Page 1
1. (c) The species CO, NO
+
, CN
–
and C
2
? 2–
contain 14 electrons each.
2. (d) NaCl : No. of e
–
in Na
+
= At. No. of Na–1
= 11 – 1 = 10
No. e
–
in Cl
–
= At. No. of Cl + 1
= 17 + 1 = 18
CsF : No. of e
–
in Cs
+
= 55 – 1 = 54
No. of e
–
in F
–
= 9 + 1 = 10
NaI : No. of e
–
in Na
+
= 11 – 1 = 10
No. of e
–
in I
–
= 53 + 1 = 54
K
2
S : No. of e
–
in K
+
= 19 – 1 = 18
No. of e
–
in S
2–
= 16 + 2 = 18
3. (a) For He
+
,
For H,
For same frequency,
=
?
? n
1
= 1 & n
2
= 2
4. (c) Series limit is the last line of the series, i.e. n
2
= 8.
Page 2
1. (c) The species CO, NO
+
, CN
–
and C
2
? 2–
contain 14 electrons each.
2. (d) NaCl : No. of e
–
in Na
+
= At. No. of Na–1
= 11 – 1 = 10
No. e
–
in Cl
–
= At. No. of Cl + 1
= 17 + 1 = 18
CsF : No. of e
–
in Cs
+
= 55 – 1 = 54
No. of e
–
in F
–
= 9 + 1 = 10
NaI : No. of e
–
in Na
+
= 11 – 1 = 10
No. of e
–
in I
–
= 53 + 1 = 54
K
2
S : No. of e
–
in K
+
= 19 – 1 = 18
No. of e
–
in S
2–
= 16 + 2 = 18
3. (a) For He
+
,
For H,
For same frequency,
=
?
? n
1
= 1 & n
2
= 2
4. (c) Series limit is the last line of the series, i.e. n
2
= 8.
The line belongs to Paschen series.
5. (d) de Broglie wavelength,
KE
6. (c) Fe (III) = [Ar] unpaired electrons = 5;
Magnetic moment = ;
Ratio =
Co(II) = [Ar] unpaired electrons = 3;
Magnetic moment =
Ratio =
7. (b)
Page 3
1. (c) The species CO, NO
+
, CN
–
and C
2
? 2–
contain 14 electrons each.
2. (d) NaCl : No. of e
–
in Na
+
= At. No. of Na–1
= 11 – 1 = 10
No. e
–
in Cl
–
= At. No. of Cl + 1
= 17 + 1 = 18
CsF : No. of e
–
in Cs
+
= 55 – 1 = 54
No. of e
–
in F
–
= 9 + 1 = 10
NaI : No. of e
–
in Na
+
= 11 – 1 = 10
No. of e
–
in I
–
= 53 + 1 = 54
K
2
S : No. of e
–
in K
+
= 19 – 1 = 18
No. of e
–
in S
2–
= 16 + 2 = 18
3. (a) For He
+
,
For H,
For same frequency,
=
?
? n
1
= 1 & n
2
= 2
4. (c) Series limit is the last line of the series, i.e. n
2
= 8.
The line belongs to Paschen series.
5. (d) de Broglie wavelength,
KE
6. (c) Fe (III) = [Ar] unpaired electrons = 5;
Magnetic moment = ;
Ratio =
Co(II) = [Ar] unpaired electrons = 3;
Magnetic moment =
Ratio =
7. (b)
8. (d)
Hence,
9. (a) We know
since ?p = ?x (given)
?
or m?v [ ? ?p= m?v]
or
or
10. (b) I. E = ...(i)
or ...(ii)
Given I
1
= – 19.6 × 10
–18
, Z
1
= 2,
n
1
= 1 , Z
2
= 3 and n
2
= 1
Substituting these values in equation (ii).
–
or
= – 4.41 × 10
–17
J/atom
11. (c) As per Bohr’s postulate,
mvr =
Page 4
1. (c) The species CO, NO
+
, CN
–
and C
2
? 2–
contain 14 electrons each.
2. (d) NaCl : No. of e
–
in Na
+
= At. No. of Na–1
= 11 – 1 = 10
No. e
–
in Cl
–
= At. No. of Cl + 1
= 17 + 1 = 18
CsF : No. of e
–
in Cs
+
= 55 – 1 = 54
No. of e
–
in F
–
= 9 + 1 = 10
NaI : No. of e
–
in Na
+
= 11 – 1 = 10
No. of e
–
in I
–
= 53 + 1 = 54
K
2
S : No. of e
–
in K
+
= 19 – 1 = 18
No. of e
–
in S
2–
= 16 + 2 = 18
3. (a) For He
+
,
For H,
For same frequency,
=
?
? n
1
= 1 & n
2
= 2
4. (c) Series limit is the last line of the series, i.e. n
2
= 8.
The line belongs to Paschen series.
5. (d) de Broglie wavelength,
KE
6. (c) Fe (III) = [Ar] unpaired electrons = 5;
Magnetic moment = ;
Ratio =
Co(II) = [Ar] unpaired electrons = 3;
Magnetic moment =
Ratio =
7. (b)
8. (d)
Hence,
9. (a) We know
since ?p = ?x (given)
?
or m?v [ ? ?p= m?v]
or
or
10. (b) I. E = ...(i)
or ...(ii)
Given I
1
= – 19.6 × 10
–18
, Z
1
= 2,
n
1
= 1 , Z
2
= 3 and n
2
= 1
Substituting these values in equation (ii).
–
or
= – 4.41 × 10
–17
J/atom
11. (c) As per Bohr’s postulate,
mvr =
So,
KE =
So, KE =
Since,
So, for 2
nd
Bohr orbit
KE =
KE =
12. (c) Not more than two electrons can be present in same atomic orbital.
This is Pauli's exclusion principle.
13. (a) 2
nd
excited state will be the 3
rd
energy level.
or
14. (a)
In Balmer series n
1
= 2 & n
2
= 3, 4, 5.... Last line of the spectrum is
called series limit.
Limiting line is the line of shortest wavelength and high energy when n
2
= 8
15. (c) r
n
= a
0
n
2
Page 5
1. (c) The species CO, NO
+
, CN
–
and C
2
? 2–
contain 14 electrons each.
2. (d) NaCl : No. of e
–
in Na
+
= At. No. of Na–1
= 11 – 1 = 10
No. e
–
in Cl
–
= At. No. of Cl + 1
= 17 + 1 = 18
CsF : No. of e
–
in Cs
+
= 55 – 1 = 54
No. of e
–
in F
–
= 9 + 1 = 10
NaI : No. of e
–
in Na
+
= 11 – 1 = 10
No. of e
–
in I
–
= 53 + 1 = 54
K
2
S : No. of e
–
in K
+
= 19 – 1 = 18
No. of e
–
in S
2–
= 16 + 2 = 18
3. (a) For He
+
,
For H,
For same frequency,
=
?
? n
1
= 1 & n
2
= 2
4. (c) Series limit is the last line of the series, i.e. n
2
= 8.
The line belongs to Paschen series.
5. (d) de Broglie wavelength,
KE
6. (c) Fe (III) = [Ar] unpaired electrons = 5;
Magnetic moment = ;
Ratio =
Co(II) = [Ar] unpaired electrons = 3;
Magnetic moment =
Ratio =
7. (b)
8. (d)
Hence,
9. (a) We know
since ?p = ?x (given)
?
or m?v [ ? ?p= m?v]
or
or
10. (b) I. E = ...(i)
or ...(ii)
Given I
1
= – 19.6 × 10
–18
, Z
1
= 2,
n
1
= 1 , Z
2
= 3 and n
2
= 1
Substituting these values in equation (ii).
–
or
= – 4.41 × 10
–17
J/atom
11. (c) As per Bohr’s postulate,
mvr =
So,
KE =
So, KE =
Since,
So, for 2
nd
Bohr orbit
KE =
KE =
12. (c) Not more than two electrons can be present in same atomic orbital.
This is Pauli's exclusion principle.
13. (a) 2
nd
excited state will be the 3
rd
energy level.
or
14. (a)
In Balmer series n
1
= 2 & n
2
= 3, 4, 5.... Last line of the spectrum is
called series limit.
Limiting line is the line of shortest wavelength and high energy when n
2
= 8
15. (c) r
n
= a
0
n
2
r = a
0
× (3)
2
= 9a
0
16. (c) l = 2 represent d orbital for which
17. (b) de – Broglie wavelength is given by :
... (i)
K.E.
Substituting this in equation (i)
...(i)
i.e.
? when KE become 4 times wavelength become 1/2.
18. (a) The electronic configuration of Rubidium (Rb = 37) is
Since last electron enters in 5s orbital
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