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For a gaseous reaction, A(g)+3B(g)?3C(g)+3D(g), ?deltaE is 17 kcal at 270C. Assuming R=2 cal K-1 mol-, the value of ?deltaH for the above reaction?
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For a gaseous reaction, A(g)+3B(g)?3C(g)+3D(g), ?deltaE is 17 kcal at ...
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For a gaseous reaction, A(g)+3B(g)?3C(g)+3D(g), ?deltaE is 17 kcal at ...
Explanation:

The enthalpy change (ΔH) for a reaction can be calculated using the equation:

ΔH = ΔE + ΔnRT

Where:
ΔH = change in enthalpy
ΔE = change in internal energy
Δn = change in the number of moles of gas
R = ideal gas constant
T = temperature in Kelvin

Given:
ΔE = 17 kcal
R = 2 cal K-1 mol-1
T = 270°C = 543 K

We need to determine the value of ΔH for the reaction A(g) + 3B(g) → 3C(g) + 3D(g).

Step 1: Calculate Δn
Δn = (sum of moles of products) - (sum of moles of reactants)
= (3+3) - (1+3)
= 2 moles

Step 2: Convert ΔE to cal
1 kcal = 1000 cal
ΔE = 17 kcal = 17,000 cal

Step 3: Calculate ΔH
ΔH = ΔE + ΔnRT
= 17,000 cal + (2 mol)(2 cal K-1 mol-1)(543 K)
= 17,000 cal + 2,172 cal
= 19,172 cal

Therefore, the value of ΔH for the reaction is 19,172 cal.

Summary:
- The enthalpy change (ΔH) for a reaction can be calculated using the equation ΔH = ΔE + ΔnRT.
- Δn is the change in the number of moles of gas.
- Given the values of ΔE, R, and T, we can calculate ΔH.
- In this case, ΔE is given as 17 kcal, R is 2 cal K-1 mol-1, and T is 270°C (543 K).
- We calculate Δn to be 2 moles.
- Converting ΔE to cal, we get 17,000 cal.
- Plugging the values into the equation, we find ΔH to be 19,172 cal.
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For a gaseous reaction, A(g)+3B(g)?3C(g)+3D(g), ?deltaE is 17 kcal at 270C. Assuming R=2 cal K-1 mol-, the value of ?deltaH for the above reaction?
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