Which among the following best describes Photocatalyst?a)A substance t...
Researchers at IISER Bhopal recently developed a new photocatalyst called UC-POP-Au, which absorbs the entire spectrum of light, making it a potent catalyst for chemical processes.
About Photocatalyst:
- The term photocatalyst is a combination of two words: photo, related to photon, and catalyst, which is a substance altering the reaction rate in its presence.
- Therefore, photocatalysts are materials that change the rate of a chemical reaction upon exposure to light. This phenomenon is known as photocatalysis.
- The illumination of the catalyst causes the generation of free charges (electrons and holes) that can participate in chemical reactions, altering the reaction rate.
- Photocatalysis includes reactions that take place by utilizing light and a semiconductor. All the photocatalysts are basically semiconductors.
- There are various materials that show photocatalytic capability, and titanium dioxide (TiO2) is said to be the most effective.
- The photocatalytic reactions can be categorized into two types based on the appearance of the physical state of the reactants.
- Homogeneous photocatalysis: When both the semiconductor and reactant are in the same phase, i.e. gas, solid, or liquid.
- Heterogeneous photocatalysis: When both the semiconductor and reactant are in different phases.
- It is valuable for applications like air and water purification, self-cleaning surfaces, and even in some aspects of solar energy conversion.
Hence option c is the correct answer.
Which among the following best describes Photocatalyst?a)A substance t...
Photocatalyst is a substance that changes the rate of a chemical reaction upon exposure to light. It is an important field of study in chemistry and materials science. Let's understand the concept of photocatalysis and its significance in various applications.
Photocatalysis:
Photocatalysis is a process in which a substance, known as a photocatalyst, is used to accelerate a chemical reaction by absorbing light energy. When a photocatalyst absorbs photons of light, it undergoes a photoexcitation process, leading to the generation of electron-hole pairs. These excited charge carriers can then participate in various chemical reactions, either directly with reactants or through the formation of reactive species.
Key points:
- Photocatalysts are typically semiconductors, such as titanium dioxide (TiO2) and zinc oxide (ZnO). These materials possess a bandgap, which allows them to absorb specific wavelengths of light and create electron-hole pairs.
- The excited electrons and holes can participate in redox reactions and transfer their energy to reactant molecules, thus promoting chemical transformations.
- Photocatalysis is often used in environmental applications, such as air and water purification, where the photocatalyst can degrade pollutants and harmful substances.
- It is also employed in energy conversion processes, such as solar cells and artificial photosynthesis, where the photocatalyst plays a crucial role in capturing and converting solar energy into useful forms.
- The efficiency of a photocatalyst depends on factors like its bandgap energy, surface area, and catalytic activity.
Significance of Photocatalysis:
1. Environmental Remediation:
Photocatalysts can be used to remove organic pollutants, volatile organic compounds (VOCs), and even toxic heavy metals from air and water. The photocatalytic reactions can break down these pollutants into harmless substances.
2. Solar Energy Conversion:
Photocatalysts are utilized in solar cells and solar fuel production. They can absorb sunlight and convert it into electricity or store it in the form of chemical fuels like hydrogen or hydrocarbons.
3. Self-Cleaning Surfaces:
Photocatalytic coatings are used on surfaces like glass and ceramics to create a self-cleaning effect. These coatings can break down organic matter, preventing the accumulation of dirt and grime.
4. Antibacterial Applications:
Certain photocatalysts, like titanium dioxide, have antibacterial properties. They can kill bacteria and other microorganisms when exposed to light, making them useful in medical devices, water treatment, and sterilization.
Conclusion:
Photocatalysts are substances that change the rate of a chemical reaction upon exposure to light. They find wide-ranging applications in environmental remediation, solar energy conversion, self-cleaning surfaces, and antibacterial applications. The ability of photocatalysts to utilize light energy for chemical transformations has immense potential for sustainable technologies and addressing global challenges.
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