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The tendency of BF3, BCl3 and BBr3 to behave as Lewis acid decreases in the sequence:
- a)BCl3 > BF3 > BBr3
- b)BBr3 > BCl3 > BF3
- c)BBr3 > BF3 > BCl3
- d)BF3 > BCl3 > BBr3
Correct answer is option 'B'. Can you explain this answer?
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Most Upvoted Answer
The tendency of BF3, BCl3 and BBr3 to behave as Lewis acid decreases ...
P-p overlap between B and F is maximum due to identical size and energy of p- orbitals, so electron deficiency in boron of BF3 is neutralized partially to the maximum extent by back donation.
Hence BF3 is least acidic.
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The tendency of BF3, BCl3 and BBr3 to behave as Lewis acid decreases in the sequence:a)BCl3 > BF3 > BBr3b)BBr3 > BCl3 > BF3c)BBr3 > BF3 > BCl3d)BF3 > BCl3 > BBr3Correct answer is option 'B'. Can you explain this answer?
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