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Direction (Q. No. 22 - 25) This section contains 4 questions. When worked out will result in an integer from 0 to 9 (both inclusive).


Q. C6H4Br2(P) is a dibromo benzene and it is the less polar isomer of its two polar isomers. If P is treated with conc. HNO3 and conc -H2SO4 mixture, in principle, how many mono nitration products are expected?

Correct answer is '2'. Can you explain this answer?
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Direction (Q. No. 22 - 25) This section contains 4 questions. When wor...
Explanation:


When C6H4Br2(P) is treated with a mixture of concentrated HNO3 and concentrated H2SO4, it undergoes nitration. Mono nitration products are expected from this reaction.




Reasoning:

  • The presence of two bromine atoms in C6H4Br2(P) makes it less polar than its two polar isomers (ortho and para).

  • When C6H4Br2(P) is treated with a mixture of concentrated HNO3 and concentrated H2SO4, it undergoes nitration.

  • Because of the less polar nature of C6H4Br2(P), it is expected to react with nitric acid to form three mononitration products.

  • The three possible mononitration products are:

    • 2-nitro-1-bromobenzene

    • 4-nitro-1-bromobenzene

    • 2,4-dinitro-1-bromobenzene




Therefore, when C6H4Br2(P) is treated with a mixture of concentrated HNO3 and concentrated H2SO4, three mononitration products are expected.
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Direction (Q. No. 22 - 25) This section contains 4 questions. When wor...
Understanding the Compound

- The compound C6H4Br2(P) is a dibromo benzene. This means it has two bromine atoms attached to the benzene ring.

Understanding Isomerism

- The less polar isomer refers to the geometric arrangement of the bromine atoms on the benzene ring that results in less polarity.
- In the case of dibromo benzene, there are three possible geometric arrangements (ortho, meta, and para) but only ortho-dibromo benzene and para-dibromo benzene are polar. The less polar of the two is the para isomer.

Nitration Reaction

- Nitration is a general class of a chemical process for the introduction of a nitro group into an organic chemical compound.
- The nitration of benzene involves substitution of a hydrogen atom by a nitro group (-NO2) and this is facilitated by a mixture of concentrated nitric acid (HNO3) and sulfuric acid (H2SO4).

Mono Nitration Products

- Considering that the compound is para-dibromo benzene, the nitration can occur at any of the 4 remaining carbon atoms in the benzene ring.
- However, since the question asks for mono nitration products (meaning only one nitro group is added), the number of unique products will depend on the symmetry of the molecule.
- For para-dibromo benzene, the molecule is symmetric. Nitration at any of the 4 remaining positions will result in only 2 unique mono-nitration products due to this symmetry.

So, the answer is 2.
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Direction (Q. No. 22 - 25) This section contains 4 questions. When worked out will result in an integer from 0 to 9 (both inclusive).Q.C6H4Br2(P) is a dibromo benzene and it is the less polar isomer of its two polar isomers. If P is treated with conc. HNO3 and conc -H2SO4 mixture, in principle, how many mono nitration products are expected?Correct answer is '2'. Can you explain this answer?
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