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which of the following have highest resonance energy? a)pyrrole b)furan c)pyridine. correct option is c)pyridine. can you explain wgy?(why*?)
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which of the following have highest resonance energy? ...
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which of the following have highest resonance energy? ...
**Resonance Energy and Aromaticity**

Resonance energy is a measure of the stability of a molecule due to the delocalization of electrons through resonance. Aromatic compounds, which exhibit a high degree of stability due to the delocalization of pi electrons, have high resonance energy. The higher the resonance energy, the more stable the compound.

**Aromaticity in Heterocyclic Compounds**

Heterocyclic compounds are organic compounds that contain one or more heteroatoms (atoms other than carbon) in their ring structure. When discussing aromaticity in heterocyclic compounds, we focus on the delocalization of pi electrons within the ring.

**Comparison of Pyrrole, Furan, and Pyridine**

Pyrrole, furan, and pyridine are all heterocyclic compounds with different ring structures. Let's compare their aromaticity and resonance energy:

**Pyrrole:**
- Pyrrole contains a five-membered ring with four carbon atoms and one nitrogen atom.
- The carbon atoms in pyrrole are sp2 hybridized and participate in pi bonding with the nitrogen atom.
- The nitrogen atom donates a lone pair of electrons into the pi system, creating a delocalized electron cloud.
- Pyrrole is aromatic and exhibits high resonance energy due to the delocalization of six pi electrons in the ring.
- The presence of the lone pair on nitrogen enhances the aromaticity of pyrrole.

**Furan:**
- Furan contains a five-membered ring with four carbon atoms and one oxygen atom.
- The oxygen atom is more electronegative than carbon, leading to a partial positive charge on the carbon atoms adjacent to oxygen.
- The pi electrons in furan are delocalized over the ring, but the presence of the oxygen atom disrupts the aromaticity.
- Furan is aromatic but less stable than pyrrole due to the presence of the electronegative oxygen atom, which withdraws electron density from the ring.
- The lower resonance energy of furan compared to pyrrole is attributed to the destabilizing effect of the oxygen atom.

**Pyridine:**
- Pyridine contains a six-membered ring with five carbon atoms and one nitrogen atom.
- The carbon atoms in pyridine are sp2 hybridized and participate in pi bonding with the nitrogen atom.
- The nitrogen atom is less electronegative than oxygen and does not disrupt the aromaticity of the ring.
- The pi electrons in pyridine are delocalized over the ring, and the compound is aromatic.
- Pyridine has the highest resonance energy among the three compounds because of the greater number of delocalized electrons in the six-membered ring.

**Conclusion**

In summary, pyridine has the highest resonance energy among pyrrole, furan, and pyridine due to the presence of a six-membered ring with a greater number of delocalized electrons. The aromaticity of pyridine is not disrupted by the nitrogen atom, unlike furan, which contains an electronegative oxygen atom.
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which of the following have highest resonance energy? a)pyrrole b)furan c)pyridine. correct option is c)pyridine. can you explain wgy?(why*?) Related: Doubts. Please write solutions?
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