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Solubility product of AgCl is 2.8 × 10-10 at 25ºC. Calculate solubility of the salt in 0.1 M AgNO3 solution -
  • a)
    2.8 × 10-9 mole/litre
  • b)
    2.8 × 10-10 mole/litre
  • c)
    3.2 × 10-9 mole/litre
  • d)
    3.2 × 10-12 mole/litre
Correct answer is option 'A'. Can you explain this answer?
Verified Answer
Solubility product of AgCl is 2.8 × 10-10at 25ºC. Calculate ...
Ksp(AgCl) = 2.8 × 10–10

2.8 × 10–10 = (s + 0.1)s
s = 2.8 × 10–9
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Solubility product of AgCl is 2.8 × 10-10at 25ºC. Calculate ...
Solubility Product of AgCl

The solubility product (Ksp) is a measure of the extent to which a sparingly soluble salt dissolves in water. It is defined as the product of the concentrations of the ions in a saturated solution of the salt.

The solubility product of AgCl can be represented by the equation:

AgCl(s) ⇌ Ag+(aq) + Cl-(aq)

The equilibrium expression for this reaction is:

Ksp = [Ag+][Cl-]

Given that the solubility product of AgCl is 2.8 × 10^-10 at 25°C, we can write the equation as:

2.8 × 10^-10 = [Ag+][Cl-]

Solubility of AgCl in 0.1 M AgNO3 Solution

When AgCl is dissolved in AgNO3 solution, the Ag+ ions from AgNO3 will combine with the Cl- ions from AgCl to form AgCl(s). This will result in a decrease in the concentration of Cl- ions in the solution.

To calculate the solubility of AgCl in 0.1 M AgNO3 solution, we need to consider the common ion effect. The presence of Ag+ ions from AgNO3 will shift the equilibrium of the AgCl dissociation reaction to the left, reducing the solubility of AgCl.

To find the solubility of AgCl, we can assume that x moles of AgCl dissolve, resulting in x moles of Ag+ and x moles of Cl- ions in the solution. Since AgNO3 is a strong electrolyte, it completely dissociates into Ag+ and NO3- ions.

Therefore, the concentration of Ag+ ions in the solution will be 0.1 M, and the concentration of Cl- ions will be x M.

Using the equilibrium expression for AgCl:

Ksp = [Ag+][Cl-]

Substituting the known values:

2.8 × 10^-10 = (0.1)(x)

Solving for x:

x = (2.8 × 10^-10) / 0.1

x ≈ 2.8 × 10^-9 mole/litre

Thus, the solubility of AgCl in 0.1 M AgNO3 solution is approximately 2.8 × 10^-9 mole/litre.

Therefore, the correct answer is option 'A'.
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Solubility product of AgCl is 2.8 × 10-10at 25ºC. Calculate solubility of the salt in 0.1 M AgNO3solution -a)2.8 × 10-9mole/litreb)2.8 × 10-10mole/litrec)3.2 × 10-9mole/litred)3.2 × 10-12mole/litreCorrect answer is option 'A'. Can you explain this answer?
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Solubility product of AgCl is 2.8 × 10-10at 25ºC. Calculate solubility of the salt in 0.1 M AgNO3solution -a)2.8 × 10-9mole/litreb)2.8 × 10-10mole/litrec)3.2 × 10-9mole/litred)3.2 × 10-12mole/litreCorrect answer is option 'A'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about Solubility product of AgCl is 2.8 × 10-10at 25ºC. Calculate solubility of the salt in 0.1 M AgNO3solution -a)2.8 × 10-9mole/litreb)2.8 × 10-10mole/litrec)3.2 × 10-9mole/litred)3.2 × 10-12mole/litreCorrect answer is option 'A'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Solubility product of AgCl is 2.8 × 10-10at 25ºC. Calculate solubility of the salt in 0.1 M AgNO3solution -a)2.8 × 10-9mole/litreb)2.8 × 10-10mole/litrec)3.2 × 10-9mole/litred)3.2 × 10-12mole/litreCorrect answer is option 'A'. Can you explain this answer?.
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