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The coordination number of Al in crystalline AICl3 and liquid AICI3, respectively, is :
  • a)
    4 and 4
  • b)
    6 and 6
  • c)
    6 and 4
  • d)
    3 and 6
Correct answer is option 'C'. Can you explain this answer?
Verified Answer
The coordination number of Al in crystalline AICl3 and liquid AICI3, r...
From above image it is clear that one Aluminium ion is surrounded by six chloride ions. Here Al3+ ions are occupying octahedral voids and Cl- ions forms a space lattice.
So the CN of Al in AlCl3 is 6 AND 4
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The coordination number of Al in crystalline AICl3 and liquid AICI3, r...
Coordination number of Al in AICl3 and liquid AICI3

Definition: Coordination number is defined as the number of atoms, ions or molecules that surround a central atom or ion in a crystal or molecule.

Coordination number of Al in AICl3: The formula of AICl3 suggests that each Al atom is surrounded by six Cl atoms. Therefore, the coordination number of Al in AICl3 is 6.

Coordination number of Al in liquid AICI3: In the liquid state, AICI3 exists as a dimer (Al2Cl6). Each Al atom in Al2Cl6 is surrounded by four Cl atoms. Therefore, the coordination number of Al in liquid AICI3 is 4.

Conclusion: The coordination number of Al in crystalline AICl3 and liquid AICI3, respectively, is 6 and 4. Therefore, option C is the correct answer.
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The coordination number of Al in crystalline AICl3 and liquid AICI3, respectively, is :a)4 and 4b)6 and 6c)6 and 4d)3 and 6Correct answer is option 'C'. Can you explain this answer?
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