Free radicals can undergoa)Rearrangement to a more stable free radical...
Free radicals can undergo all given types of processes.
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Free radicals can undergoa)Rearrangement to a more stable free radical...
Free radicals can undergo various reactions:
1. Rearrangement to a more stable free radical: Free radicals can undergo rearrangement reactions to form more stable radicals. This rearrangement occurs when the unpaired electron in the radical moves to a different atom or position within the molecule. This process helps to stabilize the radical and reduce its reactivity. For example, in the case of a carbon-centered radical, the unpaired electron can shift to a neighboring carbon atom or to a different position in the same carbon chain.
2. Decomposition to give another free radical: Free radicals can also undergo decomposition reactions where they break down into smaller fragments, generating new free radicals in the process. This can occur through homolytic cleavage of a bond, where each atom retains one electron from the broken bond, resulting in the formation of two new radicals. This chain reaction process can lead to the propagation of radical reactions.
3. Combination with other free radical: Free radicals can also combine with other free radicals to form stable molecules. This reaction, known as radical-radical combination or radical termination, occurs when two radicals collide and their unpaired electrons pair up to form a covalent bond. The resulting product is typically a non-radical species, which is more stable than the original radicals.
Overall, free radicals are highly reactive species that can participate in a variety of reactions. The specific reaction that a free radical undergoes depends on its structure, the presence of other reactive species, and the reaction conditions. The three mentioned reactions (rearrangement, decomposition, and combination) are all possible outcomes for free radicals.
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