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All questions of D and F - Block Elements for NEET Exam

Can you explain the answer of this question below:
Which one of the following is a diamagnetic ion?
  • A:
    CO2+
  • B:
    Cu2+
  • C:
    Mn2+
  • D:
    Sc3+
The answer is d.

Co+2 = [Ar] 3d7
Cu2+ = [Ar] 3d9
Mn+2 = [Ar] 3d5
Sc+3 = [Ar]
We can see that only Sc+3  has no unpaired electron, so it is a diamagnetic ion.

Which one of the following exists in the oxidation state other than +3?
  • a)
    B
  • b)
    Al
  • c)
    Ce
  • d)
    Ga
Correct answer is option 'C'. Can you explain this answer?

Vivek Rana answered
The correct answer is option C
Ce exist in the oxidation state other than +3 .
 
(a) B - Boron has +1 and +3 oxidation state.
(b) Al - Aluminium has +1,+2 and +3 oxidation state.
(c) Ce - Cerium has +3 and +4 oxidation state.
(d) Ga - Gallium has +1 and +3 oxidation state.
Cerium (Ce) have [Xe] 4f²6s² electronic configuration.

Which form of silver is colourless?
  • a)
    Ag2+
  • b)
    Ag
  • c)
    Ag3+
  • d)
    Ag+
Correct answer is option 'D'. Can you explain this answer?

Om Desai answered
ilver in the form of Ag+ is colourless. For transition metal ions to exhibit color, their metal ions must have incompletely filled (n-1)d orbitals.
Ag+ =4d10,5s0
Ag+ has completely filled d orbitals hence is colourless.

Which ion will show more paramagnetic behaviour ?
  • a)
    Cu+
  • b)
    Fe2+
  • c)
    Ag+
  • d)
    Fe3+
Correct answer is option 'D'. Can you explain this answer?

Lavanya Menon answered
Since the configuration of Fe3+ ion is (argon ) 3d5,which contains maximum number of unpaired electrons, hence more will be paramagnetic behavior.

 Which among the following is colourless?
  • a)
    Sc2+
  • b)
    Zn2+
  • c)
    Ti3+
  • d)
    V3+
Correct answer is option 'B'. Can you explain this answer?

Krishna Iyer answered
Zn2+ has completely filled d-orbitals and there are no vacant d-orbitals for the transition of electrons, hence it is colourless.

The first ionization energy of the d-block elements are?
  • a)
    Lesser than p-block elements
  • b)
    Between s and p-block elements
  • c)
    Lesser than s-block elements
  • d)
    Higher than p-block elements
Correct answer is option 'B'. Can you explain this answer?

Rahul Bansal answered
The first ionization energy of the d-block elements are between s and p-block elements. Thus they are more electropositive than p-block elements and less electropositive than s-block elements.

 Brass is an alloy of:
  • a)
    Copper and molybdenum
  • b)
    Copper and zinc
  • c)
    Copper and tungsten
  • d)
    Copper and tin
Correct answer is option 'B'. Can you explain this answer?

Krishna Iyer answered
Brass is an alloy of copper and zinc, in proportions which can be varied to achieve varying mechanical and electrical properties.It is a substitutional alloy: atoms of the two constituents may replace each other within the same crystal structure.
Brass is similar to bronze, another alloy containing copper that uses tin in place of zinc; both bronze and brass may include small proportions of a range of other elements including arsenic, lead, phosphorus, aluminum, manganese, and silicon.

Which of the following group of elements are not regarded as transition elements?
  • a)
    Sc,Y,La
  • b)
    Cu, Ag, Au
  • c)
    Zn, Cd, Hg
  • d)
    Cr ,Mo,W
Correct answer is option 'C'. Can you explain this answer?

Neha Sharma answered
Zn, Cd & Hg because the d-orbital of these elements are completely filled. So, they don't show the characteristics of transition elements (i.e. the d-orbital of transition elements is incomplete.

 The inner transition elements are the elements in which the added electrons go to:
  • a)
    (n-1)d-orbitals
  • b)
    (n-1)d-orbitals and (n-1)f-orbitals
  • c)
    (n-1)d-orbitals and ns orbitals
  • d)
    (n-2)f-orbitals
Correct answer is option 'D'. Can you explain this answer?

Rohit Shah answered
 Lanthanides and actinides are called inner transition elements because they are a group of elements that are shown as the bottom two rows of the periodic table. ... Lanthanides and actinides belong to the f-block elements, which means that they have filled up their f-orbitals with electrons.

Number of electrons with l = 2 and s = 1/2 in zinc atom are
    Correct answer is '5'. Can you explain this answer?

    Krishna Iyer answered
    l = 2 means d-subshell. Zinc has 10 electrons ind-subshell in which 5 electrons are + 1/2 spin and 5 electrons are - 1/2.

    The elements which lie between s and p block elements in the long form periodic table are called as:
    • a)
      Actinides
    • b)
      d-block elements
    • c)
      Lanthanides
    • d)
      Electropositive elements
    Correct answer is option 'B'. Can you explain this answer?

    Harsh Desai answered
    D-block elements

    The long form periodic table consists of four blocks: s, p, d, and f. The s and p blocks are located on the left and right sides of the periodic table, respectively. The d-block elements are located in the middle of the periodic table, between the s and p blocks. These elements are also known as transition elements.

    Explanation:

    The d-block elements are characterized by the presence of partially filled d-orbitals in their valence shells. These elements are often referred to as transition elements because they exhibit a transition between the highly reactive s-block elements and the relatively inert p-block elements. The d-block elements are known for their unique chemical and physical properties, such as their ability to form complex ions and their high melting and boiling points.

    Examples of d-block elements include titanium, iron, copper, and zinc. These elements are widely used in industry and technology due to their unique properties, such as their strength, durability, and conductivity.

    In summary, the elements which lie between s and p block elements in the long form periodic table are called d-block elements or transition elements. These elements exhibit unique chemical and physical properties and are widely used in industry and technology.

    Which of the following is not an interstitial compound?
    • a)
      Mn4N
    • b)
      TiC
    • c)
      Fe3H
    • d)
      FeCl3
    Correct answer is option 'D'. Can you explain this answer?

    Lavanya Menon answered
    The correct answer is option D
    An interstitial compound is a compound that is formed when an atom with a small enough radius sits a hole in a metal lattice
    They are usually transitional elements
    Eg: Tic, Mn4N, Fe3H, TiH2 etc.
    Main Characteristics:-
    ·        High melting points than metals
    ·        They are much harder
    ·        They become chemically inert
    ·        They become less malleable
    So, the answer is (a), (b), (c) .
     

    The second series of transition element starts with:
    • a)
      Scandium
    • b)
      Rhodium
    • c)
      Ytterium
    • d)
      Actinium
    Correct answer is option 'C'. Can you explain this answer?

    Pooja Mehta answered
    The second series includes the elements yttrium (symbol Y, atomic number 39) to cadmium (symbol Cd, atomic number 48)

     In neutral solution, potassium permanganate forms:
    • a)
      Manganese dioxide
    • b)
      Manganous sulphate
    • c)
      Pyrolusite
    • d)
      Potassium manganite
    Correct answer is option 'A'. Can you explain this answer?

    Prakash answered
    KMno₄ is an oxidising agent (here Mn⁺⁷)in nuetral medium there is a change of 3 in it's oxidation state M⁺⁷-------Mn⁺⁴

     Melting point of d block elements across a period:
    • a)
      Increases from left to right
    • b)
      Deceases from left to right
    • c)
      Increases to a maximum at d5 and then decreases with increase of atomic number.
    • d)
      Does not change on moving from left to right.
    Correct answer is option 'C'. Can you explain this answer?

    Jayant Mishra answered
    The melting and boiling points first increase, reaches maximum and then steadily decrease across any transition series. ... The low melting points of Zn, Cd, and Hg are due to the absence of unpaired d-electrons in their atoms and thus low metallic bonding.

    Which one is of the following is the lightest transition element?
    • a)
      Ti 
    • b)
      Sc 
    • c)
      Fe 
    • d)
      Hg
    Correct answer is option 'B'. Can you explain this answer?

    T.ttttt answered
    Scandium (Sc) is the lightest transition element. It is the first element in the 3d transition series. Among the transition elements, Sc has the lowest density.

    Which of the following is not the condition for the complex formation?
    • a)
      High ionic charge density on metal ion.
    • b)
      Smaller size of transition metal ion.
    • c)
      Absence of vacant d-orbitals.
    • d)
      Availability of vacant d-orbitals.
    Correct answer is option 'C'. Can you explain this answer?

    Gunjan Lakhani answered
    The correct answer is Option C
    Only d orbitals accept the lone pair of electrons during complex formation. Their absence means that the atom will not be able to accept the lone pair of electrons and the complex will not be formed.

    Transition metals with highest melting point is
    • a)
      Cr
    • b)
      W
    • c)
      Hg
    • d)
      Sc
    Correct answer is option 'B'. Can you explain this answer?

    W belongs to 5d series and also it have lot of unpaired electrons thus it forms strong metallic bonding.

    During the process of electrolytic refining of copper, some metals present as impurity settle as ‘anode mud’ These are
    • a)
      Sn and Ag
    • b)
      Pb and Zn
    • c)
      Ag and Au
    • d)
      Fe and Ni
    Correct answer is option 'C'. Can you explain this answer?

    Hansa Sharma answered
    The correct answer is option C
    In Electrolytic refining, the impure metal is made to act as an anode. A strip of the same metal in pure form is used as a cathode. 
    They are put in a suitable electrolytic bath containing a soluble salt of the same metal. 
    The more basic metal remains in the solution and the less basic ones go to the anode mud.
    Copper is refined using an electrolytic method.
    Impurities from the blister copper deposit as anode mud which contains antimony, selenium, tellurium, silver, gold, and platinum; recovery of these elements may meet the cost of refining.

    Which one of the following is a diamagnetic ion?
    • a)
      CO2+
    • b)
      Cu2+
    • c)
      Mn2+
    • d)
      Sc3+
    Correct answer is option 'D'. Can you explain this answer?

    Ameya Pillai answered
    Co2+ (Z = 27) : [Ar]183d7 (3 unpaired electrons)
    Cu2+ (Z = 29) : [Ar]183d9 (1 unpaired electrons)
    Mn2+ (Z = 25): [Ar]183d5 (5 unpaired electrons)
    Sc3+ (Z = 21): [Ar]183d0 (No unpaired electron)
    Sc3+ with no unpaired electron will be diamagnetic

     When an alkali is added to an orange red solution of dichromate, it forms:
    • a)
      Ferrochrome
    • b)
      Chromyl chloride
    • c)
      Chromate
    • d)
      Chromium trioxide
    Correct answer is option 'C'. Can you explain this answer?

    Knowledge Hub answered
    The correct answer is C
    When an alkali is added to an orange red solution of dichromate it forms chromate.
    For example:
    K2Cr2O7  + 2KOH ➡ 2K2CrO4  +  H2

    Lucas reagent is
    • a)
      ZnCl2 + HCl
    • b)
      MnO2 + H2O
    • c)
      H2SO+ HCl
    • d)
      NO + H2O
    Correct answer is option 'A'. Can you explain this answer?

    Lucas Test is done to distinguish primary secondary and tertiary alcohols. Lucas reagent is ZnCl2 + HCl

    If molarity of K2Cr2O7 solution is 0.5 M, its normality value is
      Correct answer is '3'. Can you explain this answer?

      Ishani Patel answered
      Normality = molarity x number of electrons gained per mole of dichromate in a redox reaction. Hence, Normality = Molarity x 6

      Which has lowest and highest first ionisation enthalpy in 3d series?
      • a)
        Sc and Zn
      • b)
        Zn and Sc
      • c)
        Cu and Zn
      • d)
        Cr and Zn
      Correct answer is option 'A'. Can you explain this answer?

      Losing one electron gives Sc noble gas configuration (Ar). While Zn has d10 s2 configuration so it won't give its electron easily. So, it has high ionization enthalpy.

      The colourless ions among the lanthanides are
      • a)
        La3+
      • b)
        Gd3+
      • c)
        Lu3+
      • d)
        Ce3+
      Correct answer is option 'A,B,C,D'. Can you explain this answer?

      La3+, Gd3+ and Lu3+ have empty (4f0) half-filled (4f7) and full-filled (4f14) orbitals. Ce3+ (4f1) is colourless because it does not absorb in the visible region.

      One mole of each KMnO4 and K2Cr2O7 can oxidise ........... moles of ferrous ion.
      • a)
        5 and 5
      • b)
        5 and 6
      • c)
        6 and 5
      • d)
        6 and 6
      Correct answer is option 'B'. Can you explain this answer?

      Gauri Khanna answered
      One equivalent of KMnO4 = One equivalent of K2Cr2O7 = One equivalent of Fe2+ ion or 1/5 moles of KMnO4 = 1/6 moles of K2Cr2O7 = One mole of Fe2+ ion.
      Hence, one mole of KMnO4 reacts with 5 moles of Fe2+ ion and one mole of K2Cr2O7 reacts with 6 moles of Fe2+ ion.

      The pair of ions that have same electronic configuration
      • a)
        Fe2+ and Mn2+
      • b)
        Fe2+ and Co3+
      • c)
        Fe3+ and Co3+
      • d)
        V2+ and Cr3+
      Correct answer is option 'B,D'. Can you explain this answer?

      Saikat Dey answered
      You simply count the electron number, though , co is present just after fe, so from this logic you count the electron number is same in fe2+ and co3+,(just think) simultaneously v2+, cr3+ electron number is same, in mathematical, fe 2+ electron number is 26-2=24,, and co 3+,electron number is 27-3=24,so simultaneously v2+, and cr 3+ has same number of electron,

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