All questions of Availability & Irreversibility for Mechanical Engineering Exam

The maximum theoretical work obtainable, when a system interacts to equilibrium with a reference environment, is called
  • a)
    Entropy
  • b)
    Enthalpy
  • c)
    Exergy
  • d)
    Rothalpy
Correct answer is option 'C'. Can you explain this answer?

Sanvi Kapoor answered
Exergy (or) Available Energy :
The maximum portion of energy which could be converted into useful work by ideal processes which reduce the system to dead state (a state in equilibrium with the earth and its atmosphere).

 Which of the following thermodynamic relation is Keenan function?
  • a)
    U + P V
  • b)
    H - T0 S
  • c)
    E - T0S
  • d)
    U - T0S
Correct answer is option 'B'. Can you explain this answer?

Explanation:

- The Keenan function is given by the thermodynamic relation: H - T0 S
- This equation represents the enthalpy (H) minus the product of the temperature (T0) and the entropy (S)
- The Keenan function is often used in thermodynamics to analyze and calculate the energy changes in a system
- It is a useful tool for studying the relationships between heat, work, and energy transfer in various processes.

In which one of the following processes is there an increase in entropy with no degradation of energy
  • a)
    Polytropic expansion
  • b)
    Isothermal expansion
  • c)
    Isochoric heat addition
  • d)
    Isobaric heat addition
Correct answer is option 'B'. Can you explain this answer?

Anshu Patel answered
Explanation:

Entropy is a thermodynamic property that measures the degree of disorder or randomness of a system. The second law of thermodynamics states that the entropy of an isolated system always increases over time, or at best remains constant.

Entropy and Energy Degradation:

The term "energy degradation" refers to the process by which energy is converted from a more usable form to a less usable form, such as from mechanical energy to heat energy. This process always results in an increase in entropy. Therefore, any process that involves energy degradation will also involve an increase in entropy.

Isothermal Expansion:

Isothermal expansion is a process in which a gas expands at a constant temperature. During this process, the gas does work on its surroundings, but there is no energy degradation. The reason for this is that the work done by the gas is reversible, meaning that it could be undone without any loss of energy.

In contrast, a polytropic expansion involves a change in temperature, which means that energy is being added or removed from the system. This process always results in an increase in entropy. Similarly, isochoric heat addition and isobaric heat addition involve energy being added to the system, which also leads to an increase in entropy.

Conclusion:

In conclusion, the only process in which there is an increase in entropy with no degradation of energy is isothermal expansion. This is because the work done by the gas is reversible and can be undone without any loss of energy.

The main cause for the irreversibility is
  • a)
    mechanical and fluid friction
  • b)
    unrestricted expansion
  • c)
    heat transfer with a finite temperature difference
  • d)
    all of the above
Correct answer is option 'D'. Can you explain this answer?

Kiran Basu answered
Irreversibility in Thermodynamics
Irreversibility in thermodynamics refers to the phenomenon where a process or a system cannot be reversed to its original state with the same efficiency. The main causes for irreversibility are as follows:

Mechanical and Fluid Friction
Mechanical and fluid friction occur when there is resistance to motion or flow within a system. This resistance leads to energy losses in the form of heat, which cannot be completely recovered. Examples include friction in moving parts of machines or fluid flow through pipes.

Unrestricted Expansion
Unrestricted expansion refers to a process where a system expands freely without any external constraints. During this process, the system loses the ability to do work, leading to irreversibility. An example is the sudden release of compressed gas into a vacuum.

Heat Transfer with a Finite Temperature Difference
When heat is transferred between two bodies at different temperatures, there is always some irreversibility due to the temperature difference. This irreversibility is caused by the entropy generation in the system, leading to a decrease in overall efficiency.

Conclusion
In summary, the irreversibility in thermodynamic processes is mainly caused by mechanical and fluid friction, unrestricted expansion, and heat transfer with a finite temperature difference. These factors result in energy losses and an overall decrease in efficiency, making the process irreversible.

The exergy of an isolated system in a process
  • a)
    can never increase
  • b)
    can never decrease
  • c)
    always remains constant
  • d)
    is always positive
Correct answer is option 'A'. Can you explain this answer?

Arshiya Dey answered
Exergy of an Isolated System in a Process:

Exergy is defined as the maximum useful work that can be obtained from a system when it is brought into equilibrium with a reference environment. It is a measure of the quality of energy, and it reflects the availability of energy to do useful work. The exergy of an isolated system in a process can never increase because of the second law of thermodynamics.

Second Law of Thermodynamics:

The second law of thermodynamics states that the total entropy of an isolated system always increases over time, or remains constant in ideal cases where the system is in a state of equilibrium. Entropy is a measure of the disorder or randomness of a system, and it increases as energy is converted from one form to another. When energy is converted from a higher quality form to a lower quality form, the exergy decreases.

Exergy Destruction:

Exergy destruction is a measure of the irreversibility of a process, and it is defined as the difference between the initial exergy of a system and the final exergy of the system after the process. Exergy destruction occurs when energy is converted from a higher quality form to a lower quality form, such as from mechanical energy to thermal energy. This irreversibility is due to the increase in entropy during the process.

Conclusion:

In conclusion, exergy is a measure of the quality of energy, and it reflects the availability of energy to do useful work. The exergy of an isolated system in a process can never increase because of the second law of thermodynamics. Exergy destruction is a measure of the irreversibility of a process, and it occurs when energy is converted from a higher quality form to a lower quality form.

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