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In metal-olefin interaction, the extent of increase in metal ⎯→ olefin π-back-donation would 
  • a)
    lead to a decrease in C = C bond length  
  • b)
    change the formal oxidation state of the metal  
  • c)
    change the hybridization of the olefin carbon from sp2 to sp3  
  • d)
    increase with the presence of electron donating substituent on the olefin
Correct answer is option 'C'. Can you explain this answer?
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In metal-olefin interaction, the extent of increase in metal olefin -...
Metal-Olefin Interaction and Its Effect on Hybridization

Metal-olefin interaction refers to the interaction between a metal and an olefin molecule, which can result in the formation of a metal-olefin complex. This interaction can have various effects on the properties of the olefin molecule, including its hybridization.

Extent of Back-Donation and Hybridization

The extent of increase in metal-olefin back-donation refers to the transfer of electrons from the metal to the olefin molecule. This transfer can result in the formation of a coordinate covalent bond between the metal and the olefin molecule. The extent of back-donation can determine the hybridization of the olefin carbon atom.

When the back-donation is strong, the olefin carbon atom can undergo hybridization from sp2 to sp3. This is because the additional electrons from the metal can occupy the unhybridized p orbital of the olefin carbon, resulting in the formation of a hybrid orbital with four electron pairs. This hybridization can increase the stability of the metal-olefin complex, as the hybrid orbital can form stronger bonds with the metal.

Other Effects of Metal-Olefin Interaction

The extent of back-donation can also have other effects on the properties of the olefin molecule, including changes in its formal oxidation state and C=C bond length. However, these effects are not directly related to its hybridization.

Conclusion

In summary, the extent of increase in metal-olefin back-donation can result in the hybridization of the olefin carbon atom from sp2 to sp3. This hybridization can increase the stability of the metal-olefin complex, as well as affect other properties of the olefin molecule.
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In metal-olefin interaction, the extent of increase in metal olefin -...
Correct answer is C
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In metal-olefin interaction, the extent of increase in metal olefin -back-donation woulda)lead to a decrease in C = C bond length b)change the formal oxidation state of the metal c)change the hybridization of the olefin carbon from sp2 to sp3 d)increase with the presence of electron donating substituent on the olefinCorrect answer is option 'C'. Can you explain this answer?
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