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​Cu metal crystallizes with fcc structure. The density of crystal is 2698 kg/m3 and mass is 26.98 Kg. X-ray of wavelength 1.537 nm are diffracted by the crystal and the Bragg’s angle is 19.20. Identify the crystal plane which caused this diffraction. (NA = 6.023 × 1023)
  • a)
    (111)
  • b)
    (112)
  • c)
    (121)
  • d)
    (110)
Correct answer is option 'A'. Can you explain this answer?
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​Cu metal crystallizes with fcc structure. The density of crysta...



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​Cu metal crystallizes with fcc structure. The density of crysta...
Angle is measured to be 36.5 degrees.

We can use Bragg's Law to calculate the spacing between the crystal lattice planes:

nλ = 2d sinθ

where n is the order of diffraction (usually 1), λ is the wavelength of the x-ray, d is the spacing between the lattice planes, and θ is the Bragg angle.

Rearranging the equation to solve for d:

d = nλ / 2sinθ

Plugging in the given values:

d = (1)(1.537 nm) / 2sin(36.5 degrees)

d = 0.209 nm

Next, we can use the density and mass of the crystal to calculate the number of atoms in the unit cell:

density = mass / volume

volume = mass / density

The atomic mass of Cu is 63.55 g/mol, so the mass of one Cu atom is:

(26.98 kg / 6.022 x 10^23 atoms/mol) = 4.49 x 10^-23 kg/atom

The volume of the unit cell is:

volume = mass / density = 26.98 kg / 2698 kg/m3 = 0.01 m3

Since the fcc unit cell contains 4 atoms, the volume of one unit cell is one-fourth the volume of the atoms it contains:

volume of one atom = volume of unit cell / 4 = 0.01 m3 / 4 = 0.0025 m3

The length of one side of the unit cell can be calculated using the formula for the volume of a cube:

volume of one atom = length^3

length = (volume of one atom)^(1/3) = (0.0025 m3)^(1/3) = 0.0625 m

Finally, we can use the length of one side of the unit cell to calculate the number of atoms in the unit cell:

number of atoms in unit cell = (length of one side)^3 / volume of one atom

number of atoms in unit cell = (0.0625 m)^3 / 0.0025 m3

number of atoms in unit cell = 4

So there are 4 Cu atoms in the fcc unit cell.
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​Cu metal crystallizes with fcc structure. The density of crystal is 2698 kg/m3 and mass is 26.98 Kg. X-ray of wavelength 1.537 nm are diffracted by the crystal and the Bragg’s angle is 19.20. Identify the crystal plane which caused this diffraction. (NA = 6.023 × 1023)a)(111)b)(112)c)(121)d)(110)Correct answer is option 'A'. Can you explain this answer?
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​Cu metal crystallizes with fcc structure. The density of crystal is 2698 kg/m3 and mass is 26.98 Kg. X-ray of wavelength 1.537 nm are diffracted by the crystal and the Bragg’s angle is 19.20. Identify the crystal plane which caused this diffraction. (NA = 6.023 × 1023)a)(111)b)(112)c)(121)d)(110)Correct answer is option 'A'. Can you explain this answer? for Chemistry 2024 is part of Chemistry preparation. The Question and answers have been prepared according to the Chemistry exam syllabus. Information about ​Cu metal crystallizes with fcc structure. The density of crystal is 2698 kg/m3 and mass is 26.98 Kg. X-ray of wavelength 1.537 nm are diffracted by the crystal and the Bragg’s angle is 19.20. Identify the crystal plane which caused this diffraction. (NA = 6.023 × 1023)a)(111)b)(112)c)(121)d)(110)Correct answer is option 'A'. Can you explain this answer? covers all topics & solutions for Chemistry 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for ​Cu metal crystallizes with fcc structure. The density of crystal is 2698 kg/m3 and mass is 26.98 Kg. X-ray of wavelength 1.537 nm are diffracted by the crystal and the Bragg’s angle is 19.20. Identify the crystal plane which caused this diffraction. (NA = 6.023 × 1023)a)(111)b)(112)c)(121)d)(110)Correct answer is option 'A'. Can you explain this answer?.
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