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In which of the following is the ratio of the sizes of cation to anion the smallest?
  • a)
    NaCl
  • b)
    KCl
  • c)
    MgCl2
  • d)
    CaF2
Correct answer is option 'C'. Can you explain this answer?
Most Upvoted Answer
In which of the following is the ratio of the sizes of cation to anio...
Na+ = 116 pm, K+ = 152 pm Mg2+ = 86 pm, Ca2+ = 114 pm
F= 119 pm, Cl = 167 pm
So, the order of the size of cations is:
Mg2+ < />2+ < />+ < />+
The ratio of the will be the smallest for MgCl2.
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Community Answer
In which of the following is the ratio of the sizes of cation to anio...
Explanation:

Size of Cation and Anion:
- The size of cation is determined by the number of protons in the nucleus.
- The size of anion is determined by the number of electrons in the electron cloud.

Ratios of Sizes:
- In NaCl, Na+ cation and Cl- anion have a size ratio of 1:1.
- In KCl, K+ cation and Cl- anion have a size ratio of 1:1.
- In MgCl2, Mg2+ cation and Cl- anion have a size ratio of 1:2.
- In CaF2, Ca2+ cation and F- anion have a size ratio of 1:2.

Smallest Size Ratio:
- Among the given options, MgCl2 has the smallest ratio of cation to anion size, which is 1:2.
- This indicates that the cation (Mg2+) is relatively smaller compared to the anion (Cl-) in MgCl2.
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In which of the following is the ratio of the sizes of cation to anion the smallest?a)NaClb)KClc)MgCl2d)CaF2Correct answer is option 'C'. Can you explain this answer?
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