How is aluminium extracted from its bauxite ore? Explain it?
**Extraction of Aluminium from Bauxite Ore**
Aluminium is the most abundant metal in the Earth's crust, but it is not found in its pure form. Instead, it is found as a compound called bauxite. The extraction of aluminium from bauxite ore involves several steps, which are explained below:
**1. Crushing and Grinding of Bauxite:**
Bauxite is first crushed and ground into fine particles. It is then mixed with a solution of sodium hydroxide (also known as caustic soda) and heated under pressure to dissolve the aluminium compounds present in the bauxite.
**2. Digestion:**
The crushed and ground bauxite is then transferred to a digester, where it is mixed with a hot solution of caustic soda (sodium hydroxide) at high temperature and pressure. This process is known as digestion. During digestion, the aluminium compounds in the bauxite dissolve and form a solution called sodium aluminate, while impurities remain undissolved.
**3. Clarification:**
The solution obtained from the digestion process is then clarified to remove any solid impurities. This is done by allowing the solution to settle and then filtering it to separate the clear liquid from the solid impurities.
**4. Precipitation:**
After clarification, the clear liquid (sodium aluminate solution) is cooled and then treated with carbon dioxide gas. This process causes the precipitation of pure aluminium hydroxide. The chemical reaction can be represented as follows:
2NaAlO2 + 3H2O + CO2 → Al(OH)3 + Na2CO3
**5. Calcination:**
The precipitated aluminium hydroxide is then heated in a kiln or furnace to remove the water and convert it into alumina (aluminium oxide). This process is known as calcination. The chemical reaction can be represented as follows:
2Al(OH)3 → Al2O3 + 3H2O
**6. Electrolysis:**
The alumina obtained from the calcination process is then dissolved in a molten electrolyte (a mixture of cryolite and aluminium fluoride) and subjected to electrolysis. The electrolysis takes place in a large tank called a cell, which contains a carbon anode and a carbon cathode. When an electric current is passed through the electrolyte, aluminium ions are reduced at the cathode, forming liquid aluminium metal, which sinks to the bottom of the cell. Oxygen is liberated at the anode. The overall reaction can be represented as follows:
2Al2O3 → 4Al + 3O2
**7. Casting and Forming:**
The molten aluminium obtained from the electrolysis process is then cast into various shapes and forms, such as ingots, sheets, or extrusions, depending on the intended use. These aluminium products can be further processed and used in a wide range of industries.
In conclusion, the extraction of aluminium from its bauxite ore involves crushing, grinding, digestion, clarification, precipitation, calcination, electrolysis, and casting/forming. These steps allow the conversion of bauxite into pure aluminium metal, which can be used in various applications.
How is aluminium extracted from its bauxite ore? Explain it?