Class 12 Exam  >  Class 12 Questions  >  Read the passage given below and answer the f... Start Learning for Free
Read the passage given below and answer the following questions:

Aryl halides are extremely less reactive towards nucleophilic substitution reactions due to the following reasons: 
(i) In haloarenes, the electron pairs on halogen atom are in conjugation with π-electrons of the ring.
(ii) In haloalkane, the carbon atom attached to halogen is sp3 hybridised while in case of haloarene, the carbon atom attached to halogen is sp2 -hybridised.
(iii) In case of haloarenes, the phenyl cation formed as a result of self-ionisation will not be stabilised by resonance.

Q. Reaction of C6H5CH2Br with aqueous sodium hydroxide follows _______.
  • a)
    SN1 mechanism
  • b)
    SN2 mechanism
  • c)
    Any of the above two depending upon the temperature of reaction
  • d)
    Saytzeff rule.
Correct answer is option 'D'. Can you explain this answer?
Verified Answer
Read the passage given below and answer the following questions:Aryl h...
C6H5-CH2 is stable cation so favours the progress of reaction by SN1 mechanism.
View all questions of this test
Most Upvoted Answer
Read the passage given below and answer the following questions:Aryl h...
The π-electrons of the aromatic ring. This conjugation delocalizes the electron density and makes it less available for attack by nucleophiles.
(ii) The carbon-halogen bond in haloarenes is shorter and stronger compared to the carbon-halogen bond in alkyl halides. This makes it more difficult for nucleophiles to break the bond and replace the halogen atom.
(iii) The aromatic ring in haloarenes is highly stable due to resonance and delocalization of electrons. This stability makes it less likely for the ring to undergo substitution reactions.

Questions:
1. Why are aryl halides less reactive towards nucleophilic substitution reactions?
2. What is the effect of conjugation on the reactivity of haloarenes?
3. How does the carbon-halogen bond length affect the reactivity of haloarenes?
4. What makes the aromatic ring in haloarenes highly stable?
Explore Courses for Class 12 exam

Similar Class 12 Doubts

Read the passage given below and answer the following questions:Aryl halides are extremely less reactive towards nucleophilic substitution reactions due to the following reasons:(i) In haloarenes, the electron pairs on halogen atom are in conjugation with π-electrons of the ring.(ii) In haloalkane, the carbon atom attached to halogen is sp3 hybridised while in case of haloarene, the carbon atom attached to halogen is sp2 -hybridised.(iii) In case of haloarenes, the phenyl cation formed as a result of self-ionisation will not be stabilised by resonance.Q. Reaction of C6H5CH2Br with aqueous sodium hydroxide follows _______.a)SN1 mechanismb)SN2 mechanismc)Any of the above two depending upon the temperature of reactiond)Saytzeff rule.Correct answer is option 'D'. Can you explain this answer?
Question Description
Read the passage given below and answer the following questions:Aryl halides are extremely less reactive towards nucleophilic substitution reactions due to the following reasons:(i) In haloarenes, the electron pairs on halogen atom are in conjugation with π-electrons of the ring.(ii) In haloalkane, the carbon atom attached to halogen is sp3 hybridised while in case of haloarene, the carbon atom attached to halogen is sp2 -hybridised.(iii) In case of haloarenes, the phenyl cation formed as a result of self-ionisation will not be stabilised by resonance.Q. Reaction of C6H5CH2Br with aqueous sodium hydroxide follows _______.a)SN1 mechanismb)SN2 mechanismc)Any of the above two depending upon the temperature of reactiond)Saytzeff rule.Correct answer is option 'D'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about Read the passage given below and answer the following questions:Aryl halides are extremely less reactive towards nucleophilic substitution reactions due to the following reasons:(i) In haloarenes, the electron pairs on halogen atom are in conjugation with π-electrons of the ring.(ii) In haloalkane, the carbon atom attached to halogen is sp3 hybridised while in case of haloarene, the carbon atom attached to halogen is sp2 -hybridised.(iii) In case of haloarenes, the phenyl cation formed as a result of self-ionisation will not be stabilised by resonance.Q. Reaction of C6H5CH2Br with aqueous sodium hydroxide follows _______.a)SN1 mechanismb)SN2 mechanismc)Any of the above two depending upon the temperature of reactiond)Saytzeff rule.Correct answer is option 'D'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Read the passage given below and answer the following questions:Aryl halides are extremely less reactive towards nucleophilic substitution reactions due to the following reasons:(i) In haloarenes, the electron pairs on halogen atom are in conjugation with π-electrons of the ring.(ii) In haloalkane, the carbon atom attached to halogen is sp3 hybridised while in case of haloarene, the carbon atom attached to halogen is sp2 -hybridised.(iii) In case of haloarenes, the phenyl cation formed as a result of self-ionisation will not be stabilised by resonance.Q. Reaction of C6H5CH2Br with aqueous sodium hydroxide follows _______.a)SN1 mechanismb)SN2 mechanismc)Any of the above two depending upon the temperature of reactiond)Saytzeff rule.Correct answer is option 'D'. Can you explain this answer?.
Solutions for Read the passage given below and answer the following questions:Aryl halides are extremely less reactive towards nucleophilic substitution reactions due to the following reasons:(i) In haloarenes, the electron pairs on halogen atom are in conjugation with π-electrons of the ring.(ii) In haloalkane, the carbon atom attached to halogen is sp3 hybridised while in case of haloarene, the carbon atom attached to halogen is sp2 -hybridised.(iii) In case of haloarenes, the phenyl cation formed as a result of self-ionisation will not be stabilised by resonance.Q. Reaction of C6H5CH2Br with aqueous sodium hydroxide follows _______.a)SN1 mechanismb)SN2 mechanismc)Any of the above two depending upon the temperature of reactiond)Saytzeff rule.Correct answer is option 'D'. Can you explain this answer? in English & in Hindi are available as part of our courses for Class 12. Download more important topics, notes, lectures and mock test series for Class 12 Exam by signing up for free.
Here you can find the meaning of Read the passage given below and answer the following questions:Aryl halides are extremely less reactive towards nucleophilic substitution reactions due to the following reasons:(i) In haloarenes, the electron pairs on halogen atom are in conjugation with π-electrons of the ring.(ii) In haloalkane, the carbon atom attached to halogen is sp3 hybridised while in case of haloarene, the carbon atom attached to halogen is sp2 -hybridised.(iii) In case of haloarenes, the phenyl cation formed as a result of self-ionisation will not be stabilised by resonance.Q. Reaction of C6H5CH2Br with aqueous sodium hydroxide follows _______.a)SN1 mechanismb)SN2 mechanismc)Any of the above two depending upon the temperature of reactiond)Saytzeff rule.Correct answer is option 'D'. Can you explain this answer? defined & explained in the simplest way possible. Besides giving the explanation of Read the passage given below and answer the following questions:Aryl halides are extremely less reactive towards nucleophilic substitution reactions due to the following reasons:(i) In haloarenes, the electron pairs on halogen atom are in conjugation with π-electrons of the ring.(ii) In haloalkane, the carbon atom attached to halogen is sp3 hybridised while in case of haloarene, the carbon atom attached to halogen is sp2 -hybridised.(iii) In case of haloarenes, the phenyl cation formed as a result of self-ionisation will not be stabilised by resonance.Q. Reaction of C6H5CH2Br with aqueous sodium hydroxide follows _______.a)SN1 mechanismb)SN2 mechanismc)Any of the above two depending upon the temperature of reactiond)Saytzeff rule.Correct answer is option 'D'. Can you explain this answer?, a detailed solution for Read the passage given below and answer the following questions:Aryl halides are extremely less reactive towards nucleophilic substitution reactions due to the following reasons:(i) In haloarenes, the electron pairs on halogen atom are in conjugation with π-electrons of the ring.(ii) In haloalkane, the carbon atom attached to halogen is sp3 hybridised while in case of haloarene, the carbon atom attached to halogen is sp2 -hybridised.(iii) In case of haloarenes, the phenyl cation formed as a result of self-ionisation will not be stabilised by resonance.Q. Reaction of C6H5CH2Br with aqueous sodium hydroxide follows _______.a)SN1 mechanismb)SN2 mechanismc)Any of the above two depending upon the temperature of reactiond)Saytzeff rule.Correct answer is option 'D'. Can you explain this answer? has been provided alongside types of Read the passage given below and answer the following questions:Aryl halides are extremely less reactive towards nucleophilic substitution reactions due to the following reasons:(i) In haloarenes, the electron pairs on halogen atom are in conjugation with π-electrons of the ring.(ii) In haloalkane, the carbon atom attached to halogen is sp3 hybridised while in case of haloarene, the carbon atom attached to halogen is sp2 -hybridised.(iii) In case of haloarenes, the phenyl cation formed as a result of self-ionisation will not be stabilised by resonance.Q. Reaction of C6H5CH2Br with aqueous sodium hydroxide follows _______.a)SN1 mechanismb)SN2 mechanismc)Any of the above two depending upon the temperature of reactiond)Saytzeff rule.Correct answer is option 'D'. Can you explain this answer? theory, EduRev gives you an ample number of questions to practice Read the passage given below and answer the following questions:Aryl halides are extremely less reactive towards nucleophilic substitution reactions due to the following reasons:(i) In haloarenes, the electron pairs on halogen atom are in conjugation with π-electrons of the ring.(ii) In haloalkane, the carbon atom attached to halogen is sp3 hybridised while in case of haloarene, the carbon atom attached to halogen is sp2 -hybridised.(iii) In case of haloarenes, the phenyl cation formed as a result of self-ionisation will not be stabilised by resonance.Q. Reaction of C6H5CH2Br with aqueous sodium hydroxide follows _______.a)SN1 mechanismb)SN2 mechanismc)Any of the above two depending upon the temperature of reactiond)Saytzeff rule.Correct answer is option 'D'. Can you explain this answer? tests, examples and also practice Class 12 tests.
Explore Courses for Class 12 exam
Signup for Free!
Signup to see your scores go up within 7 days! Learn & Practice with 1000+ FREE Notes, Videos & Tests.
10M+ students study on EduRev