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Consider the following carbocations is most stable:
  • a)
    C6H5CH2+
  • b)
    C6H5CH2CH2+
  • c)
    C6H5CH+CH3
  • d)
    C6H5C+ (CH3)2
Correct answer is option 'D'. Can you explain this answer?
Most Upvoted Answer
Consider the following carbocations is most stable:a)C6H5CH2+b)C6H5CH2...
Explanation:

The stability of a carbocation depends on the electron donating or withdrawing ability of the substituent groups attached to it. In this case, we have to compare the stability of four carbocations, which are:

a) C6H5CH2+
b) C6H5CH2CH2+
c) C6H5CH+CH3
d) C6H5C+(CH3)2

To compare their stability, we have to look at the following factors:

1. Inductive effect: It is the electron-withdrawing or donating effect of the substituent groups attached to the carbocation. The more electron-donating the groups, the more stable the carbocation.

2. Hyperconjugation effect: It is the stabilizing effect of the adjacent C-H bonds that donate electrons to the empty p-orbital of the carbocation.

3. Resonance effect: If the carbocation can form a resonance structure, it will be more stable.

Now, let's analyze each carbocation and compare their stability:

a) C6H5CH2+: It has a phenyl (C6H5) group, which is electron-donating. However, it has no adjacent C-H bonds to donate electrons to the empty p-orbital. Also, it cannot form a resonance structure. Therefore, it is the least stable carbocation among the given options.

b) C6H5CH2CH2+: It has two ethyl (CH2CH3) groups, which are weakly electron-donating. It has four adjacent C-H bonds to donate electrons to the empty p-orbital. However, it cannot form a resonance structure. Therefore, it is more stable than option a), but less stable than options c) and d).

c) C6H5CH+CH3: It has a methyl (CH3) group, which is weakly electron-donating. It has three adjacent C-H bonds to donate electrons to the empty p-orbital. Also, it can form a resonance structure, where the positive charge can be delocalized over the phenyl ring. Therefore, it is more stable than options a) and b), but less stable than option d).

d) C6H5C+(CH3)2: It has two methyl (CH3) groups, which are strongly electron-donating. It has six adjacent C-H bonds to donate electrons to the empty p-orbital. Also, it can form a resonance structure, where the positive charge can be delocalized over the phenyl ring and both methyl groups. Therefore, it is the most stable carbocation among the given options.

Therefore, the correct answer is option d) C6H5C+(CH3)2.
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Consider the following carbocations is most stable:a)C6H5CH2+b)C6H5CH2CH2+c)C6H5CH+CH3d)C6H5C+ (CH3)2Correct answer is option 'D'. Can you explain this answer?
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Consider the following carbocations is most stable:a)C6H5CH2+b)C6H5CH2CH2+c)C6H5CH+CH3d)C6H5C+ (CH3)2Correct answer is option 'D'. Can you explain this answer? for Chemistry 2024 is part of Chemistry preparation. The Question and answers have been prepared according to the Chemistry exam syllabus. Information about Consider the following carbocations is most stable:a)C6H5CH2+b)C6H5CH2CH2+c)C6H5CH+CH3d)C6H5C+ (CH3)2Correct answer is option 'D'. Can you explain this answer? covers all topics & solutions for Chemistry 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Consider the following carbocations is most stable:a)C6H5CH2+b)C6H5CH2CH2+c)C6H5CH+CH3d)C6H5C+ (CH3)2Correct answer is option 'D'. Can you explain this answer?.
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