Which is more electronegative among sp3, sp2, sp hybradisation...
SP is more electronegative because in SP s character is 50% than in SP2 it is 33% and SP3 it is 25%.....
Which is more electronegative among sp3, sp2, sp hybradisation...
Electronegativity of sp3, sp2, and sp Hybridization
Introduction:
Electronegativity is a measure of an atom's ability to attract electrons towards itself in a chemical bond. It is influenced by factors such as atomic size, nuclear charge, and electron shielding. Hybridization is a concept used to explain the bonding and molecular geometry in molecules. The sp3, sp2, and sp hybridizations are commonly observed in organic chemistry. In this explanation, we will discuss the electronegativity of these hybridizations.
Electronegativity:
Electronegativity values are typically obtained from experimental data or calculated using various scales such as Pauling scale or Mulliken scale. Pauling electronegativity values are commonly used, ranging from 0.7 (for cesium) to 4.0 (for fluorine). Higher electronegativity values indicate a stronger attraction for electrons.
Comparison of Electronegativity:
Let's compare the electronegativity of sp3, sp2, and sp hybridizations:
1. sp3 Hybridization:
- Example: Methane (CH4)
- In sp3 hybridization, one s orbital and three p orbitals combine to form four sp3 hybrid orbitals.
- The electronegativity of the atoms in sp3 hybridization is determined by the electronegativity of the atoms involved. For example, carbon has an electronegativity value of 2.55 (Pauling scale).
- In methane, since all carbon atoms are identical, their electronegativity is the same.
- Therefore, the electronegativity of sp3 hybridized carbon atoms is 2.55.
2. sp2 Hybridization:
- Example: Ethene (C2H4)
- In sp2 hybridization, one s orbital and two p orbitals combine to form three sp2 hybrid orbitals.
- The electronegativity of the atoms in sp2 hybridization is again determined by the electronegativity of the atoms involved. Carbon has an electronegativity value of 2.55.
- In ethene, both carbon atoms are identical, so their electronegativity is the same.
- Therefore, the electronegativity of sp2 hybridized carbon atoms is 2.55.
3. sp Hybridization:
- Example: Ethyne (C2H2)
- In sp hybridization, one s orbital and one p orbital combine to form two sp hybrid orbitals.
- The electronegativity of the atoms in sp hybridization is determined by the electronegativity of the atoms involved. Carbon has an electronegativity value of 2.55.
- In ethyne, both carbon atoms are identical, so their electronegativity is the same.
- Therefore, the electronegativity of sp hybridized carbon atoms is 2.55.
Conclusion:
In summary, the electronegativity of sp3, sp2, and sp hybridized carbon atoms is the same and is determined by the electronegativity of carbon, which is 2.55 on the Pauling scale. The hybridization itself does not significantly affect the electronegativity. It is important to note that electronegativity can vary for
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