Specify any three rules of nomenclature of organic compounds ?
Chemical Nomenclature: IUPAC Rules
According to the IUPAC system, the nomenclature of organic compounds consists of the following parts:
1) Steps Involved
Longest Chain Rule: In this step, all we have to do is identify the parent hydrocarbon and give the name to it. The parent chain of the compound is usually the longest chain of carbon atoms. This chain could be straight or of a different shape.
Lowest number of Locants: We start the numbering of the carbon atoms in the longest chain from the end that gives the lowest number to the carbon atoms carrying the substituents.
Multiple Presence of the same substituent: Prefixes such as di, tri, etc. are added to the substituents that are present twice, thrice respectively in the parent chain.
Naming the various substituents: If more than one substituent is present, then we need to arrange the substituents in an alphabetical order of their names.
Naming different substituents at equivalent positions: If we find the presence of two different substituents on the same position from the two ends, what do we do? In such cases, the substituent first in the alphabetical order gets the lowest number.
The Naming of Complex Substituents: We name the complex substituent when the substituent on the parent chain has a branched structure (i.e complex structure). We name these substituents as a substituted alkyl group. It is also important to note that the carbon atom of this substituent gets the number 1. We write the name of these type of substituents in brackets.
The final name will be in format : Locant + Prefix + Root + Locant + Suffix. Now, we will look at some more details of nomenclature of organic compounds.
2) Word root
It indicates the number of carbon atoms in the longest selected carbon chain. For example, C1 is ‘Meth’ and C5 is ‘Pent’.
3) Suffix
A suffix is generally a functional group in the molecule which follows the word root. We can divide it into:
Primary suffix: We write it immediately after the word root. For example, in alkanes the suffix is ane.
Secondary suffix: We write it after the primary suffix. For instance, if a compound has alkane and alcohol group attached to it, the naming will be alkanol, -ol being the suffix for alcohol.
4) Prefix
We add the prefix to the word root while naming the compound. It indicates the presence of substituent groups or side chains in the organic molecule. It reveals the cyclic and acyclic nature of the compound.
Primary prefix: Indicates whether the molecule is cyclic or not. For example, for cyclic compounds the prefix used is cyclo.
Secondary prefix: Indicates the presence of substituent groups or any side chain. For example –CH3is known as Methyl and –Br is Bromo.
Specify any three rules of nomenclature of organic compounds ?
Introduction:
Nomenclature is the systematic naming of organic compounds. It is important to have a common naming system for organic compounds to ensure clear communication among scientists. The rules of nomenclature provide guidelines for naming organic compounds based on their structure and functional groups.
1. IUPAC Nomenclature:
The International Union of Pure and Applied Chemistry (IUPAC) is the organization responsible for establishing and maintaining the rules of nomenclature for organic compounds. The IUPAC nomenclature system ensures that every compound has a unique and unambiguous name.
2. Rule of Priority:
In organic compounds, functional groups are the key determinants for naming. The rule of priority states that the functional group with the highest priority receives the lowest possible number in the name. The priority order is determined by the functional groups' ability to influence the properties and reactions of the compound. For example:
- Alkenes have a higher priority than alkynes.
- Alcohols have a higher priority than ethers.
- Carboxylic acids have a higher priority than aldehydes.
The priority order is determined by the location of the functional group in the carbon chain. The carbon chain is numbered from the end that gives the functional group the lowest number.
3. Naming Alkanes:
Alkanes are hydrocarbon compounds that consist of only carbon and hydrogen atoms bonded together by single bonds. The following rules are used to name alkanes:
- Identify the longest continuous carbon chain in the molecule.
- Use the corresponding prefix (meth-, eth-, prop-, but-, etc.) to indicate the number of carbon atoms in the chain.
- Add the suffix "-ane" to indicate that it is an alkane.
If there are substituent groups attached to the carbon chain, their names are added as prefixes. The substituent groups are named using the appropriate prefixes (methyl-, ethyl-, propyl-, etc.) and their positions are indicated by numbers.
Conclusion:
Nomenclature of organic compounds is based on the IUPAC system, which provides a systematic and unambiguous way of naming compounds. The rules of priority ensure that functional groups are given the lowest possible numbers in the name. Alkanes, the simplest organic compounds, are named by identifying the longest carbon chain and using appropriate prefixes and suffixes. Following these rules allows scientists to communicate effectively and accurately describe organic compounds.