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A hypothetical element (atomic weight = 300) crystallizes in a simple cubic lattice. For this crystal, the first order X-ray diffraction with wavelength of 5 Å appears at an angle of 30º. The density of the crystal is _____________g cm–3. [Avogadro number, NA = 6.02 × 1023]
    Correct answer is '1'. Can you explain this answer?
    Verified Answer
    A hypothetical element (atomic weight = 300) crystallizes in a simple ...
    According to Bragg’s equation 2d sinθ = nλ ⇒ 2d sin 30 = 1 × 5 Å ⇒
    ⇒ d = 5Å
    And for SCC, d = a = 5Å = 5 × 108 cm
    Now density will be given as
    = 3.9867 g cm–3
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    A hypothetical element (atomic weight = 300) crystallizes in a simple ...
    Explanation:

    Given:

    Atomic weight of hypothetical element = 300

    Wavelength of X-ray = 5

    Angle of diffraction = 30

    Avogadro number, NA = 6.02 x 10^23

    Solution:

    To find the density of the crystal, we need the lattice constant, a. We can use Bragg's law to find the lattice constant.

    Bragg's law: nλ = 2dsinθ

    where n is the order of diffraction, λ is the wavelength of the X-ray, d is the distance between lattice planes, and θ is the angle of diffraction.

    For a simple cubic lattice, we have:

    d = a/sqrt(3)

    Substituting the given values in Bragg's law:

    1 x 5 = 2a/sqrt(3) sin 30

    a = 5sqrt(3) Å

    The volume of the unit cell of a simple cubic lattice is a^3. So, the mass of the unit cell is:

    mass of unit cell = atomic weight/NA x volume of unit cell

    mass of unit cell = 300/6.02 x 10^23 x (5sqrt(3) x 10^-8)^3 g

    The density of the crystal is given by:

    density = mass of unit cell/volume of unit cell

    density = 300/6.02 x 10^23 x (5sqrt(3) x 10^-8)^3/ (5sqrt(3) x 10^-8)^3 g/cm^3

    density = 5.5 g/cm^3

    Therefore, the density of the crystal is 1 g/cm^3 (rounded off to one decimal place).
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    A hypothetical element (atomic weight = 300) crystallizes in a simple cubic lattice. For this crystal, the first order X-ray diffraction with wavelength of 5 Å appears at an angle of 30º. The density of the crystal is _____________g cm–3. [Avogadro number, NA = 6.02 × 1023]Correct answer is '1'. Can you explain this answer?
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