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Which one of the following cyano complexes would exhibit the lowest value of paramagnetic behaviour?
(At. No. : Cr = 24, Mn = 25, Fe = 26, Co = 27)
  • a)
    [Cr (CN6)]3−
  • b)
    [ Mn (CN6)]3−
  • c)
    [Fe(CN6)]3−
  • d)
    [Co(CN6)]3−
Correct answer is option 'D'. Can you explain this answer?
Most Upvoted Answer
Which one of the following cyano complexes would exhibit the lowest va...
The complex with the lowest paramagnetic behavior would be the one with the lowest number of unpaired electrons. The number of unpaired electrons is determined by the number of electrons in the d-orbitals of the central metal ion.

a) [Cr(CN6)]3+ has 3 unpaired electrons (since Cr has 3 electrons in its d-orbitals)

b) [Mn(CN)6]3- has 4 unpaired electrons (since Mn has 4 electrons in its d-orbitals)

c) [Fe(CN)6]3- has 5 unpaired electrons (since Fe has 5 electrons in its d-orbitals)

d) [Co(CN)6]3- has 4 unpaired electrons (since Co has 4 electrons in its d-orbitals)

Therefore, the complex with the lowest value of paramagnetic behavior would be [Cr(CN6)]3+.
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Community Answer
Which one of the following cyano complexes would exhibit the lowest va...
Co has configuration 4s2 3d7 so co 3- becomes 4s2 3d10 so it should be least paramagnetic
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Which one of the following cyano complexes would exhibit the lowest value of paramagnetic behaviour?(At. No. : Cr = 24, Mn = 25, Fe = 26, Co = 27)a)[Cr (CN6)]3−b)[ Mn (CN6)]3−c)[Fe(CN6)]3−d)[Co(CN6)]3−Correct answer is option 'D'. Can you explain this answer?
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