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Which one of the following oxides of chlorine is obtained by passing dry chlorine over silver chlorate at 90 °C?
  • a)
    Cl2O
  • b)
    ClO3
  • c)
    ClO2
  • d)
    ClO4
Correct answer is option 'C'. Can you explain this answer?
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Passing Dry Chlorine Over Silver Chlorate at 90 °C
- When dry chlorine gas is passed over silver chlorate (AgClO3) at 90 °C, it undergoes a redox reaction and forms different oxides of chlorine.
- The reaction can be represented as: 2AgClO3 + Cl2 → 2AgCl + 3ClO2
- As per the reaction, the oxide of chlorine obtained in this process is ClO2.

Explanation of the Reaction
- Silver chlorate (AgClO3) decomposes upon heating to form silver chloride (AgCl) and oxygen gas (O2).
- When dry chlorine gas (Cl2) is passed over silver chlorate at 90 °C, chlorine displaces oxygen from silver chlorate to form silver chloride and chlorine dioxide.
- The formation of ClO2 is evident from the balanced chemical equation that shows the production of 3 moles of ClO2 for every 1 mole of Cl2 reacted with 2 moles of AgClO3.

Conclusion
- Therefore, the correct oxide of chlorine obtained by passing dry chlorine over silver chlorate at 90 °C is ClO2, as per the reaction and stoichiometry involved in the process.
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Which one of the following oxides of chlorine is obtained by passing dry chlorine over silver chlorate at 90 °C?a)Cl2Ob)ClO3c)ClO2d)ClO4Correct answer is option 'C'. Can you explain this answer?
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