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The equation of state for 5 g of oxygen at a pressure P and temperature T, when occupying a volume V, will be [2004]
  • a)
    PV = (5/16) RT
  • b)
    PV = (5/32) RT
  • c)
    PV = 5 RT
  • d)
    PV = (5/2) RT where R is the gas constant.
Correct answer is option 'B'. Can you explain this answer?
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The equation of state for 5 g of oxygen at a pressure P and temperatur...
  [∵ PV = nRT]
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The equation of state for 5 g of oxygen at a pressure P and temperatur...
Explanation:
The ideal gas law equation is given by: PV = nRT

Where:
P = pressure
V = volume
n = number of moles
R = gas constant
T = temperature

In this question, we have 5 g of oxygen. To find the number of moles, we need to use the molar mass of oxygen.

The molar mass of oxygen (O₂) is 32 g/mol. Therefore, the number of moles of oxygen is given by:

n = mass/molar mass = 5 g/32 g/mol = 0.15625 mol

Now, we can substitute the values in the ideal gas law equation:

PV = nRT

P * V = (0.15625 mol) * R * T

To eliminate the need for the gas constant, we can rearrange the equation as follows:

PV = (0.15625 mol) * R * T

Now, we need to find the value of (0.15625 mol) * R. Let's call it 'k':

k = (0.15625 mol) * R

Therefore, the equation becomes:

PV = k * T

Now, we need to find the value of k. To do that, let's consider the ideal gas law equation for 1 mol of any gas:

PV = RT

Since we know that 1 mol of any gas at STP (standard temperature and pressure) occupies a volume of 22.4 L, we can substitute the values:

(1 mol) * (22.4 L) = R * (273 K)

Simplifying, we find:

R = (1 mol) * (22.4 L) / (273 K)

R = 0.0821 L mol⁻¹ K⁻¹ (approximately)

Substituting this value in the equation for k:

k = (0.15625 mol) * (0.0821 L mol⁻¹ K⁻¹)

k = 0.0128 L K⁻¹

Finally, substituting the value of k in the equation PV = k * T:

PV = (0.0128 L K⁻¹) * T

Simplifying further, we get:

PV = (5/32) * RT

Therefore, the correct equation of state for 5 g of oxygen at a pressure P and temperature T, when occupying a volume V, is PV = (5/32) RT. Hence, option B is the correct answer.
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Community Answer
The equation of state for 5 g of oxygen at a pressure P and temperatur...
PV=nRT
PV=(m/M)RT
PV=(5/32)RT (O mass is given at question is 5g
and molar mass of O is 32 )
Thus option B is correct.
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