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Page 1 PART-I (Single Correct MCQs) 1. Among the following groupings which represents the collection of isoelectronic species? (a) (b) (c) (d) 2. The compound in which cation is isoelectronic with anion is : (a) NaCl (b) CsF (c) NaI (d) K 2 S Page 2 PART-I (Single Correct MCQs) 1. Among the following groupings which represents the collection of isoelectronic species? (a) (b) (c) (d) 2. The compound in which cation is isoelectronic with anion is : (a) NaCl (b) CsF (c) NaI (d) K 2 S 3. The frequency of light emitted for the transition n = 4 to n = 2 of the He + is equal to the transition in H atom corresponding to which of the following ? (a) n = 2 to n = 1 (b) n = 3 to n = 2 (c) n = 4 to n = 3 (d) n = 3 to n = 1 4. In hydrogen atomic spectrum, a series limit is found at 12186.3 cm –1 . Then it belong to (a) Lyman series (b) Balmer series (c) Paschen series (d) Brackett series 5. Two fast moving particles X and Y are associated with de Broglie wavelengths 1 nm and 4 nm respectively. If mass of X is nine times the mass of Y, the ratio of kinetic energies of X and Y would be (a) 3 : 1 (b) 9 : 1 (c) 5 : 12 (d) 16 : 9 6. The ratio of magnetic moments of Fe(III) and Co(II) is (a) 7 : 3 (b) 3 : 7 (c) : Page 3 PART-I (Single Correct MCQs) 1. Among the following groupings which represents the collection of isoelectronic species? (a) (b) (c) (d) 2. The compound in which cation is isoelectronic with anion is : (a) NaCl (b) CsF (c) NaI (d) K 2 S 3. The frequency of light emitted for the transition n = 4 to n = 2 of the He + is equal to the transition in H atom corresponding to which of the following ? (a) n = 2 to n = 1 (b) n = 3 to n = 2 (c) n = 4 to n = 3 (d) n = 3 to n = 1 4. In hydrogen atomic spectrum, a series limit is found at 12186.3 cm –1 . Then it belong to (a) Lyman series (b) Balmer series (c) Paschen series (d) Brackett series 5. Two fast moving particles X and Y are associated with de Broglie wavelengths 1 nm and 4 nm respectively. If mass of X is nine times the mass of Y, the ratio of kinetic energies of X and Y would be (a) 3 : 1 (b) 9 : 1 (c) 5 : 12 (d) 16 : 9 6. The ratio of magnetic moments of Fe(III) and Co(II) is (a) 7 : 3 (b) 3 : 7 (c) : (d) : 7. The values of Planck’s constant is 6.63 × 10 –34 Js. The velocity of light is 3.0 × 10 8 m s –1 . Which value is closest to the wavelength in nanometres of a quantum of light with frequency of 8 × 10 15 s –1 ? (a) 5 × 10 –18 (b) 4 × 10 1 (c) 3 × 10 7 (d) 2 × 10 –25 8. Li and a proton are accelerated by the same potential, their de Broglie wavelengths ? Li and ? p have the ratio (assume m Li = 9m p ) (a) 1 : 2 (b) 1 : 4 (c) 1 : 1 (d) 9. If uncertainty in position and momentum are equal, then uncertainty in velocity is : (a) (b) (c) (d) 10. Ionisation energy of He + is 19.6 × 10 –18 J atom –1 . The energy of the first stationary state (n = 1) of Li 2+ is Page 4 PART-I (Single Correct MCQs) 1. Among the following groupings which represents the collection of isoelectronic species? (a) (b) (c) (d) 2. The compound in which cation is isoelectronic with anion is : (a) NaCl (b) CsF (c) NaI (d) K 2 S 3. The frequency of light emitted for the transition n = 4 to n = 2 of the He + is equal to the transition in H atom corresponding to which of the following ? (a) n = 2 to n = 1 (b) n = 3 to n = 2 (c) n = 4 to n = 3 (d) n = 3 to n = 1 4. In hydrogen atomic spectrum, a series limit is found at 12186.3 cm –1 . Then it belong to (a) Lyman series (b) Balmer series (c) Paschen series (d) Brackett series 5. Two fast moving particles X and Y are associated with de Broglie wavelengths 1 nm and 4 nm respectively. If mass of X is nine times the mass of Y, the ratio of kinetic energies of X and Y would be (a) 3 : 1 (b) 9 : 1 (c) 5 : 12 (d) 16 : 9 6. The ratio of magnetic moments of Fe(III) and Co(II) is (a) 7 : 3 (b) 3 : 7 (c) : (d) : 7. The values of Planck’s constant is 6.63 × 10 –34 Js. The velocity of light is 3.0 × 10 8 m s –1 . Which value is closest to the wavelength in nanometres of a quantum of light with frequency of 8 × 10 15 s –1 ? (a) 5 × 10 –18 (b) 4 × 10 1 (c) 3 × 10 7 (d) 2 × 10 –25 8. Li and a proton are accelerated by the same potential, their de Broglie wavelengths ? Li and ? p have the ratio (assume m Li = 9m p ) (a) 1 : 2 (b) 1 : 4 (c) 1 : 1 (d) 9. If uncertainty in position and momentum are equal, then uncertainty in velocity is : (a) (b) (c) (d) 10. Ionisation energy of He + is 19.6 × 10 –18 J atom –1 . The energy of the first stationary state (n = 1) of Li 2+ is (a) 4.41 × 10 –16 J atom –1 (b) –4.41 × 10 –17 J atom –1 (c) –2.2 × 10 –15 J atom –1 (d) 8.82 × 10 –17 J atom –1 11. The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is [a 0 is Bohr radius] : (a) (b) (c) (d) 12. If the nitrogen atom had electronic configuration 1s 7 it would have energy lower than that of the normal ground state configuration 1s 2 2s 2 2p 3 because the electrons would be closer to the nucleus. Yet 1s 7 is not observed. It violates (a) Heisenberg’s uncertainty principle (b) Hund’s rule (c) Pauli exclusion principle (d) Bohr postulate of stationary orbits 13. In a hydrogen atom, if energy of an electron in ground state is 13.6. ev, then that in the 2 nd excited state is (a) 1.51 eV (b) 3.4 eV (c) 6.04 eV Page 5 PART-I (Single Correct MCQs) 1. Among the following groupings which represents the collection of isoelectronic species? (a) (b) (c) (d) 2. The compound in which cation is isoelectronic with anion is : (a) NaCl (b) CsF (c) NaI (d) K 2 S 3. The frequency of light emitted for the transition n = 4 to n = 2 of the He + is equal to the transition in H atom corresponding to which of the following ? (a) n = 2 to n = 1 (b) n = 3 to n = 2 (c) n = 4 to n = 3 (d) n = 3 to n = 1 4. In hydrogen atomic spectrum, a series limit is found at 12186.3 cm –1 . Then it belong to (a) Lyman series (b) Balmer series (c) Paschen series (d) Brackett series 5. Two fast moving particles X and Y are associated with de Broglie wavelengths 1 nm and 4 nm respectively. If mass of X is nine times the mass of Y, the ratio of kinetic energies of X and Y would be (a) 3 : 1 (b) 9 : 1 (c) 5 : 12 (d) 16 : 9 6. The ratio of magnetic moments of Fe(III) and Co(II) is (a) 7 : 3 (b) 3 : 7 (c) : (d) : 7. The values of Planck’s constant is 6.63 × 10 –34 Js. The velocity of light is 3.0 × 10 8 m s –1 . Which value is closest to the wavelength in nanometres of a quantum of light with frequency of 8 × 10 15 s –1 ? (a) 5 × 10 –18 (b) 4 × 10 1 (c) 3 × 10 7 (d) 2 × 10 –25 8. Li and a proton are accelerated by the same potential, their de Broglie wavelengths ? Li and ? p have the ratio (assume m Li = 9m p ) (a) 1 : 2 (b) 1 : 4 (c) 1 : 1 (d) 9. If uncertainty in position and momentum are equal, then uncertainty in velocity is : (a) (b) (c) (d) 10. Ionisation energy of He + is 19.6 × 10 –18 J atom –1 . The energy of the first stationary state (n = 1) of Li 2+ is (a) 4.41 × 10 –16 J atom –1 (b) –4.41 × 10 –17 J atom –1 (c) –2.2 × 10 –15 J atom –1 (d) 8.82 × 10 –17 J atom –1 11. The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is [a 0 is Bohr radius] : (a) (b) (c) (d) 12. If the nitrogen atom had electronic configuration 1s 7 it would have energy lower than that of the normal ground state configuration 1s 2 2s 2 2p 3 because the electrons would be closer to the nucleus. Yet 1s 7 is not observed. It violates (a) Heisenberg’s uncertainty principle (b) Hund’s rule (c) Pauli exclusion principle (d) Bohr postulate of stationary orbits 13. In a hydrogen atom, if energy of an electron in ground state is 13.6. ev, then that in the 2 nd excited state is (a) 1.51 eV (b) 3.4 eV (c) 6.04 eV (d) 13.6 eV. 14. The limiting line in Balmer series will have a frequency of (Rydberg constant, R 8 = 3.29 × 10 15 cycles/s) (a) 8.22 × 10 14 s –1 (b) 3.29 × 10 15 s –1 (c) 3.65 × 10 14 s –1 (d) 5.26 × 10 13 s –1 15. If the radius of first orbit of H atom is a 0 , the de-Broglie wavelength of an electron in the third orbit is (a) 4pa 0 (b) 8pa 0 (c) 6pa 0 (d) 2pa 0 16. Which of the following radial distribution graphs correspond to l = 2 for the H atom ? (a) (b) (c)Read More
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