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All questions of p-Block Elements for JEE Exam

Which of the following statements is true?
a)The atomic radius of Ga is less than B.
b)The atomic radius of Ga is more than Al.
c)The atomic radius of Ga is less than Al.
d)The atomic radius of Ga is equal to Al
Correct answer is option 'C'. Can you explain this answer?

Neha Joshi answered
The atomic radius of the Ga is less than Al because of poor screening effect. The atomic radius of Ga is slightly lesser than of Al because in going from Al to Ga, the electrons have already occupied 3d sub shell in Ga

Maximum number of compounds are known in case of :
  • a)
    Krypton
  • b)
    Helium
  • c)
    Argon
  • d)
    Xenon
Correct answer is option 'D'. Can you explain this answer?

Only xenon is well known to form chemical compounds, because xenon is large in size and having higer atomic mass.Due to having larger atomic radius the force of attraction between the outer electron and the protons in the nucleus is weaker.

 In the third period of the periodic table the element having smallest size is        
  • a)
    Na
  • b)
    CI
  • c)
    Ar
  • d)
    Si
Correct answer is option 'B'. Can you explain this answer?

Aarav Sharma answered
The third period contains eight elements: sodium, magnesium, aluminium, silicon, phosphorus, sulfur, chlorine, and argon.
In a period from left to right atomic size decreases due to Increase in nuclear charge.
but the noble gases are bigger than the halogens as they have octet and sort of repulsion occurs in the shells.
so the smallest element in a period is the halogen.so chlorine Cl is the smallest.

  • a)
  • b)
  • c)
  • d)
Correct answer is option 'B'. Can you explain this answer?

Nikita Singh answered
The second ionization energy refers to the energy required to remove the electron from the corresponding monovalent cation of the respective atom.
It is expected to increase from left to right in the periodic table with the decrease in atomic size.
Since the Oxygen atom gets a stable electronic configuration, 2s22p3 after removing one electron, the O+ shows greater ionization energy than F+ as well as N+
Thus, correct order will be: O > F > N > C

The exhibition of highest co-ordination number depends on the availability of vacant orbitals in the central atom. Which of the following elements is not likely to act as central atom in MF3-6?
  • a)
    B
  • b)
    Al
  • c)
    Ga
  • d)
    In
Correct answer is option 'A'. Can you explain this answer?

Anjana Sharma answered
The element M in the complex ion MF6^3-  has a coordination number of six. Since B has only s- and p-orbitals and no d – orbitals, therefore, at the maximum it can show a coordination number of 4. Thus, B cannot form complex of the type MF6^3-, i.e., option (a) is correct.

 The correct no. of lone pairs on the central atom of compounds XeF2, XeF4 & XeF6are respectively-            [AIEEE-2002]
  • a)
    3, 2,1
  • b)
    4, 3, 2
  • c)
    1, 3, 4
  • d)
    1, 2, 3
Correct answer is option 'A'. Can you explain this answer?

Krishna Iyer answered
The correct answer is option A (3,2,1)
XeF2​ has a linear shape. Its hybridization is sp3d which means it should have a trigonal bipyramidal shape. Since it has 3 lone pairs, they occupy the equatorial triangle.
XeF4​ has sp3d2 hybridization. It has a square planar shape and 2 lone pairs of electrons.
XeF6​ has one lone pair of electrons. The 6 out of 8 electrons of Xenon are shared by 6 atoms of fluorine.

The maximum oxidation state shown by a p-block element is equal to the:
  • a)
    Total number of valence electrons (i.e., the sum of the s and p-electrons)
  • b)
    Total number of s electrons
  • c)
    Total number of p electrons
  • d)
    None of these
Correct answer is option 'A'. Can you explain this answer?

Preeti Khanna answered
  • The oxidation state of an element is related to the number of electrons that an atom loses, gains, or appears to use when joining with another atom in compounds. 
  • It also determines the ability of an atom to oxidize (to lose electrons) or to reduce (to gain electrons) other atoms or species.
  • They should release the total valence electrons to attain stability, so the maximum possible oxidation state is the number of valence electrons.

Which of the outer electronic configuration represent argon?
  • a)
    ns2np4
  • b)
    ns2
  • c)
    ns2np2
  • d)
    ns2np6
Correct answer is option 'D'. Can you explain this answer?

Aadhar Academy answered
The correct answer is option D
Outer electronic configuration represents argon ns2,np6.
Atomic no. of argon is 18. Its electronic configuration will be
 1s2 2s2 2p6 3s2 3p6.
As the outermost shell is full (3s23p6) it is called noble gas.

The order of ionization enthalpy for B, Al and Ga is:
  • a)
    B>Al<Ga 
  • b)
    B
  • c)
    B>Al>Ga
  • d)
    Ga
Correct answer is option 'A'. Can you explain this answer?

Ayush Joshi answered
(A) B>Al<Ga 
The trend in ionization enthalpy is because there is decrease in Ionisation enthalpy from B to Al due to increase in size and from Al to Ga. Ga has more ionisation energy than Al due to uneffective screening effect.
 

One of the following p-block elements has unusually low melting point
  • a)
    Indium
  • b)
    boron
  • c)
    gallium
  • d)
    aluminium
Correct answer is option 'C'. Can you explain this answer?

Preeti Iyer answered
Argon
Argon is most abundant in composition of air percent by volume. It is in 0.934% in composition of air and is one of the major gas in the Earth's atmosphere.

Which of the following group 13 elements oxide is acidic in nature?​
  • a)
    Al2O3
  • b)
    B2O3
  • c)
    Tl2O3
  • d)
    Ga2O3
Correct answer is option 'B'. Can you explain this answer?

Naina Bansal answered
The acidic character of oxides of group 13 decreases down the group, because non-metallic character of elements decreases down the group and metallic character increases.

And we know that oxides of metals are basic in nature and oxides of non-metals are acidic in nature. So acidic character of oxides of group 13 decreases down the group.

For example boron (1st element of group 13) is non-metal, so its oxide is acidic.

Aluminum (2nd element of group 13) shows characteristics of both metal and non-metal, so its oxide shows amphoteric nature.

As we go down the group, indium and thalium (4th and 5th element of group 13) show metallic properties, so their oxides are basic.

Which of the following gaseous molecule is monoatomic?
  • a)
    Oxygen
  • b)
    Helium
  • c)
    Nitrogen
  • d)
    Chlorine
Correct answer is option 'B'. Can you explain this answer?

Swara Sharma answered
Explanation:
Monoatomic molecules are the molecules that consist of only one atom of an element. They are rare because most elements tend to bond with other atoms to form molecules. However, some elements are stable in their monoatomic form.

The given options are:
a) Oxygen (O2) - Oxygen molecule is diatomic, which means it consists of two atoms of oxygen.
b) Helium (He) - Helium is a rare example of a monoatomic molecule. It exists as a single atom and does not bond with other atoms.
c) Nitrogen (N2) - Nitrogen molecule is diatomic, which means it consists of two atoms of nitrogen.
d) Chlorine (Cl2) - Chlorine molecule is diatomic, which means it consists of two atoms of chlorine.

Therefore, the correct answer is option 'B', Helium, which is a monoatomic molecule.

Which one of the following statements regarding helium is incorrect 
[AIEEE 2004]
  • a)
    It is used to produce and sustain powerful superconducting magnets
  • b)
    It is used as a cryogenic agent for carrying out experiments at low temperatures
  • c)
    It is used to fill gas balloons instead of hydrogen because it is lighter and non-inflammable
  • d)
    It is used in gas-cooled nuclear reactors
Correct answer is option 'C'. Can you explain this answer?

Shreya Gupta answered
Helium is twice as heavy as hydrogen, its lifting power is 92% of that of hydrogen. Helium has the lowest melting and boiling point of any element which makes liquid helium an ideal coolant for many extremely low temperature application such as super conducting magnet and cryogenic research where temperature close to absolute zero are needed.

XeF2 is isostructural with
  • a)
    SbCl3
  • b)
    BaCl2
  • c)
    TeF2
  • d)
    ICl2
Correct answer is option 'D'. Can you explain this answer?

Arya Dasgupta answered
C) TeF2

XeF2 and TeF2 have the same structure, which is linear with a bond angle of 180 degrees. SbCl3 has a trigonal pyramidal structure, BaCl2 has a linear structure, and ICl2 has a bent structure.

A brown ring is formed in the ring test for NO3 ion. It is due to the formation of
  • a)
    [Fe(H2O)5 (NO)]2+
  • b)
     FeSO4.NO2
  • c)
    [Fe(H2O)4(NO)2]2+
  • d)
    FeSO4.HNO3
Correct answer is option 'A'. Can you explain this answer?

Sushil Kumar answered
When freshly prepared solution of FeSOis added in a solution containing NO3– ion, it leads to formation of a brown coloured complex. This is known as brown ring test of nitrate.

In which of the following arrangements, the sequence is not strictly according to the property written against it ?      [AIEEE-2009]
  • a)
    HF < HCl < HBr < HI : increasing acid strength
  • b)
    NH3 < PH3 < AsH3 < SbH3 : increasing basic strength
  • c)
    B < C < O < N : increasing first ionization enthalpy
  • d)
    CO< SiO< SnO< PbO2 : increasing oxidising power
Correct answer is option 'B'. Can you explain this answer?

Geetika Shah answered
The correct answer is Option B.
In group15 hydrides, the basic character decreases on going down the group due to decrease in the availability of the lone pair of electrons because of the increase in size of elements from N to Bi. Thus, correct order of basicity is:
NH3 > PH3 > AsH3 > SbH3.
 

When Cl2 gas reacts with hot and concentrated sodium hydroxide solution, the oxidation number of chlorine changes from
  • a)
    Zero to – 1 and zero to +3
  • b)
    Zero to + 1 and zero to –3
  • c)
    Zero to + 1 and zero to –5
  • d)
    Zero to – 1 and zero to +5
Correct answer is option 'D'. Can you explain this answer?

Raghav Bansal answered
The correct answer is option D
The reaction of chlorine gas with hot and concentrated sodium hydroxide solution is
3Cl2​ + 6NaOH⟶NaClO3​+ 5NaCl+3H2​O
Oxidation number of Cl is 0 in Cl2​, −1 in NaCl and +5 in NaClO3
So the oxidation number of chlorine changes from Zero to -1 and Zero to +5.
 

In the MOT of F2 molecule, number of electrons occupying antibonding orbitals are
    Correct answer is '8'. Can you explain this answer?

    Nandita Ahuja answered
    Fluorine atom have 2+7 electrons so an F2 molecule contain 18 electrons.

    Hence, 8 electrons occupy the antibonding orbitals.

     The valency of inert gas is:
    • a)
      Zero
    • b)
      1
    • c)
      2
    • d)
      3
    Correct answer is option 'A'. Can you explain this answer?

    Sushil Kumar answered
    The correct answer is Option A. 
    Valency of an element is defined as its tendency to accept valence electrons.
    Since noble gas has completely filled valence (outer) shells, they have the least reactivity.
    Hence noble gases are already stable in its elemental form. So its valency is zero.
     

    The number of hydrogen atoms (s) attached to phosphorus atom in hypophosphorous acid  is – [AIEEE-2005]
    • a)
       Two
    • b)
      Zero
    • c)
       Three
    • d)
       One
    Correct answer is option 'A'. Can you explain this answer?

    Anjali Iyer answered
    Molecular formula of Hypophosphorous Acid is H3PO2. In this, two hydrogen atoms are attached to phosphorus atom with single bond, one -OH group is attached to phosphorus atom with single bond and one oxygen atom is attached to phosphorus atom with double bond.

    • a)
    • b)
    • c)
    • d)
    Correct answer is option 'B'. Can you explain this answer?

    Gauri Datta answered
    Oxidation of ammonia with CuO produces nitrogen gas and water vapor. This reaction is represented as:

    2NH3 + 3CuO → 3Cu + N2 + 3H2O

    The gaseous chemical produced in this reaction is nitrogen gas (N2), which is also obtained by reacting excess ammonia with chlorine. This reaction is represented as:

    2NH3 + Cl2 → N2 + 2HCl

    Explanation:

    - Ammonium nitrate: Heating ammonium nitrate results in the decomposition of ammonium nitrate into nitrogen gas, water vapor, and oxygen gas. The reaction is represented as:

    NH4NO3 → N2 + 2H2O + O2

    - Potassium dichromate: Heating potassium dichromate results in the production of oxygen gas and potassium chromate. The reaction is represented as:

    4K2Cr2O7 → 4K2CrO4 + 3O2

    - Catalytic oxidation of ammonia: Catalytic oxidation of ammonia involves the use of a catalyst (such as platinum or palladium) to oxidize ammonia to nitrogen gas and water vapor. The reaction is represented as:

    4NH3 + 5O2 → 4NO + 6H2O
    2NO + O2 → 2NO2
    4NO2 + O2 → 2N2O5
    N2O5 → N2 + 2.5O2

    - Reacting excess ammonia with chlorine: This reaction involves the reaction of excess ammonia with chlorine gas to produce nitrogen gas and hydrochloric acid. The reaction is represented as:

    2NH3 + Cl2 → N2 + 2HCl

    Therefore, option B, reacting excess ammonia with chlorine, is the correct answer.

     Which one of the following reactions of Xenon compounds is not feasible ?     [AIEEE-2009]
    • a)
       3 XeF+ 6 H2O → 2 Xe + XeO+ 12 HF + 1.5 O2
    • b)
      2 XeF+ 2H2O → 2 Xe + 4 HF + O2
    • c)
      XeF6 + RbF → Rb [XeF7]
    • d)
      XeO3 + 6 HF → XeF+ 3 H2O
    Correct answer is option 'D'. Can you explain this answer?

    Geetika Shah answered
    XeO3​+6HF⟶XeF6​+3H2​O
    This reaction is not feasible because the products again react to give reactants back. All the xenon fluorides easily undergo hydrolysis and give xenon oxides but the opposite is not possible.
    Hence D

    • a)
    • b)
    • c)
    • d)
    Correct answer is option 'A'. Can you explain this answer?

    (i) Nitrogen is a non-metal.
    (ii) Phosphorus is a non-metal.
    (iii) Arsenic is a metalloid and shows Sublimation.
    (iv) Bismuth is metal and shows the Inert pair effect.
    Hence, option A is correct.

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