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Hofmann’s bromamide degradation is used to convert a primary amide into primary amine. The proposed mechanism of reaction are :






Q. 
In the following reaction,
Formation of the above shown products and not any cross-products eliminates completely which step of the reaction mechanism?
  • a)
    Ill
  • b)
    IV
  • c)
    V
  • d)
    VI
Correct answer is option 'C'. Can you explain this answer?
Verified Answer
Hofmann’s bromamide degradation is used to convert a primary ami...
Had the reaction occurred via step (V), carbanion could have attacked either of bromocyanates giving cross-over products also.
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Hofmann’s bromamide degradation is used to convert a primary amide into primary amine. The proposed mechanism of reaction are :Q.In the following reaction,Formation of the above shown products and not any cross-products eliminates completely which step of the reaction mechanism?a)Illb)IVc)Vd)VICorrect answer is option 'C'. Can you explain this answer?
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