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Which of the following is correct about Tetraamminedithiocyanato-s cobalt (III) tris (oxalato) cobaltate (III) ?
- a)Formula of the complex is [Co(SCN)2(NH3)4][Co(ox)3]
- b)It is a chelating complex and show linkage isomerism
- c)It shows optical isomerism
- d)It shows geometrical isomerism
Correct answer is option 'B,C,D'. Can you explain this answer?
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Most Upvoted Answer
Which of the following is correct about Tetraamminedithiocyanato-s co...
Formula of the complex [CoIII (SCN)2(NH3)4]3[CoIII(ox)3]
Linkage isomerism is due to presence of SCN- .
Ring closure due to (ox)2- Bideutate ligand.
optical isomerism is exhibited due to presence of [Co(ox)3]-3 complex ion, which has asymmetric structure.
Geometrical isomerism is exhibited due to cationic part :
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Which of the following is correct about Tetraamminedithiocyanato-s co...
Complex Name: Tetraamminedithiocyanato-s cobalt (III) tris (oxalato) cobaltate (III)
Formula of the complex: [Co(SCN)2(NH3)4][Co(ox)3]
Explanation:
Chelating complex and linkage isomerism:
- The complex contains two different ligands, namely thiocyanate (SCN-) and oxalate (ox2-).
- The thiocyanate ligands can bind to the cobalt ion through the sulfur atom, forming a chelate ring.
- The oxalate ligands can bind to the cobalt ion through one oxygen atom of each oxalate ion.
- This type of complex is known as a chelating complex because it forms a cyclic structure with the central metal ion.
- The complex can exhibit linkage isomerism because the thiocyanate ligand can attach to the cobalt ion through either the sulfur or nitrogen atom.
Optical isomerism:
- The complex does not contain any chiral centers, so it does not show optical isomerism.
- Optical isomerism occurs when a complex contains chiral ligands or has a chiral arrangement of ligands around the central metal ion.
Geometrical isomerism:
- The complex can exhibit geometrical isomerism because it contains both cis and trans isomers.
- The oxalate ligands can arrange themselves in a cis or trans configuration with respect to each other.
- The cis isomer refers to the arrangement where the two oxalate ligands are adjacent to each other, while the trans isomer refers to the arrangement where the two oxalate ligands are opposite to each other.
Summary:
- The formula of the complex is [Co(SCN)2(NH3)4][Co(ox)3].
- The complex is a chelating complex and exhibits linkage isomerism, where the thiocyanate ligand can attach to the cobalt ion through either the sulfur or nitrogen atom.
- The complex does not show optical isomerism because it does not contain any chiral centers.
- The complex can exhibit geometrical isomerism due to the arrangement of the oxalate ligands in cis or trans configuration.
Formula of the complex: [Co(SCN)2(NH3)4][Co(ox)3]
Explanation:
Chelating complex and linkage isomerism:
- The complex contains two different ligands, namely thiocyanate (SCN-) and oxalate (ox2-).
- The thiocyanate ligands can bind to the cobalt ion through the sulfur atom, forming a chelate ring.
- The oxalate ligands can bind to the cobalt ion through one oxygen atom of each oxalate ion.
- This type of complex is known as a chelating complex because it forms a cyclic structure with the central metal ion.
- The complex can exhibit linkage isomerism because the thiocyanate ligand can attach to the cobalt ion through either the sulfur or nitrogen atom.
Optical isomerism:
- The complex does not contain any chiral centers, so it does not show optical isomerism.
- Optical isomerism occurs when a complex contains chiral ligands or has a chiral arrangement of ligands around the central metal ion.
Geometrical isomerism:
- The complex can exhibit geometrical isomerism because it contains both cis and trans isomers.
- The oxalate ligands can arrange themselves in a cis or trans configuration with respect to each other.
- The cis isomer refers to the arrangement where the two oxalate ligands are adjacent to each other, while the trans isomer refers to the arrangement where the two oxalate ligands are opposite to each other.
Summary:
- The formula of the complex is [Co(SCN)2(NH3)4][Co(ox)3].
- The complex is a chelating complex and exhibits linkage isomerism, where the thiocyanate ligand can attach to the cobalt ion through either the sulfur or nitrogen atom.
- The complex does not show optical isomerism because it does not contain any chiral centers.
- The complex can exhibit geometrical isomerism due to the arrangement of the oxalate ligands in cis or trans configuration.
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Which of the following is correct about Tetraamminedithiocyanato-s cobalt (III) tris (oxalato) cobaltate (III) ?a)Formula of the complex is [Co(SCN)2(NH3)4][Co(ox)3]b)It is a chelating complex and show linkage isomerismc)It shows optical isomerismd)It shows geometrical isomerismCorrect answer is option 'B,C,D'. Can you explain this answer?
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Which of the following is correct about Tetraamminedithiocyanato-s cobalt (III) tris (oxalato) cobaltate (III) ?a)Formula of the complex is [Co(SCN)2(NH3)4][Co(ox)3]b)It is a chelating complex and show linkage isomerismc)It shows optical isomerismd)It shows geometrical isomerismCorrect answer is option 'B,C,D'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about Which of the following is correct about Tetraamminedithiocyanato-s cobalt (III) tris (oxalato) cobaltate (III) ?a)Formula of the complex is [Co(SCN)2(NH3)4][Co(ox)3]b)It is a chelating complex and show linkage isomerismc)It shows optical isomerismd)It shows geometrical isomerismCorrect answer is option 'B,C,D'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Which of the following is correct about Tetraamminedithiocyanato-s cobalt (III) tris (oxalato) cobaltate (III) ?a)Formula of the complex is [Co(SCN)2(NH3)4][Co(ox)3]b)It is a chelating complex and show linkage isomerismc)It shows optical isomerismd)It shows geometrical isomerismCorrect answer is option 'B,C,D'. Can you explain this answer?.
Which of the following is correct about Tetraamminedithiocyanato-s cobalt (III) tris (oxalato) cobaltate (III) ?a)Formula of the complex is [Co(SCN)2(NH3)4][Co(ox)3]b)It is a chelating complex and show linkage isomerismc)It shows optical isomerismd)It shows geometrical isomerismCorrect answer is option 'B,C,D'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about Which of the following is correct about Tetraamminedithiocyanato-s cobalt (III) tris (oxalato) cobaltate (III) ?a)Formula of the complex is [Co(SCN)2(NH3)4][Co(ox)3]b)It is a chelating complex and show linkage isomerismc)It shows optical isomerismd)It shows geometrical isomerismCorrect answer is option 'B,C,D'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Which of the following is correct about Tetraamminedithiocyanato-s cobalt (III) tris (oxalato) cobaltate (III) ?a)Formula of the complex is [Co(SCN)2(NH3)4][Co(ox)3]b)It is a chelating complex and show linkage isomerismc)It shows optical isomerismd)It shows geometrical isomerismCorrect answer is option 'B,C,D'. Can you explain this answer?.
Solutions for Which of the following is correct about Tetraamminedithiocyanato-s cobalt (III) tris (oxalato) cobaltate (III) ?a)Formula of the complex is [Co(SCN)2(NH3)4][Co(ox)3]b)It is a chelating complex and show linkage isomerismc)It shows optical isomerismd)It shows geometrical isomerismCorrect answer is option 'B,C,D'. Can you explain this answer? in English & in Hindi are available as part of our courses for JEE.
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Which of the following is correct about Tetraamminedithiocyanato-s cobalt (III) tris (oxalato) cobaltate (III) ?a)Formula of the complex is [Co(SCN)2(NH3)4][Co(ox)3]b)It is a chelating complex and show linkage isomerismc)It shows optical isomerismd)It shows geometrical isomerismCorrect answer is option 'B,C,D'. Can you explain this answer?, a detailed solution for Which of the following is correct about Tetraamminedithiocyanato-s cobalt (III) tris (oxalato) cobaltate (III) ?a)Formula of the complex is [Co(SCN)2(NH3)4][Co(ox)3]b)It is a chelating complex and show linkage isomerismc)It shows optical isomerismd)It shows geometrical isomerismCorrect answer is option 'B,C,D'. Can you explain this answer? has been provided alongside types of Which of the following is correct about Tetraamminedithiocyanato-s cobalt (III) tris (oxalato) cobaltate (III) ?a)Formula of the complex is [Co(SCN)2(NH3)4][Co(ox)3]b)It is a chelating complex and show linkage isomerismc)It shows optical isomerismd)It shows geometrical isomerismCorrect answer is option 'B,C,D'. Can you explain this answer? theory, EduRev gives you an
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