NEET Exam  >  NEET Questions  >  Can you explain why is bimolecular dehydratio... Start Learning for Free
Can you explain why is bimolecular dehydration not appropriate for preparation of ethyl methyl ether?
Verified Answer
Can you explain why is bimolecular dehydration not appropriate for pre...
"Bimolecular dehydration" is a way of preparing diethyl ether from the dehydrating action of concentrated sulfuric acid on ethanol. The dehydrating agent, conc. H2SO4 abstracts a hydrogen from one ethanol and a hydroxyl (the -OH group) of a neighbor. Those radicals formed, join together. Sulfuric acid grabs a mole of water. 
So this method works only with symmetrical ethers,Methyl Ethyl ether is better prepared from Sodium ethoxide and methanol or Sodium methoxide and ethanol.        
This question is part of UPSC exam. View all NEET courses
Most Upvoted Answer
Can you explain why is bimolecular dehydration not appropriate for pre...
Introduction:

Ethyl methyl ether (also known as methoxyethane) is an organic compound with the formula CH3OCH2CH3. It is an ether that can be prepared through various methods, including bimolecular dehydration. However, bimolecular dehydration is not an appropriate method for the preparation of ethyl methyl ether due to several reasons.

Explanation:

Lack of Suitable Reactants:
Bimolecular dehydration involves the removal of water (H2O) from two molecules to form a new compound. In the case of ethyl methyl ether, the reactants required for bimolecular dehydration would be ethanol (CH3CH2OH) and methanol (CH3OH). However, these reactants do not undergo dehydration to form ethyl methyl ether under normal conditions. Instead, they predominantly undergo intermolecular dehydration to form diethyl ether.

Competition from Diethyl Ether Formation:
When ethanol and methanol are subjected to dehydration conditions, they primarily undergo intermolecular dehydration to form diethyl ether (CH3CH2OCH2CH3). This is due to the higher stability of diethyl ether compared to ethyl methyl ether. The reaction between ethanol and methanol takes place as follows:
CH3CH2OH + CH3OH → CH3CH2OCH2CH3 + H2O

Higher Reactivity of Alcohols:
Alcohols, such as ethanol and methanol, are more reactive towards dehydration than ethers. This is because alcohols contain a hydroxyl (-OH) group, which is a good leaving group. In contrast, ethers do not have a leaving group, making them less reactive towards dehydration. Therefore, even if ethyl methyl ether were to be formed through bimolecular dehydration, the reaction would be sluggish and inefficient.

Alternative Methods:
There are alternative methods for the preparation of ethyl methyl ether that are more suitable and efficient. One common method involves the reaction between methanol and ethyl chloride in the presence of a base, such as sodium hydroxide (NaOH). This method, known as Williamson ether synthesis, allows for the direct formation of ethyl methyl ether without the need for dehydration.

Conclusion:

In conclusion, bimolecular dehydration is not appropriate for the preparation of ethyl methyl ether due to the lack of suitable reactants, competition from diethyl ether formation, and the higher reactivity of alcohols. Alternative methods, such as Williamson ether synthesis, are more suitable for the efficient synthesis of ethyl methyl ether.
Attention NEET Students!
To make sure you are not studying endlessly, EduRev has designed NEET study material, with Structured Courses, Videos, & Test Series. Plus get personalized analysis, doubt solving and improvement plans to achieve a great score in NEET.
Explore Courses for NEET exam

Top Courses for NEET

Can you explain why is bimolecular dehydration not appropriate for preparation of ethyl methyl ether?
Question Description
Can you explain why is bimolecular dehydration not appropriate for preparation of ethyl methyl ether? for NEET 2024 is part of NEET preparation. The Question and answers have been prepared according to the NEET exam syllabus. Information about Can you explain why is bimolecular dehydration not appropriate for preparation of ethyl methyl ether? covers all topics & solutions for NEET 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Can you explain why is bimolecular dehydration not appropriate for preparation of ethyl methyl ether?.
Solutions for Can you explain why is bimolecular dehydration not appropriate for preparation of ethyl methyl ether? in English & in Hindi are available as part of our courses for NEET. Download more important topics, notes, lectures and mock test series for NEET Exam by signing up for free.
Here you can find the meaning of Can you explain why is bimolecular dehydration not appropriate for preparation of ethyl methyl ether? defined & explained in the simplest way possible. Besides giving the explanation of Can you explain why is bimolecular dehydration not appropriate for preparation of ethyl methyl ether?, a detailed solution for Can you explain why is bimolecular dehydration not appropriate for preparation of ethyl methyl ether? has been provided alongside types of Can you explain why is bimolecular dehydration not appropriate for preparation of ethyl methyl ether? theory, EduRev gives you an ample number of questions to practice Can you explain why is bimolecular dehydration not appropriate for preparation of ethyl methyl ether? tests, examples and also practice NEET tests.
Explore Courses for NEET exam

Top Courses for NEET

Explore Courses
Signup for Free!
Signup to see your scores go up within 7 days! Learn & Practice with 1000+ FREE Notes, Videos & Tests.
10M+ students study on EduRev