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In metal caronyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligand bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide.
Simple carbonyls are invariably spin-paired complexes except for vanadium metal.
Simple carbonyls are invariably spin-paired complexes except for vanadium metal.
Q.
Which one of the following metal carbonyls involves the d2sp3?hybridisation for the formation of metal-carbon?? bonds and is paramagnetic.
- a)Cr(CO)6]
- b)[V(CO)6]
- c)[Mo(CO)6]
- d)[W (CO)6]
Correct answer is option 'B'. Can you explain this answer?
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Hybridization in Metal Carbonyls
Metal carbonyls are coordination compounds in which carbon monoxide (CO) acts as a ligand, forming a complex with a metal atom. The interaction between the metal and carbon monoxide involves synergic bonding, which leads to an increase in the strength of the metal-ligand bond and a decrease in the bond order of CO in the carbonyl complex compared to the bond order in free carbon monoxide.
Spin Pairing and Paramagnetism
In simple carbonyls, the metal-ligand complexes are invariably spin-paired, meaning that the electrons in the metal's d orbitals are paired up, resulting in a diamagnetic complex. However, there are exceptions to this rule, and one such exception is vanadium metal carbonyl (V(CO)6). Vanadium metal carbonyl is paramagnetic, which means it has unpaired electrons and is attracted to a magnetic field.
Identification of the Metal Carbonyl with d2sp3 Hybridization
To identify the metal carbonyl that involves d2sp3 hybridization for the formation of metal-carbon bonds and is paramagnetic, we need to consider the electronic configuration of the metal atom and the nature of its d orbitals.
Electronic Configuration of Vanadium (V)
Vanadium (V) is a transition metal with an atomic number of 23. Its electronic configuration is [Ar] 3d3 4s2. This configuration indicates that vanadium has three electrons in its d orbitals.
Hybridization in Vanadium Metal Carbonyl (V(CO)6)
For vanadium metal carbonyl (V(CO)6) to have d2sp3 hybridization, the metal atom must utilize two of its d orbitals and a combination of s and p orbitals to form six hybrid orbitals. This hybridization allows the formation of six sigma bonds between the metal and carbon monoxide ligands.
Paramagnetism in Vanadium Metal Carbonyl (V(CO)6)
The presence of unpaired electrons in vanadium metal carbonyl (V(CO)6) leads to its paramagnetic nature. The unpaired electrons cause the complex to be attracted to a magnetic field.
Conclusion
Among the given options, the metal carbonyl that involves d2sp3 hybridization for the formation of metal-carbon bonds and is paramagnetic is option B, [V(CO)6]. Vanadium metal carbonyl exhibits d2sp3 hybridization due to the utilization of two of its d orbitals and a combination of s and p orbitals to form six sigma bonds with carbon monoxide ligands. Additionally, the presence of unpaired electrons in vanadium metal carbonyl leads to its paramagnetic nature.
Metal carbonyls are coordination compounds in which carbon monoxide (CO) acts as a ligand, forming a complex with a metal atom. The interaction between the metal and carbon monoxide involves synergic bonding, which leads to an increase in the strength of the metal-ligand bond and a decrease in the bond order of CO in the carbonyl complex compared to the bond order in free carbon monoxide.
Spin Pairing and Paramagnetism
In simple carbonyls, the metal-ligand complexes are invariably spin-paired, meaning that the electrons in the metal's d orbitals are paired up, resulting in a diamagnetic complex. However, there are exceptions to this rule, and one such exception is vanadium metal carbonyl (V(CO)6). Vanadium metal carbonyl is paramagnetic, which means it has unpaired electrons and is attracted to a magnetic field.
Identification of the Metal Carbonyl with d2sp3 Hybridization
To identify the metal carbonyl that involves d2sp3 hybridization for the formation of metal-carbon bonds and is paramagnetic, we need to consider the electronic configuration of the metal atom and the nature of its d orbitals.
Electronic Configuration of Vanadium (V)
Vanadium (V) is a transition metal with an atomic number of 23. Its electronic configuration is [Ar] 3d3 4s2. This configuration indicates that vanadium has three electrons in its d orbitals.
Hybridization in Vanadium Metal Carbonyl (V(CO)6)
For vanadium metal carbonyl (V(CO)6) to have d2sp3 hybridization, the metal atom must utilize two of its d orbitals and a combination of s and p orbitals to form six hybrid orbitals. This hybridization allows the formation of six sigma bonds between the metal and carbon monoxide ligands.
Paramagnetism in Vanadium Metal Carbonyl (V(CO)6)
The presence of unpaired electrons in vanadium metal carbonyl (V(CO)6) leads to its paramagnetic nature. The unpaired electrons cause the complex to be attracted to a magnetic field.
Conclusion
Among the given options, the metal carbonyl that involves d2sp3 hybridization for the formation of metal-carbon bonds and is paramagnetic is option B, [V(CO)6]. Vanadium metal carbonyl exhibits d2sp3 hybridization due to the utilization of two of its d orbitals and a combination of s and p orbitals to form six sigma bonds with carbon monoxide ligands. Additionally, the presence of unpaired electrons in vanadium metal carbonyl leads to its paramagnetic nature.
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In metal caronyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligand bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide.Simple carbonyls are invariably spin-paired complexes except for vanadium metal.Q.Which one of the following metal carbonyls involves the d2sp3?hybridisation for the formation of metal-carbon?? bonds and is paramagnetic.a)Cr(CO)6]b)[V(CO)6]c)[Mo(CO)6]d)[W (CO)6]Correct answer is option 'B'. Can you explain this answer?
Question Description
In metal caronyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligand bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide.Simple carbonyls are invariably spin-paired complexes except for vanadium metal.Q.Which one of the following metal carbonyls involves the d2sp3?hybridisation for the formation of metal-carbon?? bonds and is paramagnetic.a)Cr(CO)6]b)[V(CO)6]c)[Mo(CO)6]d)[W (CO)6]Correct answer is option 'B'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about In metal caronyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligand bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide.Simple carbonyls are invariably spin-paired complexes except for vanadium metal.Q.Which one of the following metal carbonyls involves the d2sp3?hybridisation for the formation of metal-carbon?? bonds and is paramagnetic.a)Cr(CO)6]b)[V(CO)6]c)[Mo(CO)6]d)[W (CO)6]Correct answer is option 'B'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for In metal caronyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligand bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide.Simple carbonyls are invariably spin-paired complexes except for vanadium metal.Q.Which one of the following metal carbonyls involves the d2sp3?hybridisation for the formation of metal-carbon?? bonds and is paramagnetic.a)Cr(CO)6]b)[V(CO)6]c)[Mo(CO)6]d)[W (CO)6]Correct answer is option 'B'. Can you explain this answer?.
In metal caronyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligand bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide.Simple carbonyls are invariably spin-paired complexes except for vanadium metal.Q.Which one of the following metal carbonyls involves the d2sp3?hybridisation for the formation of metal-carbon?? bonds and is paramagnetic.a)Cr(CO)6]b)[V(CO)6]c)[Mo(CO)6]d)[W (CO)6]Correct answer is option 'B'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about In metal caronyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligand bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide.Simple carbonyls are invariably spin-paired complexes except for vanadium metal.Q.Which one of the following metal carbonyls involves the d2sp3?hybridisation for the formation of metal-carbon?? bonds and is paramagnetic.a)Cr(CO)6]b)[V(CO)6]c)[Mo(CO)6]d)[W (CO)6]Correct answer is option 'B'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for In metal caronyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligand bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide.Simple carbonyls are invariably spin-paired complexes except for vanadium metal.Q.Which one of the following metal carbonyls involves the d2sp3?hybridisation for the formation of metal-carbon?? bonds and is paramagnetic.a)Cr(CO)6]b)[V(CO)6]c)[Mo(CO)6]d)[W (CO)6]Correct answer is option 'B'. Can you explain this answer?.
Solutions for In metal caronyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligand bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide.Simple carbonyls are invariably spin-paired complexes except for vanadium metal.Q.Which one of the following metal carbonyls involves the d2sp3?hybridisation for the formation of metal-carbon?? bonds and is paramagnetic.a)Cr(CO)6]b)[V(CO)6]c)[Mo(CO)6]d)[W (CO)6]Correct answer is option 'B'. Can you explain this answer? in English & in Hindi are available as part of our courses for JEE.
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In metal caronyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligand bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide.Simple carbonyls are invariably spin-paired complexes except for vanadium metal.Q.Which one of the following metal carbonyls involves the d2sp3?hybridisation for the formation of metal-carbon?? bonds and is paramagnetic.a)Cr(CO)6]b)[V(CO)6]c)[Mo(CO)6]d)[W (CO)6]Correct answer is option 'B'. Can you explain this answer?, a detailed solution for In metal caronyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligand bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide.Simple carbonyls are invariably spin-paired complexes except for vanadium metal.Q.Which one of the following metal carbonyls involves the d2sp3?hybridisation for the formation of metal-carbon?? bonds and is paramagnetic.a)Cr(CO)6]b)[V(CO)6]c)[Mo(CO)6]d)[W (CO)6]Correct answer is option 'B'. Can you explain this answer? has been provided alongside types of In metal caronyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligand bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide.Simple carbonyls are invariably spin-paired complexes except for vanadium metal.Q.Which one of the following metal carbonyls involves the d2sp3?hybridisation for the formation of metal-carbon?? bonds and is paramagnetic.a)Cr(CO)6]b)[V(CO)6]c)[Mo(CO)6]d)[W (CO)6]Correct answer is option 'B'. Can you explain this answer? theory, EduRev gives you an
ample number of questions to practice In metal caronyls, there is synergic bonding interaction between metal and carbon monoxide. This leads to increase in strength of metal ligand bond and decrease in bond order of CO in carbonyl complex as compared to bond order in carbon monoxide.Simple carbonyls are invariably spin-paired complexes except for vanadium metal.Q.Which one of the following metal carbonyls involves the d2sp3?hybridisation for the formation of metal-carbon?? bonds and is paramagnetic.a)Cr(CO)6]b)[V(CO)6]c)[Mo(CO)6]d)[W (CO)6]Correct answer is option 'B'. Can you explain this answer? tests, examples and also practice JEE tests.
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