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[Co(NH₃)₄Cl₂]NO₂ and [Co(NH₃)₄ClNO₂]Cl exhibit which type of isomerism
- a)Geometrical
- b)Optical
- c)Linkage
- d)Ionisation
Correct answer is option 'D'. Can you explain this answer?
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[Co(NH)Cl]NO and [Co(NH)ClNO]Cl exhibit which type of isomerisma)Geome...
Ionisation Isomerism in Coordination Compounds
Ionisation isomerism is a type of structural isomerism that occurs in coordination compounds where the ligands inside and outside the coordination sphere are exchanged.
Explanation of the Given Isomers
- The given compounds, [Co(NH)Cl]NO and [Co(NH)ClNO]Cl, exhibit ionisation isomerism.
- In [Co(NH)Cl]NO, the nitrate ion (NO) is outside the coordination sphere, while in [Co(NH)ClNO]Cl, the nitrosonium ion (NO+) is inside the coordination sphere.
- The exchange of the nitrate ion and nitrosonium ion results in the formation of two different compounds with the same chemical formula but different structures.
Significance of Ionisation Isomerism
- Ionisation isomerism is important in understanding the structural diversity of coordination compounds.
- It helps in studying the effects of ligand exchange on the overall chemical and physical properties of the compounds.
Conclusion
In conclusion, the isomerism exhibited by the compounds [Co(NH)Cl]NO and [Co(NH)ClNO]Cl is ionisation isomerism. Understanding different types of isomerism in coordination compounds is crucial in the field of inorganic chemistry.
Ionisation isomerism is a type of structural isomerism that occurs in coordination compounds where the ligands inside and outside the coordination sphere are exchanged.
Explanation of the Given Isomers
- The given compounds, [Co(NH)Cl]NO and [Co(NH)ClNO]Cl, exhibit ionisation isomerism.
- In [Co(NH)Cl]NO, the nitrate ion (NO) is outside the coordination sphere, while in [Co(NH)ClNO]Cl, the nitrosonium ion (NO+) is inside the coordination sphere.
- The exchange of the nitrate ion and nitrosonium ion results in the formation of two different compounds with the same chemical formula but different structures.
Significance of Ionisation Isomerism
- Ionisation isomerism is important in understanding the structural diversity of coordination compounds.
- It helps in studying the effects of ligand exchange on the overall chemical and physical properties of the compounds.
Conclusion
In conclusion, the isomerism exhibited by the compounds [Co(NH)Cl]NO and [Co(NH)ClNO]Cl is ionisation isomerism. Understanding different types of isomerism in coordination compounds is crucial in the field of inorganic chemistry.
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[Co(NH)Cl]NO and [Co(NH)ClNO]Cl exhibit which type of isomerisma)Geometricalb)Opticalc)Linkaged)IonisationCorrect answer is option 'D'. Can you explain this answer?
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