CATION
A cation is an atom which has lost one or more electrons. This gives a net positive charge to the cation, since the protons that are positively charged outnumber the electrons.
A cation is smaller in size than its respective atom, since the loss of an electron decreases the repulsive power of the electrons. This in turn enables the protons to attract the electrons towards the nucleus, thereby reducing the radius of the cation.
It is represented using the '+' sign. For instance, the cation Na+ indicates that it has one electron less than the protons. Similarly, a cation with +4 charge has four electrons less than the total number of protons.
Cations get attracted towards the cathode (negative electrode) during electrolysis.
They are usually formed by metals through endothermic reactions.
Example of the formation of a hydrogen cation from a hydrogen atom:
H - e- ➞ H^+
ANION
An anion is an atom which has gained one or more electrons. This gives a net negative charge to the anion, since the electrons that are negatively charged are high in number as compared to the protons.
An anion is larger than its respective atom, since the addition of electrons in the outermost orbit increases the electron-electron repulsion, which pushes the electrons further apart, thereby increasing the radius of the anion.
It is represented using the '-' sign. For instance, the anion Cl- indicates that it has one electron more than the protons. Similarly, an anion with -2 charge has two electrons more than the total number of protons.
It gets attracted towards the anode (positive electrode) during electrolysis.
Anions are usually formed by non-metals through exothermic reactions.
Example of the formation of an iodide anion from an iodine atom:
I + e- ➞ I^-