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Silver chloride dissolves in excess of NH4OH. The cation present in this solution is
  • a)
    Ag+
  • b)
    [Ag(NH3)2]+
  • c)
    [Ag(NH3)4]+
  • d)
    [Ag(NH3)6]+
Correct answer is option 'B'. Can you explain this answer?
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Silver chloride dissolves in excess of NH4OH. The cation present in th...
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Silver chloride dissolves in excess of NH4OH. The cation present in th...
Explanation:
When silver chloride (AgCl) is dissolved in excess NH4OH (ammonium hydroxide), it forms a complex ion called [Ag(NH3)2]+.

AgCl Dissociation:
AgCl dissociates in water to form Ag+ and Cl- ions.

AgCl(s) ↔ Ag+(aq) + Cl-(aq)

Formation of Complex Ion:
When NH4OH is added in excess, it reacts with Ag+ ions to form a complex ion.

Ag+(aq) + 2NH3(aq) → [Ag(NH3)2]+ (aq)

The reaction involves the coordination of two NH3 molecules (ammonia) with the Ag+ ion to form a complex ion. This complex ion is stable in solution and responsible for the dissolution of silver chloride.

Other Options:
a) Ag: This is the silver cation, but it is not the correct answer because silver chloride does not dissolve in water to form Ag+ ions.

c) [Ag(NH3)4]+: This complex ion has four coordinated NH3 molecules with the Ag+ ion. It is not the correct answer because silver chloride does not form this complex ion.

d) [Ag(NH3)6]+: This complex ion has six coordinated NH3 molecules with the Ag+ ion. It is not the correct answer because silver chloride does not form this complex ion.

Correct Answer:
b) [Ag(NH3)2]+: This complex ion has two coordinated NH3 molecules with the Ag+ ion. It is the correct answer because silver chloride dissolves in excess NH4OH to form this complex ion.

Overall, the dissolution of silver chloride in excess NH4OH involves the formation of a complex ion [Ag(NH3)2]+, which is responsible for the presence of the Ag+ cation in the solution.
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Silver chloride dissolves in excess of NH4OH. The cation present in this solution isa)Ag+b)[Ag(NH3)2]+c)[Ag(NH3)4]+d)[Ag(NH3)6]+Correct answer is option 'B'. Can you explain this answer?
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