An excess of AgNO3 is added to 100mL of a 0.01M solution of dichlorote...
**Solution:**
To find out the number of AgCl precipitated, we need to determine the reaction between AgNO3 and dichlorotetraaquachromium III chloride.
The chemical equation for the reaction can be written as follows:
AgNO3 + CrCl3.4H2O → AgCl + CrCl3.4H2O
From the balanced equation, we can see that 1 mole of AgNO3 reacts with 1 mole of CrCl3.4H2O to produce 1 mole of AgCl.
Given:
Volume of solution = 100 mL = 0.1 L
Concentration of CrCl3.4H2O = 0.01 M
**Step 1: Convert volume to moles**
Number of moles of CrCl3.4H2O = concentration × volume
= 0.01 M × 0.1 L
= 0.001 moles
**Step 2: Determine the limiting reactant**
The molar ratio between AgNO3 and CrCl3.4H2O is 1:1. Since excess AgNO3 is added, AgNO3 is not the limiting reactant. Therefore, the limiting reactant is CrCl3.4H2O.
**Step 3: Calculate the number of moles of AgCl precipitated**
From the balanced equation, we know that 1 mole of CrCl3.4H2O produces 1 mole of AgCl.
Therefore, the number of moles of AgCl precipitated = 0.001 moles
**Step 4: Calculate the mass of AgCl precipitated**
To calculate the mass of AgCl precipitated, we need to know the molar mass of AgCl.
The molar mass of AgCl = atomic mass of Ag + atomic mass of Cl
= 107.87 g/mol + 35.45 g/mol
= 143.32 g/mol
Mass of AgCl precipitated = number of moles × molar mass
= 0.001 moles × 143.32 g/mol
= 0.14332 g
**Step 5: Convert mass to volume**
To convert the mass of AgCl precipitated to volume, we need to know the density of AgCl. Assuming the density of AgCl is 5.56 g/mL, we can calculate the volume as follows:
Volume of AgCl precipitated = mass/density
= 0.14332 g/5.56 g/mL
= 0.0258 mL
Therefore, the number of AgCl precipitated is approximately 0.0258 mL.
**Answer: (D) 0.001**
An excess of AgNO3 is added to 100mL of a 0.01M solution of dichlorote...
Answer is A
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