Explanation:

The correct answer is option 'D' - Khadi and village industry.

Major large-scale industries in India:
- Cotton textile industry: The cotton textile industry is one of the oldest and largest industries in India. It is a major contributor to the country's economy and provides employment to a large number of people. India is one of the largest producers and exporters of cotton textiles in the world.

- Iron and steel industry: The iron and steel industry is another major large-scale industry in India. It is an essential industry for the development of infrastructure and manufacturing sectors. India is the third-largest producer of crude steel in the world.

- Jute industry: The jute industry is another important large-scale industry in India. Jute is a natural fiber that is used to make various products like sacks, bags, and textiles. India is one of the largest producers and exporters of jute in the world.

Khadi and village industry:
- Khadi and village industry, also known as the small-scale industry, is not a major large-scale industry in India. It primarily consists of small-scale and cottage industries that are based in rural areas. These industries are focused on producing traditional and indigenous products like khadi (hand-spun and hand-woven cloth), handicrafts, and village-based products. These industries play a crucial role in rural employment generation and the promotion of rural entrepreneurship.

- While the Khadi and village industry is an important sector in terms of rural development and employment generation, it is not considered as one of the major large-scale industries in India. The major large-scale industries are characterized by their significant contribution to the country's economy, employment generation on a large scale, and their impact on industrial development and exports.

In conclusion, the Khadi and village industry does not belong to India's major large-scale industries, as it primarily consists of small-scale and cottage industries focused on rural development and employment generation.