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Vapours of an alcohol were passed over red hot copper. It gave an olefin. The alcohol is
  • a)
    Primary
  • b)
    Secondary
  • c)
    Tertiary
  • d)
    None
Correct answer is option 'C'. Can you explain this answer?
Most Upvoted Answer
Vapours of an alcohol were passed over red hot copper. It gave an olef...
Tertiary alcohol when react with copper at 573Kdehydration takes place and alkene (olefin) is formed while primary and secondary alcohol on reaction gives aldehyde and ketone by dehydrogenation. Hence opt C is correct
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Community Answer
Vapours of an alcohol were passed over red hot copper. It gave an olef...
Explanation:

Alcohol Reacting with Copper:
When vapours of an alcohol are passed over red hot copper, the alcohol undergoes dehydrogenation to give an olefin.

Tertiary Alcohol:
In this case, the alcohol must be tertiary in nature. Tertiary alcohols are the most reactive towards dehydrogenation reactions as they have a more stable carbocation intermediate formation during the process.

Formation of Olefin:
The dehydrogenation reaction leads to the removal of hydrogen atoms from the alcohol molecule, resulting in the formation of a double bond in the olefin product.

Red Hot Copper Catalyst:
The presence of red hot copper acts as a catalyst in this reaction, providing the necessary conditions for the dehydrogenation process to occur efficiently.
Therefore, based on the given information, the alcohol in this scenario is most likely a tertiary alcohol since it forms an olefin when reacted with red hot copper.
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