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The decreasing value of bond angles from NH3 (106)° to SbH3 (101)° down group-15 of the periodic table is due to: 
[AIEEE-2006]
  • a)
     Decreasing lp – bp repulsion
  • b)
    Decreasing electronegativity
  • c)
    Increasing bp – bp repulsion
  • d)
    Increasing p–orbital character in sp3
Correct answer is option 'B'. Can you explain this answer?
Verified Answer
The decreasing value of bond angles from NH3(106)° to SbH3(101)&de...
With the increase in electronegativity, bond pairs move farther and farther away from the central atom. As a result bp-bp repulsion decreases and the angle decreases accordingly.
 
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The decreasing value of bond angles from NH3(106)° to SbH3(101)° down group-15 of the periodic table is due to:[AIEEE-2006]a)Decreasing lp –bp repulsionb)Decreasing electronegativityc)Increasing bp –bp repulsiond)Increasing p–orbital character in sp3Correct answer is option 'B'. Can you explain this answer?
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