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Co-ordination number of Be in Beryllium chloride in solid state and at higher temperature of order of 1200 K respectively are
  • a)
    2, 2
  • b)
    2, 6
  • c)
    4, 2
  • d)
    4, 4
Correct answer is option 'C'. Can you explain this answer?
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Co-ordination number of Be in Beryllium chloride in solid state and at...
BeCI2 in solid state form polymeric chloro bridge compound,

At high temperature, it exist as linear monomer of form 
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Co-ordination number of Be in Beryllium chloride in solid state and at...
BeCI2 in solid state form polymeric chloro bridge compound,

At high temperature, it exist as linear monomer of form 
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Co-ordination number of Be in Beryllium chloride in solid state and at...
BeCl2 is an electron deficient compound with sp hybridization,so in solid state it combines with another BeCl2 molecule to give Be2Cl4 by forming coordinate bond between Cl and Be thus attaining more stability. Thus, coordination number is 4 in solid state. However in gaseous state it exists as a single molecule BeCl2, having coordination number 2.
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Co-ordination number of Be in Beryllium chloride in solid state and at higher temperature of order of 1200 K respectively area)2, 2b)2, 6c)4, 2d)4, 4Correct answer is option 'C'. Can you explain this answer?
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