the decrease in atomic size.
    Since the Oxygen atom gets a stable electronic configuration, 2s22p3 after removing one electron, the O+ shows greater ionization energy than F+ as well as N+
    Thus, correct order will be: O > F > N > C

     In the third period of the periodic table the element having smallest size is        
    • a)
      Na
    • b)
      CI
    • c)
      Ar
    • d)
      Si
    Correct answer is option 'B'. Can you explain this answer?

    Aarav Sharma answered
    The third period contains eight elements: sodium, magnesium, aluminium, silicon, phosphorus, sulfur, chlorine, and argon.
    In a period from left to right atomic size decreases due to Increase in nuclear charge.
    but the noble gases are bigger than the halogens as they have octet and sort of repulsion occurs in the shells.
    so the smallest element in a period is the halogen.so chlorine Cl is the smallest.

    Maximum number of compounds are known in case of :
    • a)
      Krypton
    • b)
      Helium
    • c)
      Argon
    • d)
      Xenon
    Correct answer is option 'D'. Can you explain this answer?

    Only xenon is well known to form chemical compounds, because xenon is large in size and having higer atomic mass.Due to having larger atomic radius the force of attraction between the outer electron and the protons in the nucleus is weaker.

    Which of the outer electronic configuration represent argon?
    • a)
      ns2np4
    • b)
      ns2
    • c)
      ns2np2
    • d)
      ns2np6
    Correct answer is option 'D'. Can you explain this answer?

    Aadhar Academy answered
    The correct answer is option D
    Outer electronic configuration represents argon ns2,np6.
    Atomic no. of argon is 18. Its electronic configuration will be
     1s2 2s2 2p6 3s2 3p6.
    As the outermost shell is full (3s23p6) it is called noble gas.

    Which of the following gaseous molecule is monoatomic?
    • a)
      Oxygen
    • b)
      Helium
    • c)
      Nitrogen
    • d)
      Chlorine
    Correct answer is option 'B'. Can you explain this answer?

    Swara Sharma answered
    Explanation:
    Monoatomic molecules are the molecules that consist of only one atom of an element. They are rare because most elements tend to bond with other atoms to form molecules. However, some elements are stable in their monoatomic form.

    The given options are:
    a) Oxygen (O2) - Oxygen molecule is diatomic, which means it consists of two atoms of oxygen.
    b) Helium (He) - Helium is a rare example of a monoatomic molecule. It exists as a single atom and does not bond with other atoms.
    c) Nitrogen (N2) - Nitrogen molecule is diatomic, which means it consists of two atoms of nitrogen.
    d) Chlorine (Cl2) - Chlorine molecule is diatomic, which means it consists of two atoms of chlorine.

    Therefore, the correct answer is option 'B', Helium, which is a monoatomic molecule.

    A brown ring is formed in the ring test for NO3 ion. It is due to the formation of
    • a)
      [Fe(H2O)5 (NO)]2+
    • b)
       FeSO4.NO2
    • c)
      [Fe(H2O)4(NO)2]2+
    • d)
      FeSO4.HNO3
    Correct answer is option 'A'. Can you explain this answer?

    Sushil Kumar answered
    When freshly prepared solution of FeSOis added in a solution containing NO3– ion, it leads to formation of a brown coloured complex. This is known as brown ring test of nitrate.

    • a)
    • b)
    • c)
    • d)
    Correct answer is option 'A'. Can you explain this answer?

    (i) Nitrogen is a non-metal.
    (ii) Phosphorus is a non-metal.
    (iii) Arsenic is a metalloid and shows Sublimation.
    (iv) Bismuth is metal and shows the Inert pair effect.
    Hence, option A is correct.

     The valency of inert gas is:
    • a)
      Zero
    • b)
      1
    • c)
      2
    • d)
      3
    Correct answer is option 'A'. Can you explain this answer?

    Tanuja Kapoor answered
    The correct answer is Option A. 
    Valency of an element is defined as its tendency to accept valence electrons.
    Since noble gas has completely filled valence (outer) shells, they have the least reactivity.
    Hence noble gases are already stable in its elemental form. So its valency is zero.
     

    • a)
    • b)
    • c)
    • d)
    Correct answer is option 'B'. Can you explain this answer?

    Gauri Datta answered
    Oxidation of ammonia with CuO produces nitrogen gas and water vapor. This reaction is represented as:

    2NH3 + 3CuO → 3Cu + N2 + 3H2O

    The gaseous chemical produced in this reaction is nitrogen gas (N2), which is also obtained by reacting excess ammonia with chlorine. This reaction is represented as:

    2NH3 + Cl2 → N2 + 2HCl

    Explanation:

    - Ammonium nitrate: Heating ammonium nitrate results in the decomposition of ammonium nitrate into nitrogen gas, water vapor, and oxygen gas. The reaction is represented as:

    NH4NO3 → N2 + 2H2O + O2

    - Potassium dichromate: Heating potassium dichromate results in the production of oxygen gas and potassium chromate. The reaction is represented as:

    4K2Cr2O7 → 4K2CrO4 + 3O2

    - Catalytic oxidation of ammonia: Catalytic oxidation of ammonia involves the use of a catalyst (such as platinum or palladium) to oxidize ammonia to nitrogen gas and water vapor. The reaction is represented as:

    4NH3 + 5O2 → 4NO + 6H2O
    2NO + O2 → 2NO2
    4NO2 + O2 → 2N2O5
    N2O5 → N2 + 2.5O2

    - Reacting excess ammonia with chlorine: This reaction involves the reaction of excess ammonia with chlorine gas to produce nitrogen gas and hydrochloric acid. The reaction is represented as:

    2NH3 + Cl2 → N2 + 2HCl

    Therefore, option B, reacting excess ammonia with chlorine, is the correct answer.

     The element having highest ionisation potential is:
    • a)
      Oxygen
    • b)
      Helium
    • c)
      Nitrogen
    • d)
      Hydrogen
    Correct answer is option 'B'. Can you explain this answer?

    Rajeev Saxena answered
    Thereby, the amount of energy required to remove an electron from the atom decreases. Ionization potential, thus, decreases down a group. The element with highest ionization potential in the periodic table is Helium (2372.1 kj/mol), while the element with the lowest ionization potential is Caesium (375.7 kj/mol).

    In the MOT of F2 molecule, number of electrons occupying antibonding orbitals are
      Correct answer is '8'. Can you explain this answer?

      Nandita Ahuja answered
      Fluorine atom have 2+7 electrons so an F2 molecule contain 18 electrons.

      Hence, 8 electrons occupy the antibonding orbitals.

      The correct statements among the following are
      • a)
        Bond lengths in O2 , are 121 , 134, 149 pm
      • b)
        Ozone is stronger oxidising agent than dioxygen
      • c)
        O2 acts as reducing agent when it reacts with powerful oxidising agents like PtF6
      • d)
        Ozone is much more stable than oxygen
      Correct answer is option 'A,B,C'. Can you explain this answer?

      Srishti Kaur answered
      The correct option is Option A, B and C.
      Bond length is inversely proportional to bond order. O2+ has the highest bond order among these three, so it should have the shortest bond length.
      Ozone is a powerful oxidizing agent as compared to oxygen. This is due to the unstable nature of ozone and the nascent oxygen that is released during the reaction.
      O2 when gas makes others like H2 gas to lose electrons, therefore, O2 gas is an oxidizing agent and H2 when gas loses electrons in redox reaction, therefore H2 gas is a reducing agent.
      Oxygen is more stable than ozone. On heating, ozone readily dissociates and forms oxygen and free radicals of oxygen known as nascent oxygen which take part in reaction, thus ozone is more reactive than oxygen

      Which of the following molecular species has unpaired electron(s) ?
      • a)
        N2
      • b)
        O2
      • c)
        NO+
      • d)
        CN-
      Correct answer is option 'B'. Can you explain this answer?

      Priya Chavan answered
       contains two unpaired electrons and is paramagnetic in nature. On the other hand,  and  contains all paired electrons and are diamagnetic in nature. 

      Noble gases are inert and do not form compounds like other elements because of their:
      • a)
        Low ionization energy
      • b)
        High electron affinities
      • c)
        Close shell electronic configuration
      • d)
        High density
      Correct answer is option 'C'. Can you explain this answer?

      Aravind Kapoor answered
      Helium has two electrons in its outer shell and the rest have eight electrons. Because of their full outer shells, they are very inert and stable. This means they don't tend to react with other elements to form compounds. They are gases under standard conditions.

       Geometry of xenon oxyfluoride (XeOF4) is
      • a)
        Octahedral
      • b)
        Tetrahedral
      • c)
        Linear
      • d)
        Square pyramidal
      Correct answer is option 'D'. Can you explain this answer?

      Naina Menon answered
      Answer:
      Square pyramidal.
      Explanation:
      In order to be able to determine the molecular geometry of xenon oxytetrafluoride,
      XeOF4, you need to start by drawing its Lewis structure.
      To find the number of valence electron you get in one molecule of xenon oxytetrafluoride, add the number of valence electrons of each individual atom that makes up the molecule.
      So, xenon oxytetrafluoride will have a total of
      42 valence electrons 8 valence electrons are coming from the xenon atom 6 valence electrons are coming from the oxygen atom 7 valence electrons from each of the four fluorine atoms.
      Now, xenon will be the central atom. It will bond with the oxygen atom via a double bond. This will ensure that oxygen has a complete octet.
      The xenon atom will bond with the four fluorine atoms via four single bonds, which will ensure that each of the four fluorine atoms gets a complete octet. Afterwards the xenon atom will make double bond with oxygen atom to fulfill its octet. The remaining two electrons will remain as a lone pair.

      Which one of the following has a linear shape?
      • a)
        XeF4
      • b)
        XeF2
      • c)
        XeO3
      • d)
        XeOF4
      Correct answer is option 'B'. Can you explain this answer?

      The correct answer is Option B.
      Xe has an electronic configuration of 5s25p6
      In XeF2, there are two bonding pairs and three lone pairs of electrons. So acc. to VSEPR theory, the structure would be trigonal bipyramidal to avoid electron pair repulsions.(sp3d)
      In XeF4, the structure would be square planar. There are four pairs of bonding electrons and two lone pairs in the molecule. The hybridisation would be sp3d2
      XeOF4 has an octahedral geometry due to sp3d2 hybridization. One trans position is occupied by a lone pair giving pyramid shape to the molecule.
      Thus  XeF2 has sp3d hybridization.

      When chlorine reacts with hot, cone. NaOH, the products formed are
      • a)
        NaCI
      • b)
        NaOCI
      • c)
        NaCIO3
      • d)
        HCI
      Correct answer is option 'A,C'. Can you explain this answer?

      Anupama Nair answered
      When Cl2 reacts with hot and concentrated NaOH, then....6NaOH+3Cl2→5NaCl +NaClO3+3H2O...When Cl2 reacts with cold and dilute NaOH then ...2NaOH+Cl2→NaCl+NaOCl+H2O

      Which pair is isostructural?
      • a)
      • b)
        CO2 and OCS
      • c)
        SO2 and CS2
      • d)
      Correct answer is option 'B,D'. Can you explain this answer?

      C.k Singh answered
      In option B co2 and OCS has Sp2 hybridisation for the central atom.in option D Sp3 hybridisation for the central atom.

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