An inorganic chloride (X) on heating with a sodium hydroxide solution ...
Explanation:
1. Inorganic chloride liberating a colourless and non-inflammable gas:
When an inorganic chloride is heated with a sodium hydroxide solution, it liberates a colourless and non-inflammable gas. This information suggests that the inorganic chloride does not contain any combustible elements and the gas liberated is likely to be odourless.
2. Salt (X) giving a red colouration with 4-nitrobenzene-diazonium chloride:
The salt (X) reacts with 4-nitrobenzene-diazonium chloride in the presence of sodium hydroxide solution to give a red colouration. This reaction is a characteristic test for the presence of ammonium salts.
3. Identifying the correct option:
Based on the information provided, we need to choose the option that satisfies both conditions mentioned above. Let's analyze each option:
a) PH4Cl (tetraphenylphosphonium chloride): This compound contains phosphorus, which is a combustible element. Therefore, it does not fit the criteria of liberating a non-inflammable gas.
b) NH4Cl (ammonium chloride): Ammonium chloride is an inorganic chloride and does not contain any combustible elements. When heated with sodium hydroxide solution, it liberates ammonia gas (NH3), which is colorless and non-inflammable. Furthermore, ammonium salts, including NH4Cl, give a red coloration with 4-nitrobenzene-diazonium chloride in the presence of sodium hydroxide solution. Therefore, option B is the correct answer.
c) BiCl3 (bismuth chloride): Bismuth is not a combustible element; however, bismuth chloride does not liberate a colorless and non-inflammable gas when heated with sodium hydroxide. Therefore, it does not satisfy the first condition.
d) CrO2Cl2 (chromium oxychloride): Chromium is a combustible element. Therefore, it does not satisfy the first condition.
Conclusion:
Based on the given information, the correct answer is option B, NH4Cl (ammonium chloride). It liberates a colorless and non-inflammable gas when heated with sodium hydroxide solution and gives a red coloration with 4-nitrobenzene-diazonium chloride in the presence of sodium hydroxide solution.
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