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   + ZnBr2
This reaction is a case of
  • a)
    α-elimination
  • b)
    β-elimination
  • c)
    γ-elimination
  • d)
    None of these
Correct answer is option 'B'. Can you explain this answer?
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Most Upvoted Answer
+ ZnBr2This reaction is a case ofa)-eliminationb)-eliminationc)-elimin...

both Br are eliminate from adjacent corbon that is called B elimination.
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Community Answer
+ ZnBr2This reaction is a case ofa)-eliminationb)-eliminationc)-elimin...

both Br are eliminate from adjacent corbon that is called B elimination.
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Both the Cβ–H and Cα–X bonds are breaking in the transition state of E2 reactions. The rate of E2 reaction is of second order. The rate shows primary isotopic (deuterium) effect, i.e. if Cβ–H is replaced by Cβ–D, the rate of reaction decreases sharply. The rate is also corelated with nucleofugality i.e. the ability of leaving group to leave. With a better nucleofuge, the rate of reaction increases. This is called the element effect.The element effect is also observed in E1cB reactions in which the second step is rate determining and elimination of first order w.r.t. conjugate base is observed. For E1cB reaction KH/KD ~ 1, therefore proton abstraction is not involved in the rate determing step. In D2O the incorporation of Deuterium at Cβ–H in the substrate is found many times faster than rate of elimination, in E1cB reaction.In E1 reaction only nucleofuge departs in slow step and a carbocation intermediate is formed.Q.Observe the given reaction. In this reactionWhat is not true about this reaction

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+ ZnBr2This reaction is a case ofa)-eliminationb)-eliminationc)-eliminationd)None of theseCorrect answer is option 'B'. Can you explain this answer?
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