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An octahedral com plex with m olecular form ula 5NH3.Cl.SO4 has two isomers A and B. The solution of A gives a white precipitate with AgNO3 solution and the solution of B gives white precipitate with BaCI2 solution .The type of isomerism exhibited by the complex is
  • a)
    linkage isomerism
  • b)
    ionisation isomerism
  • c)
    coordination isomerism
  • d)
    geometrical isomerism
Correct answer is option 'B'. Can you explain this answer?
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Introduction:

In this problem, we are given an octahedral complex with the molecular formula 5NH3.Cl.SO4, which has two isomers A and B. We are also given that the solution of A gives a white precipitate with AgNO3 solution and the solution of B gives a white precipitate with BaCI2 solution. We need to determine the type of isomerism exhibited by the complex.

Explanation:

To determine the type of isomerism exhibited by the complex, let's first understand the different types of isomerism:

1. Linkage Isomerism: It occurs when the ligand is bonded to the central metal atom through a different atom. For example, if the ligand is bonded to the metal atom through a nitrogen atom in one isomer and through a sulfur atom in another isomer.

2. Ionisation Isomerism: It occurs when the counter ion of the complex is different in different isomers. For example, if the complex has a chloride ion as the counter ion in one isomer and a sulfate ion as the counter ion in another isomer.

3. Coordination Isomerism: It occurs when the ligands and the metal atoms are different in different isomers. For example, if the complex has NH3 ligands in one isomer and Cl ligands in another isomer.

4. Geometrical Isomerism: It occurs when there is a different spatial arrangement of ligands around the central metal atom in different isomers. For example, if the complex has a cis arrangement of ligands in one isomer and a trans arrangement in another isomer.

Analysis:

From the given information, we can see that the solutions of both isomers A and B give a white precipitate with different solutions. This indicates that there is a difference in the counter ions of the two isomers. Therefore, the type of isomerism exhibited by the complex is ionisation isomerism.

Conclusion:

The complex exhibits ionisation isomerism, where the counter ions of the two isomers are different.
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An octahedral com plex with m olecular form ula 5NH3.Cl.SO4 has two isomers A and B. The solution of A gives a white precipitate with AgNO3 solution and the solution of B gives white precipitate with BaCI2 solution .The type of isomerism exhibited by the complex isa)linkage isomerismb)ionisationisomerismc)coordinationisomerismd)geometricalisomerismCorrect answer is option 'B'. Can you explain this answer?
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An octahedral com plex with m olecular form ula 5NH3.Cl.SO4 has two isomers A and B. The solution of A gives a white precipitate with AgNO3 solution and the solution of B gives white precipitate with BaCI2 solution .The type of isomerism exhibited by the complex isa)linkage isomerismb)ionisationisomerismc)coordinationisomerismd)geometricalisomerismCorrect answer is option 'B'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about An octahedral com plex with m olecular form ula 5NH3.Cl.SO4 has two isomers A and B. The solution of A gives a white precipitate with AgNO3 solution and the solution of B gives white precipitate with BaCI2 solution .The type of isomerism exhibited by the complex isa)linkage isomerismb)ionisationisomerismc)coordinationisomerismd)geometricalisomerismCorrect answer is option 'B'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for An octahedral com plex with m olecular form ula 5NH3.Cl.SO4 has two isomers A and B. The solution of A gives a white precipitate with AgNO3 solution and the solution of B gives white precipitate with BaCI2 solution .The type of isomerism exhibited by the complex isa)linkage isomerismb)ionisationisomerismc)coordinationisomerismd)geometricalisomerismCorrect answer is option 'B'. Can you explain this answer?.
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