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All questions of December Week 1 for NEET Exam

Heterocysts that take part in nitrogen fixation occur in
  • a)
    Nostoc
  • b)
    Polysiphonia
  • c)
    Ulothrix
  • d)
    Fucus
Correct answer is option 'A'. Can you explain this answer?

Mubeena Akhter answered
Heterocysts contain nitrogenase enzyme which helps to carry out nitrogen fixation.Nostoc show symbiotic association with corralloid roots of cycas and carries out nitrogen fixation.

 Phenol is acidic due to resonance stabilization of its conjugate base :
  • a)
    O-H
  • b)
    Benzyl alcohol
  • c)
    Alkoxide ion
  • d)
    Phenoxide ion
Correct answer is option 'D'. Can you explain this answer?

Rishika Patel answered
Polarity of Phenol

Phenol, also known as benzenol or carbolic acid, is an aromatic compound that consists of a benzene ring bonded to a hydroxyl group (-OH). The presence of the hydroxyl group makes phenol a polar molecule because oxygen is more electronegative than carbon and hydrogen.

Acidity of Phenol

Phenol is considered an acid because it can donate a proton (H+) and form a conjugate base. The acidity of phenol is attributed to resonance stabilization of its conjugate base, the phenoxide ion.

Resonance Stabilization of Phenoxide Ion

When phenol loses a proton, it forms the phenoxide ion (C6H5O-). The phenoxide ion is resonance stabilized, which means that the negative charge can be delocalized over the entire ring system through resonance structures.

Resonance Structures of Phenoxide Ion

The resonance structures of the phenoxide ion can be represented as follows:

1. In the first resonance structure, the lone pair on the oxygen atom forms a double bond with carbon, while the negative charge is located on the oxygen atom.

2. In the second resonance structure, the lone pair on the oxygen atom forms a double bond with one of the carbon atoms in the ring, while the negative charge is located on that carbon atom.

3. In the third resonance structure, the lone pair on the oxygen atom forms a double bond with another carbon atom in the ring, while the negative charge is located on that carbon atom.

The resonance structures demonstrate that the negative charge of the phenoxide ion is delocalized over the entire ring system, resulting in stability.

Comparison with Other Options

a) O-H: The O-H bond in phenol is the source of acidity, but it does not explain the resonance stabilization of the conjugate base.

b) Benzyl alcohol: While benzyl alcohol also has an -OH group, it lacks the aromatic ring required for resonance stabilization of the conjugate base.

c) Alkoxide ion: Alkoxide ions are formed when an alcohol loses a proton, but they do not have the same resonance stabilization as the phenoxide ion.

Conclusion

The correct answer is option 'D' (Phenoxide ion) because the resonance stabilization of the phenoxide ion is responsible for the acidity of phenol. The delocalization of the negative charge over the aromatic ring system increases the stability of the conjugate base, making phenol acidic.

 Identify the alcohol or phenol having a stronger acidic nature from the following.
  • a)
    CH3CH2OH
  • b)
    C6H5OH
  • c)
    CH3CHOHCH2CH3
  • d)
    CH3CH2CH2CH2OH
Correct answer is option 'B'. Can you explain this answer?

Mohit Rajpoot answered
- Phenol (C₆H₅OH) is more acidic than typical alcohols.
- This is due to the resonance stabilization of the phenoxide ion formed when phenol loses a hydrogen ion (H⁺).
- The negative charge on the oxygen atom in phenoxide ion is delocalized over the aromatic ring, increasing stability and acidity.
- In contrast, alcohols like ethanol (CH₃CH₂OH) do not have such resonance stabilization, making them less acidic.
- Therefore, phenol is the strongest acid among the given options.

Can you explain the answer of this question below:

The acidity of phenols is due to

  • A:

    Oxidation process

  • B:

    Resonance stabilization of its ions.

  • C:

    Hybridisation

  • D:

    Presence of O-H group

The answer is b.

Rahul Bansal answered
The acidity of phenols is due to its ability to lose hydrogen ion to form phenoxide ions. In a phenol molecule, the sp2hybridised carbon atom of benzene ring attached directly to the hydroxyl group acts as an electron withdrawing group. This sp2 hybridized carbon atom of benzene ring attached directly to the hydroxyl group has higher electronegativity in comparison to hydroxyl group. Due to the higher electronegativity of this carbon atom in comparison to the hydroxyl group attached, electron density decreases on oxygen atom. The decrease in electron density increases the polarity of O-H bond and results in the increase in ionization of phenols. Thus, the phenoxide ion is formed. The phenoxide ion formed is stabilized by the delocalization of negative charge due to the resonance in benzene ring. Phenoxide ion has greater stability than phenols, as in case of phenol charge separation takes place during resonance.The resonance structures of phenoxide ions explain the delocalization of negative charge. In case of substituted phenols, acidity of phenols increases in the presence of electron withdrawing group. This is due to the stability of the phenoxide ion generated. The acidity of phenols further increases if these groups are attached at ortho and para positions. This is due to the fact that the negative charge in phenoxide ion is mainly delocalized at ortho and para positions of the attached benzene ring. On the other hand, the acidity of phenols decreases in presence of electron donating groups as they prohibit the formation of phenoxide ion.

 We can obtain picric acid from phenol by:
  • a)
    Sulphonation of phenol
  • b)
    By Reimer Tiemann reaction
  • c)
    Nitration of phenol
  • d)
    Halogenation of phenol
Correct answer is option 'C'. Can you explain this answer?

Shreya Gupta answered
Phenol heated with sulphuric acid gives phenol disulphonic acid, which further on reaction with nitric acid forms picric acid (2,4,6-trinitrophenol).

IUPAC name of m-cresol is ___________.
  • a)
    3-methylphenol
  • b)
    3-chlorophenol
  • c)
     3-methoxyphenol
  • d)
    benzene-1,3-diol
Correct answer is option 'A'. Can you explain this answer?

Preeti Iyer answered
Meta-Cresol, also 3-methylphenol, is an organic compound with the formula CH3C6H4(OH). It is a colourless, viscous liquid that is used as an intermediate in the production of other chemicals. It is a derivative of phenol and is an isomer of p-cresol and o-cresol.

The residue left after methane production from cattle dung is
  • a)
    Used as manure
  • b)
    Buried in landfills
  • c)
    Used in civil construction
  • d)
    Burnt
Correct answer is option 'A'. Can you explain this answer?

Vijay Bansal answered
The raw material for biogas production is excreta (dung) of cattle. The biogas plant consists of a concrete tank (10-15 feet deep) in which bio-wastes are collected and slurry of dung is fed. A floating cover is placed over the slurry, which keeps on rising as the gas is produced in the tank due to the microbial activity. Methano bacterium in the dung act on the bio-wastes to produce bio-gas. The gas produced is supplied to nearby houses by an outlet. Through another outlet, the spent slurry is removed to be used as manure. 

A convergent lens made of crown glass (refractive index 1.5) has focal length 20cm in air. If it is immersed in a liquid of refractive index 1.60, its focal length will be:​
  • a)
    100cm
  • b)
    160cm
  • c)
    -80cm
  • d)
    -160cm
Correct answer is option 'D'. Can you explain this answer?

Mira Sharma answered
When the lens is in air, we have (from lens maker's equation), 1/20 = [(1.5/1) - 1) (1/R1- 1/R2). 
We are not bothered about the signs of R1 and R2 since they are unknown quantities. 
Even though we know that the convergent lens will become divergent in the denser medium, we write lens maker's equation without bothering about the sign of its unknown focal length in the liquid. If if is the focal length in the liquid, we can write, 
1/f = ((1.5/1.6) - 1) (1/R1 - 1/R2). 
Dividing the first equation by the second, we obtain f/20 = 0.5x1.6/(-0.1) from which f = -160 cm 

If two thin lenses of power p1 and p2 are held in contact then the power of the combination will be​
  • a)
    p1 +p2
  • b)
    p12 +p22
  • c)
    p1 -p2
  • d)
    (p1 +p2)1/2
Correct answer is option 'A'. Can you explain this answer?

Explanation:
When two thin lenses of power p1 and p2 are held in contact, the power of the combination can be calculated using the lens formula:

1/f = 1/f1 + 1/f2

where f is the focal length of the combination lens, f1 is the focal length of the first lens, and f2 is the focal length of the second lens.

Using the relation p = 1/f, we get:

p = p1 + p2

This means that the power of the combination lens is equal to the sum of the powers of the individual lenses.

Therefore, the correct option is 'A' i.e. p1p2.

Summary:
When two thin lenses are held in contact, the power of the combination is equal to the sum of the powers of the individual lenses.

One of the constituents of baking powder is sodium hydrogencarbonate, the other constituent is
  • a)
    hydrochloric acid
  • b)
    tartaric acid
  • c)
    acetic acid
  • d)
    sulphuric acid
Correct answer is option 'B'. Can you explain this answer?

Vijay Bansal answered
(b) Baking powder is a mixture of baking soda NaHCO3,(sodium hydrogen carbonate)and a mild edible acid such as tartaric acid. When baking powder mixes with water (form a king cake or bread), sodium hydrogen carbonate reacts with tartaric acid to evolve carbon dioxide gas. 

Select the correct group of biocontrol agents:
  • a)
    Nostoc, Azospirillum, Nucleopolyhedrovirus
  • b)
    Bacillus thuringiensis, Tobacco mosaic virus, Aphids
  • c)
    Trichoderma, Baculovirus, Bacillus thuringiensis
  • d)
    Oscillatoria, Rhizobium, Trichoderma
Correct answer is option 'C'. Can you explain this answer?

Lead Academy answered
Biocontrol agents are organisms used to control pests or pathogens biologically.
Trichoderma is a fungus used against plant pathogens.
Baculovirus (like Nucleopolyhedrovirus) is used to target insect pests.
Bacillus thuringiensis is a bacterium producing toxins effective against insects.
Hence, Option C correctly lists known biocontrol agents.

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