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An organic compound on analysis gave C = 48 gm, H =  8 gm and N = 56 gm. Volume of 1.0 g of the compound was found to be 200 ml at NTP. Molecular formula of the compound is
  • a)
     
    C4H8N4
  • b)
     
    C2H4N2
  • c)
     
    C12H24N12
  • d)
     
    C16H32N16
Correct answer is option 'A'. Can you explain this answer?
Most Upvoted Answer
An organic compound on analysis gave C = 48 gm, H = 8 gm and N = 56 gm...
Given:
- Mass of carbon (C) = 48 gm
- Mass of hydrogen (H) = 8 gm
- Mass of nitrogen (N) = 56 gm
- Volume of 1.0 g of the compound = 200 ml at NTP

To Find:
- Molecular formula of the compound

Solution:
Step 1: Calculate the moles of each element:
- Moles of carbon (C) = Mass of carbon (C) / Molar mass of carbon (C)
- Moles of hydrogen (H) = Mass of hydrogen (H) / Molar mass of hydrogen (H)
- Moles of nitrogen (N) = Mass of nitrogen (N) / Molar mass of nitrogen (N)

The molar mass of carbon (C) is 12 g/mol, the molar mass of hydrogen (H) is 1 g/mol, and the molar mass of nitrogen (N) is 14 g/mol.

Moles of carbon (C) = 48 gm / 12 g/mol = 4 mol
Moles of hydrogen (H) = 8 gm / 1 g/mol = 8 mol
Moles of nitrogen (N) = 56 gm / 14 g/mol = 4 mol

Step 2: Find the empirical formula of the compound:
The empirical formula represents the simplest whole number ratio of the atoms present in a compound.

The empirical formula can be determined by dividing the moles of each element by the smallest number of moles.

Since the smallest number of moles is 4, we divide the moles of each element by 4.

Empirical formula: C1H2N1

Step 3: Calculate the molar mass of the empirical formula:
Molar mass of the empirical formula = (Molar mass of carbon (C) × Number of carbon atoms) + (Molar mass of hydrogen (H) × Number of hydrogen atoms) + (Molar mass of nitrogen (N) × Number of nitrogen atoms)

Molar mass of the empirical formula = (12 g/mol × 1) + (1 g/mol × 2) + (14 g/mol × 1) = 12 g/mol + 2 g/mol + 14 g/mol = 28 g/mol

Step 4: Calculate the number of empirical formula units in 1.0 g:
Number of empirical formula units = Mass of the compound / Molar mass of the empirical formula

Number of empirical formula units = 1.0 g / 28 g/mol = 0.0357 mol

Step 5: Determine the molecular formula:
The molecular formula represents the actual number of atoms of each element in a compound.

The molecular formula can be determined by multiplying the empirical formula by a whole number (n).

Molecular formula = Empirical formula × n

To find the value of 'n', we divide the number of empirical formula units (0.0357 mol) by the number of moles of the empirical formula (0.0357 mol).

n = Number of empirical formula units / Number of moles of the empirical formula
n = 0.0357 mol / 0.0357 mol = 1

Therefore, the molecular formula is the same
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An organic compound on analysis gave C = 48 gm, H = 8 gm and N = 56 gm. Volume of 1.0 g of the compound was found to be 200 ml at NTP. Molecular formula of the compound isa)C4H8N4b)C2H4N2c)C12H24N12d)C16H32N16Correct answer is option 'A'. Can you explain this answer?
Question Description
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