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Direction (Q. Nos. 1-10) This section contains 10 multiple choice questions. Each question has four choices (a), (b), (c) and (d), out of which ONLY ONE is correct.
Q. 
Which of the following is not a pseudo halideion?
  • a)
    CNO-
  • b)
    CN-
  • c)
    SCN-
  • d)
    S2-
Correct answer is option 'D'. Can you explain this answer?
Verified Answer
Direction (Q. Nos. 1-10) This section contains 10 multiple choice ques...
Pseudo halides are uni-negative charged similar to halideions.
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Direction (Q. Nos. 1-10) This section contains 10 multiple choice ques...
Explanation:

Pseudo halides are ions that have similar chemical properties to halide ions (such as chloride, bromide, and iodide) but are not actually halides. They typically have a negative charge and contain a central atom bonded to one or more electronegative atoms.

In the given options, CNO-, CN-, and SCN- are all examples of pseudo halide ions because they exhibit similar chemical properties to halides. However, S2- is not a pseudo halide ion.

The reason S2- is not a pseudo halide ion is because it does not have similar chemical properties to halide ions. Unlike halides, which are typically good nucleophiles and are often used in substitution reactions, S2- is a strong reducing agent and is not commonly involved in substitution reactions.

S2- is a reducing agent because it can easily gain two electrons to form S2-, which has a filled valence shell. This makes it a good reducing agent in redox reactions. In contrast, halides are not strong reducing agents because they have a filled valence shell and do not readily gain electrons.

Additionally, S2- does not have the same size or electronegativity as halide ions. Halides (such as Cl-, Br-, and I-) have larger atomic radii and lower electronegativities than sulfur (S). This difference in size and electronegativity affects their chemical properties and reactivity.

In summary, S2- is not a pseudo halide ion because it does not exhibit the same chemical properties as halide ions and has different size and electronegativity characteristics.
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