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Which kind of isomerism is exhibited by octah edral Co(NH3)4Br2Cl?
- a)Geometrical and Ionization
- b)Geometrical and Optical
- c)Optical and Ionization
- d)Geometrical only
Correct answer is option 'A'. Can you explain this answer?
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Which kind of isomerism is exhibited by octah edral Co(NH3)4Br2Cl?a)Ge...
Co(NH3)4Br 2Cl will show both geometr ical a n d ionization isomerism. [Co(NH3)4Br2]Cl and [Co(NH3)4BrCl]Br are ionization isomers and geometrical isomers are
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Which kind of isomerism is exhibited by octah edral Co(NH3)4Br2Cl?a)Ge...
Isomerism in Co(NH3)4Br2Cl
The coordination compound Co(NH3)4Br2Cl exhibits different types of isomerism due to its octahedral geometry. Understanding the types of isomerism it can exhibit is crucial for grasping the behavior of coordination compounds.
1. Geometrical Isomerism
- In octahedral complexes, geometrical isomerism arises from different arrangements of ligands around the central metal ion.
- For Co(NH3)4Br2Cl, there are two types of geometrical isomers:
- Cis Isomer: The bromide ligands are adjacent to each other.
- Trans Isomer: The bromide ligands are opposite each other.
- This results in different spatial configurations leading to distinct physical and chemical properties.
2. Ionization Isomerism
- Ionization isomerism occurs when a complex can give different ions in solution.
- In the case of Co(NH3)4Br2Cl, it can form two different ionization isomers:
- One can have the formula Co(NH3)4Br2Cl in which Cl is a neutral ligand.
- The other can have Cl displaced by a bromide ion, resulting in different ionic compositions when dissolved in solution.
Conclusion
- The correct answer is option 'A' because Co(NH3)4Br2Cl exhibits both geometrical and ionization isomerism.
- It does not exhibit optical isomerism due to the presence of a plane of symmetry in the geometrical arrangements, hence ruling out option 'B' and 'C'.
Understanding these isomeric forms enhances our knowledge of the structural diversity in coordination chemistry, a key concept for competitive exams like JEE.
The coordination compound Co(NH3)4Br2Cl exhibits different types of isomerism due to its octahedral geometry. Understanding the types of isomerism it can exhibit is crucial for grasping the behavior of coordination compounds.
1. Geometrical Isomerism
- In octahedral complexes, geometrical isomerism arises from different arrangements of ligands around the central metal ion.
- For Co(NH3)4Br2Cl, there are two types of geometrical isomers:
- Cis Isomer: The bromide ligands are adjacent to each other.
- Trans Isomer: The bromide ligands are opposite each other.
- This results in different spatial configurations leading to distinct physical and chemical properties.
2. Ionization Isomerism
- Ionization isomerism occurs when a complex can give different ions in solution.
- In the case of Co(NH3)4Br2Cl, it can form two different ionization isomers:
- One can have the formula Co(NH3)4Br2Cl in which Cl is a neutral ligand.
- The other can have Cl displaced by a bromide ion, resulting in different ionic compositions when dissolved in solution.
Conclusion
- The correct answer is option 'A' because Co(NH3)4Br2Cl exhibits both geometrical and ionization isomerism.
- It does not exhibit optical isomerism due to the presence of a plane of symmetry in the geometrical arrangements, hence ruling out option 'B' and 'C'.
Understanding these isomeric forms enhances our knowledge of the structural diversity in coordination chemistry, a key concept for competitive exams like JEE.
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Which kind of isomerism is exhibited by octah edral Co(NH3)4Br2Cl?a)Geometrical and Ionizationb)Geometrical and Opticalc)Optical and Ionizationd)Geometrical onlyCorrect answer is option 'A'. Can you explain this answer?
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