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At 300 K and 1 atm, 15 mL of a gaseous hydrocarbon requires 375 mL air containing 20% O2 by volume for complete combustion. After combustion the gases occupy 330 mL.Assuming that the water formed is in liquid form and the volumes were measured at the same temperature and pressure, the formula of the hydrocarbon is:  [JEE M 2016]
  • a)
    C4H8
  • b)
    C4H10
  • c)
    C3H6
  • d)
    C3H8
Correct answer is option 'D'. Can you explain this answer?
Verified Answer
At 300 K and 1 atm, 15 mL of a gaseous hydrocarbon requires 375 mL air...
Volume of O2 used =  = 75 ml
∴ From the reaction of combustion
1 ml CxHy requires =
So, 4x + y = 20
x = 3
y = 8
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Most Upvoted Answer
At 300 K and 1 atm, 15 mL of a gaseous hydrocarbon requires 375 mL air...
Given data:
- Temperature (T) = 300 K
- Pressure (P) = 1 atm
- Volume of hydrocarbon (V_hydrocarbon) = 15 mL
- Volume of air (V_air) = 375 mL
- Oxygen content in air (O2_air) = 20% by volume
- Final volume of gases after combustion (V_final) = 330 mL

Key equations:
1. Ideal Gas Law: PV = nRT
2. Volume ratio of gases in combustion: V_hydrocarbon : V_oxygen : V_carbon dioxide : V_water = a : b : c : d (where a, b, c, d are coefficients of balanced combustion equation)

Solution:
Step 1: Finding the volume of oxygen (V_oxygen) required for combustion:
Since the oxygen content in air is 20%, the volume of oxygen in the air can be calculated as:
V_oxygen = V_air * O2_air = 375 mL * 0.20 = 75 mL

Step 2: Calculating the volume of carbon dioxide (V_carbon dioxide) produced:
Since the volume of oxygen is half the volume of hydrocarbon, the balanced combustion equation can be written as:
V_hydrocarbon : V_oxygen : V_carbon dioxide : V_water = 1 : 0.5 : c : d

Since the total volume after combustion is 330 mL, we can write:
V_hydrocarbon + V_oxygen + V_carbon dioxide + V_water = 330 mL

Substituting the given values, we get:
15 mL + 75 mL + V_carbon dioxide + V_water = 330 mL
V_carbon dioxide + V_water = 330 mL - 90 mL = 240 mL

Step 3: Calculating the volume of water (V_water) produced:
Since water is in liquid form, its volume doesn't change with temperature and pressure. Therefore, we can write:
V_water = 240 mL

Step 4: Balancing the combustion equation:
Using the volume ratios of the balanced combustion equation, we have:
1 : 0.5 : c : 240 mL

The lowest whole number ratio for c is 480. Therefore, the balanced combustion equation is:
1 : 0.5 : 480 : 240

Step 5: Determining the formula of the hydrocarbon:
The balanced combustion equation is:
C_hydrocarbonH_hydrocarbon + 0.5O2 → 480CO2 + 240H2O

From the equation, we can determine that the hydrocarbon contains 4 carbon atoms (C4H_hydrocarbon). Therefore, the formula of the hydrocarbon is C3H8 (option D).

Conclusion:
The formula of the hydrocarbon is C3H8 (option D).
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At 300 K and 1 atm, 15 mL of a gaseous hydrocarbon requires 375 mL air containing 20% O2 by volume for complete combustion. After combustion the gases occupy 330 mL.Assuming that the water formed is in liquid form and the volumes were measured at the same temperature and pressure, the formula of the hydrocarbon is: [JEE M 2016]a)C4H8b)C4H10c)C3H6d)C3H8Correct answer is option 'D'. Can you explain this answer?
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