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A compound on treatment with NaOH followed by addition of AgN03 produces white precipitate at room temperature. The precipitate is soluble in NH4OH, The compound is identified as
  • a)
    vinyl chloride
  • b)
    benzyl chloride
  • c)
    chlorobenzene
  • d)
    ethyl bromide
Correct answer is option 'B'. Can you explain this answer?
Verified Answer
A compound on treatment with NaOH followed by addition of AgN03 produc...
Halides Cl¯, Br¯ , I React with AgN03 to give
AgCl → soluble in NH4OH
AgBr → spraringly soluble in NH4OH A g l → Insoluble
and the C - Cl bond is weakest in benzyl chloride [(sp3) hybridised carbon is attached toCl]
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Most Upvoted Answer
A compound on treatment with NaOH followed by addition of AgN03 produc...
Identification of the Compound:
- The compound is identified as benzyl chloride based on the given reactions.

Reaction with NaOH:
- Benzyl chloride reacts with NaOH to form benzyl alcohol and sodium chloride.
- The reaction is: C6H5CH2Cl + NaOH → C6H5CH2OH + NaCl

Formation of White Precipitate with AgNO3:
- When benzyl alcohol is treated with AgNO3, a white precipitate of silver chloride (AgCl) is formed.
- The reaction is: C6H5CH2OH + AgNO3 → C6H5CH2Cl + AgCl + HNO3

Solubility in NH4OH:
- The white precipitate of AgCl formed is soluble in NH4OH due to the formation of a complex ion [Ag(NH3)2]+.
- The reaction is: AgCl + 2NH4OH → [Ag(NH3)2]+ + Cl- + 2H2O
Therefore, based on the given reactions, the compound is identified as benzyl chloride.
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A compound on treatment with NaOH followed by addition of AgN03 produces white precipitate at room temperature. The precipitate is soluble in NH4OH, The compound is identified asa)vinyl chlorideb)benzyl chloridec)chlorobenzened)ethyl bromideCorrect answer is option 'B'. Can you explain this answer?
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A compound on treatment with NaOH followed by addition of AgN03 produces white precipitate at room temperature. The precipitate is soluble in NH4OH, The compound is identified asa)vinyl chlorideb)benzyl chloridec)chlorobenzened)ethyl bromideCorrect answer is option 'B'. Can you explain this answer? for NEET 2025 is part of NEET preparation. The Question and answers have been prepared according to the NEET exam syllabus. Information about A compound on treatment with NaOH followed by addition of AgN03 produces white precipitate at room temperature. The precipitate is soluble in NH4OH, The compound is identified asa)vinyl chlorideb)benzyl chloridec)chlorobenzened)ethyl bromideCorrect answer is option 'B'. Can you explain this answer? covers all topics & solutions for NEET 2025 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for A compound on treatment with NaOH followed by addition of AgN03 produces white precipitate at room temperature. The precipitate is soluble in NH4OH, The compound is identified asa)vinyl chlorideb)benzyl chloridec)chlorobenzened)ethyl bromideCorrect answer is option 'B'. Can you explain this answer?.
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