Thermodynamics is a Greek word. Its literal meaning is motion or flow (dynamics) of heat (thermos).
Thermodynamics, science of the relationship between heat, work, temperature, and energy. In broad terms, thermodynamics deals with the transfer of energy from one place to another and from one form to another.
The key concept is that heat is a form of energy corresponding to a definite amount of mechanical work.
Thermodynamics deals with energy interaction b/w two bodies & its effect on the properties of matter.
SCOPE OF THERMODYNAMICS
Efficiency of a process
LIMITATIONS OF THERMODYNAMICS
TERMS USED IN THERMODYNAMICS
System + Boundary + Surrounding = Universe
(i) System: The part of the universe under thermodynamic observation is called system.
(ii) Surroundings: All the part of the universe excepting system is called surroundings.
(iii) Boundary: The part which separates system and surroundings is called boundary it may be rigid or flexible.
Fig: System Thermodynamic
TYPES OF SYSTEMS
(i) Open system: The system which can exchange matter as well as energy with the surroundings.
For example, a liquid kept in an open flask.
(ii) Closed System: A system which can exchange only energy with the surroundings.
For example, a liquid in a closed vessel.
(iii) Isolated System: A system which can neither exchange matter nor energy with the surroundings.
For example, a thermally insulated flask.
STATE OF A SYSTEM
When macroscopic properties of a system have definite values, the system is said to be in definite state. Whenever there is a change in any one of the macroscopic properties, the system is said to change into a different state. Thus, the state of a system is fixed by its macroscopic properties.
State or condition of a system is described by certain measurable properties & these measurable properties are called state variables. State variables or the thermodynamics parameters depends only upon the initial and final states of the system and independent of the manner as to how the change is brought are called state functions. Some common state functions are internal energy, enthalpy, entropy, free energy, pressure, temperature, volume etc.
State function depends only on initial & final state of the system. If does not depend on the path or how process was carried out.
Where ΔU = uf - ui
Solution. The parameters which are required to completely define the state of the system are called state functions.
State functions are path independent function.
Path independent means the difference in state functions will be same for any path followed between two states.
Path Functions: Path function depends on the initial as well as final state of a system & also depends on the path of the process.
Example: heat and work.
EXTENSIVE AND INTENSIVE PROPERTIES
An extensive property of a system is that which depends upon the amount of the substance present in the system.
Example: mass, volume and energy.
An intensive property of a system is that which is independent of the amount of the substance present in the system.
Example: Temperature, pressure, density, concentration, viscosity, surface tension, refractive index etc.
INTENSIVE PROPERTIES VERSUS EXTENSIVE PROPERTIES
How to identify extensive or intensive properties?
If a system in a particular state is divided into two equal or unequal parts, the properties which have value equal to the original value of that property for the whole of the system is called an Intensive property. While the properties which have values different from the values for whole of the system are called extensive properties.
For example: Consider air in a room at temp of 300K, 1 atm pressure. Now, if the room is divided by some boundary( imaginary or real) into two parts( equal or unequal) then in these two parts : The temperature, pressure, density of the gas, concentration of gaseous molecules etc. will have the same value as that of for whole of the system. (intensive) While the volume of two parts, mass of gas in two parts, total energy of the gaseous molecules in the two parts, entropy the two parts etc. will be different from the values of these properties as for the whole of the system initially. (extensive)